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11.
Duraiswamy SukanyaDuraisamy Senthil Raja Nattamai S.P. BhuvaneshKaruppannan Natarajan 《Polyhedron》2011,30(6):1108-1113
New hexa-coordinated Ru(III) complexes of the type [Ru(H2Pzdc)(EPh3)3X2] have been synthesized by reacting 3,5-pyrazole dicarboxylic acid (H3Pzdc) with the appropriate starting complexes [RuX3(EPh3)3] (where X = Cl or Br; E = P or As). The ligand behaves as a bidentate monobasic chelate. All the complexes have been characterized by analytical and spectroscopic (IR, electronic and EPR) data. Single-crystal X-ray analysis of the complex [Ru(H2Pzdc)(PPh3)2Cl2]·C6H6·C2H5OH revealed that the coordination environment around the ruthenium center consists of an NOP2Cl2 octahedron. The planar ligand occupies the equatorial position along with two chlorine atoms, while the triphenylphosphine groups occupy the axial positions. The electrochemical behavior of the new complexes was studied using cyclic voltammetry. The new mononuclear ruthenium complexes are capable of acting as catalysts for the oxidation of alcohols. 相似文献
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The geometry dependent resistance models are used to estimate the effective thermal conductivity of two-phase materials based on the unit cell approach. The algebraic equations are derived based on isotherm approach for various geometries. The effective thermal conductivity of the above models are found and compared with experimental data with a minimum and maximum deviation of ±3.976 and ±19.55%, respectively. The present models are good agreement with experimental results. 相似文献
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Research on Chemical Intermediates - Caryota urens seeds are an agro-based material that can be used as an eco-friendly and low cost adsorbent for the removal of metal ions. In the present study,... 相似文献
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We show that simple Bose Hubbard models with unfrustrated hopping and short range two-body repulsive interactions can support stable fractionalized phases in two and higher dimensions, and in zero magnetic field. The simplicity of the constructed models advances the possibility of a controlled experimental realization and novel applications of such unconventional states. 相似文献
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In spatial dimensions d>or=2, Kondo lattice models of conduction and local moment electrons can exhibit a fractionalized, nonmagnetic state (FL(*)) with a Fermi surface of sharp electronlike quasiparticles, enclosing a volume quantized by (rho(a)-1)(mod 2), with rho(a) the mean number of all electrons per unit cell of the ground state. Such states have fractionalized excitations linked to the deconfined phase of a gauge theory. Confinement leads to a conventional Fermi liquid state, with a Fermi volume quantized by rho(a)(mod 2), and an intermediate superconducting state for the Z2 gauge case. The FL(*) state permits a second order metamagnetic transition in an applied magnetic field. 相似文献
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Natarajan Senthil Kumar 《Tetrahedron》2009,65(4):822-830
Synthesis of mixed heterocyclic system containing benzo[c]thiophene, dibenzo-heterocycles, and thiophene unit is described. 相似文献
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Chinnusamy Saravanan Sengodan Senthil Palaninathan Kannan 《Journal of polymer science. Part A, Polymer chemistry》2008,46(23):7843-7860
Copolymer containing new thermally reversible click chemistry‐assisted triazole‐substituted azobenzene and fulgimide units in the pendant F‐co‐A was prepared by free‐radical solution addition polymerization technique. The F and A were also prepared for comparison. The DSC analysis of F indicates that the polymer possessing the C‐form of fulgimide unit exhibited higher Tm than that of E‐form of the same polymer and revealed that the C‐form of fulgimide unit in F is highly ordered. The cis‐trans back isomerization behavior of the click chemistry‐assisted triazole‐substituted azobenzene unit in film A has thermal irreversibility, while in F‐co‐A it exhibited thermal reversibility. The UV‐exposed film of F‐co‐A heated around Tg leads to cis‐trans back isomerization of azobenzene unit and thermally stable C‐form of fulgimide which retains its conjugated structure where both the photochromic units are converted into planar conformations and exhibit high fluorescence properties. The fluorescence maxima of C‐form in F‐co‐A red shifted compared with F , because the substituted triazole ring in the azobenzene unit stabilized the C‐form of fulgimide unit. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7843–7860, 2008 相似文献