首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   80423篇
  免费   538篇
  国内免费   388篇
化学   25998篇
晶体学   798篇
力学   6769篇
数学   32293篇
物理学   15491篇
  2023年   52篇
  2022年   75篇
  2021年   118篇
  2020年   167篇
  2019年   187篇
  2018年   10487篇
  2017年   10297篇
  2016年   6232篇
  2015年   981篇
  2014年   439篇
  2013年   486篇
  2012年   4018篇
  2011年   10699篇
  2010年   5757篇
  2009年   6142篇
  2008年   6752篇
  2007年   8873篇
  2006年   344篇
  2005年   1378篇
  2004年   1567篇
  2003年   1984篇
  2002年   1026篇
  2001年   264篇
  2000年   301篇
  1999年   167篇
  1998年   200篇
  1997年   148篇
  1996年   203篇
  1995年   124篇
  1994年   84篇
  1993年   103篇
  1992年   67篇
  1991年   68篇
  1990年   55篇
  1989年   60篇
  1988年   61篇
  1987年   63篇
  1986年   62篇
  1985年   47篇
  1984年   44篇
  1982年   42篇
  1981年   45篇
  1980年   49篇
  1979年   47篇
  1978年   40篇
  1914年   45篇
  1913年   40篇
  1912年   40篇
  1909年   41篇
  1908年   40篇
排序方式: 共有10000条查询结果,搜索用时 12 毫秒
991.
The nonlinear lattice — a new and nonlinear class of periodic potentials — was recently introduced to generate various nonlinear localized modes. Several attempts failed to stabilize two-dimensional (2D) solitons against their intrinsic critical collapse in Kerr media. Here, we provide a possibility for supporting 2D matter-wave solitons and vortices in an extended setting — the cubic and quintic model — by introducing another nonlinear lattice whose period is controllable and can be different from its cubic counterpart, to its quintic nonlinearity, therefore making a fully “nonlinear quasi-crystal”.A variational approximation based on Gaussian ansatz is developed for the fundamental solitons and in particular, their stability exactly follows the inverted Vakhitov–Kolokolov stability criterion, whereas the vortex solitons are only studied by means of numerical methods. Stability regions for two types of localized mode — the fundamental and vortex solitons — are provided. A noteworthy feature of the localized solutions is that the vortex solitons are stable only when the period of the quintic nonlinear lattice is the same as the cubic one or when the quintic nonlinearity is constant, while the stable fundamental solitons can be created under looser conditions. Our physical setting (cubic-quintic model) is in the framework of the Gross–Pitaevskii equation or nonlinear Schrödinger equation, the predicted localized modes thus may be implemented in Bose–Einstein condensates and nonlinear optical media with tunable cubic and quintic nonlinearities.  相似文献   
992.
Nowadays, mixed metal oxide (MMO) anodes are a superior alternative to lead alloys in electrowinning processes. Passivation of titanium substrate is the most common mechanism of deactivation in these anodes. In this research, titanium oxide nanotubes have been utilised as an interlayer between the substrate and a mixed metal oxide coating in order to improve the anode electrochemical behaviour and life via retardation of titanium passivation. Anodising of the substrate was done in 0.5 wt% hydrofluoric acid for 30, 60 and 240 min. The samples were subsequently coated with a coating composed of IrO2-RuO2-Ta2O5. The microstructure of different samples was observed by scanning with an electron microscope, and the electrochemical behaviour of the samples was studied by accelerated life test, cyclic voltammetry and electrochemical impedance spectroscopy. The studies showed that formation of titanium oxide nanotubes with anodising times of 60 and 240 min increases the life of the anode through the provision of a compact coating. The life of the anode which was anodised for 240 min lasted about 20% longer than the sample which had a substrate without any anodised layer.  相似文献   
993.
Yehua Li  Xianwen Wu 《Ionics》2018,24(5):1329-1337
In this paper, the urchin-like NiCo2O4 microspheres assembled by using sodium dodecyl sulfate (SDS) as soft template are successfully fabricated by a facile procedure including microemulsion-solvothermal reaction and subsequent calcination at 400 °C for 4 h. The structure and morphology of synthesized NiCo2O4 particles are investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). It has been clearly revealed that the prepared three-dimensional urchin-like NiCo2O4 microspheres are constituted by one-dimension nanowires. As it is applied to anode for lithium-ion batteries (LIBs), the initial coulombic efficiency is up to 75.7%, and the specific reversible capacity retains up to 1034.2 mAh/g even after 40 cycles at a current density of 100 mA/g. Furthermore, as the current density gradually increases to 800 mA/g, it still delivers the reversible capacity of 895.4 mAh/g. The high reversible specific capacity, perfect cyclability, and rate performance are attributed to the unique urchin-like NiCo2O4 microspheres, which can alleviate the volume expansion and shorten the diffusion path of ions and electrons during lithiation/delithiation process. The self-standing urchin-like NiCo2O4 microspheres may be a very promising candidate in place of the commercial graphite-based anode materials for high-performance LIBs.  相似文献   
994.
Focusing on additive-free electrodes, thin films are of typical interest as electrodes for lithium ion battery application. Herein, we report the fabrication of TiO2 thin films by spray pyrolysis deposition technique. X-ray diffraction and transmission electron microscopic analysis confirms the formation of anatase TiO2. Electrochemical evaluation of these sub-micron TiO2 thin films exhibits high-rate performance and long cycling stability. At 1C rate (1C?=?335 mA/g), the electrode delivered discharge capacity of 247 mAh/g allowing about 0.74 lithium into the structure. The electrodes also delivered specific capacities of 122 and 72 mAh/g at 10 and 30C rates, respectively. Without conductive additives, this excellent performance can be attributed to the nanosize effect of TiO2 particles combined with the uniform porous architecture of the electrode. Upon cycling at high rates (10 and 30C), the electrode exhibited excellent cycling stability and retention, specifically only <?0.6% capacity loss per cycle over 2500 cycles.  相似文献   
995.
Silver ion conducting glass system composed of xAgI–(100???x)[0.444 Ag2SO4–0.555 (0.4TeO2–0.6B2O3)] has been prepared by melt quenching method for x?=?0 to 80 in step of 10. XRD, DSC, FTIR, and SEM were carried out to understand some structural properties of prepared samples. XRD and DSC studies of the samples with x?≤?60 show predominantly glassy nature. Electrical parameters and activation energies of all the samples were evaluated by complex impedance analysis and Arrhenius plots of DC conductivity, respectively. Carrier concentration, mobility, inter-ionic distance, and ionic conductivity of samples were measured and discussed. It is observed that the conductivity varies with increasing the temperature and composition. The highest conductivity (1.8?×?10?1 S cm?1) and ionic current (8.33 μA) is observed for =?50 sample at room temperature; hence, it can be used as best electrolyte material for solid-state battery application.  相似文献   
996.
Zn2SnO4 (ZTO) is a stable semiconductor in ZnO–SnO2 system and important transparent conducting oxide (TCO) predominantly used in optoelectronic devices. ZTO thin films were prepared by RF magnetron sputtering using Zn2SnO4 ceramic target in this paper. The effects of annealing temperatures and oxygen contents on characterization of ZTO thin films were studied. The results show that ZTO thin films prepared by RF magnetron sputtering are amorphous with an optical band gap of 3.22 eV. After annealing at 650°C in Ar atmosphere for 40 min, ZTO films possess a spinel structure with an optical band gap of 3.62 eV. The atomic force microscope (AFM) data of morphology reveals that the surface roughness of films is about 2 nm. The results of energy dispersive spectrometer (EDS) show that the concentration ratio of Zn to Sn is in the range from 1.44 to 1.57. The results of Hall-effect-measurement system reveal that the resistivity of films varies from 102 to 10–1 Ωcm, carrier concentration is about 1017 cm–3, and mobility ranges from 100 to 101 cm2 v–1 s–1.  相似文献   
997.
Based on an improved HR neuron model, the effects of electrical and chemical autapses on the firing activities of single neurons are studied, and the wave propagation in forward feedback neural network is also discussed by considering autapstic regulation under different intensities of electromagnetic induction. It is found that the electrical activities of single neuron can be changed by exerting excitatory or inhibitory of electrical and chemical autapses. With different feedback gains of electromagnetic induction current, membrane potential shows the oscillatory solutions and steady states. Under the condition of different autapse or electromagnetic induction, the propagation of electrical activities caused by the central neuron is transformed in the forward feedback network. Moreover, the spatial synchronization of the network will be changed by choosing different coupling intensities and feedback gains. It is proved that the electrical and chemical autapses play a significant role in firing modes of single neuron and the wave propagation of the forward feedback networks under the electromagnetic induction.  相似文献   
998.
In visual fields composed of dots spatially randomly distributed but moving rigidly, the percept of coherent motion is lost once Dmax is exceeded, resulting in an incoherent, random percept. We have investigated this transition both from a psychophysics perspective and in the development of a dynamic model of the visual system based on a spatially coupled array of nonlinear damped mass-springs cells. We present results of experiments using rigidly moving arrays of dots of different levels of sparseness and differing displacement magnitudes. Results show that the perception of randomness can be reliably judged and displays a transition from coherent to non-coherent motion as the motion amplitude is increased. Using standard psychophysical just noticeable difference (JND) judgements, we noted that the threshold JND was a function of displacement magnitude and sparseness and could not be explained by extant spatiotemporal filtering models. Our model qualitatively explains the important features of the data, reproducing the experimental Dmax and entropy perception effects with increased stimuli motion amplitude at different spatial sparseness levels. We have then performed some numerical simulations of the model when the masses in the array are randomly distributed. Results show that sparseness plays different role if close or far from Dmax in terms of motion coherence discrimination.  相似文献   
999.
We study the dynamics of networks with coupling delay, from which the connectivity changes over time. The synchronization properties are shown to depend on the interplay of three time scales: the internal time scale of the dynamics, the coupling delay along the network links and time scale at which the topology changes. Concentrating on a linearized model, we develop an analytical theory for the stability of a synchronized solution. In two limit cases, the system can be reduced to an “effective” topology: in the fast switching approximation, when the network fluctuations are much faster than the internal time scale and the coupling delay, the effective network topology is the arithmetic mean over the different topologies. In the slow network limit, when the network fluctuation time scale is equal to the coupling delay, the effective adjacency matrix is the geometric mean over the adjacency matrices of the different topologies. In the intermediate regime, the system shows a sensitive dependence on the ratio of time scales, and on the specific topologies, reproduced as well by numerical simulations. Our results are shown to describe the synchronization properties of fluctuating networks of delay-coupled chaotic maps.  相似文献   
1000.
Polarisation of the particle spin can be an important problem for different plasmas. In this article, the contribution of the electron spin on the growth rate of the temperature anisotropy of electromagnetic instabilities has been investigated. Results show that polarisation of the electron spin will restrict the instability growth rate while instability can survive due to the spin-depolarised electrons even when the requested temperature anisotropy is vanished. Instability can reach the damping state exponentially due to the spin-polarised electrons while it can grow linearly due to the spin-depolarised (the semi-classical) electrons.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号