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41.
S. Bhattacharyya S. K. Saha M. Chakravorty B. M. Mandal D. Chakravorty K. Goswami 《Journal of Polymer Science.Polymer Physics》2001,39(16):1935-1941
The frequency‐dependent conductivity of interpenetrating polymer network composites of polypyrrole (PPy) and poly(vinyl acetate) (PVAc) synthesized by FeCl3‐impregnated PVAc films being dipped into solutions of pyrrole in water was investigated over a frequency range of 100 Hz to 2 MHz and a temperature range of 110–300 K. For specimens with a PPy content less than the percolation threshold, the quantum mechanical tunneling of electrons was the conduction mechanism. For specimens with a higher PPy content, correlated barrier hopping of electrons appeared to be operative. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1935–1941, 2001 相似文献
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The synthesis of dibenzoazocine framework through palladium-mediated reductive Mizoroki-Heck cyclization has been described. The procedure is simple, straightforward, and regioselective. 相似文献
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Summary The Hirshfeld population analysis scheme which carves the molecular density into atomic density contributions is tested. This method does not require a reference to basis sets or their respective locations, but is based on a different physical and mathematical footing. The advantage of this method is that, when the molecular deformation density converges to the true solution, the computed net charges will necessarily converge. This method also allows a straightforward definition for local moments. About 36 molecules have been used to compute the conventional Mulliken and Löwdin population analyses with STO3G, 6311G** and Dunning-Hay split valence basis sets. These results have been compared to the estimates provided by the Hirshfeld model. The charges found in the Hirshfeld method are smaller than those from the other methods. 相似文献
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S. Bhattacharyya S. K. Saha D. Chakravorty 《Journal of Polymer Science.Polymer Physics》2000,38(9):1193-1200
Conductivity relaxation spectra of interpenetrating network conducting composites of polypyrrole (PPy) and poly(styrene‐co‐butyl acrylate) (SBA) have been analysed on the basis of coupling model developed by Ngai. The macroscopic activation energy obtained from coupling model using the stretch exponent β compares favourably with the tunnel energy estimated from the overlapping large polaron tunnelling (OLPT) model. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 1193–1200, 2000 相似文献
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A simple and straightforward palladium mediated ligand free bis- and tris-biaryl coupling on an unactivated phenylbenzyl ether system to produce hitherto unreported heterocyclic compound is described. 相似文献
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Rajaram D Burnstein RA Chakravorty A Chan A Chen YC Choong WS Clark K Dukes EC Durandet C Felix J Gidal G Gu P Gustafson HR Ho C Holmstrom T Huang M James C Jenkins CM Kaplan DM Lederman LM Leros N Longo MJ Lopez F Lu LC Luebke W Luk KB Nelson KS Park HK Perroud JP Rubin HA Teng PK Volk J White CG White SL Zyla P 《Physical review letters》2005,94(18):181801
A sensitive search for the lepton-number-violating decay Xi(-)-->pmu(-)mu(-) has been performed using a sample of approximately 10(9) Xi(-) hyperons produced in 800 GeV/c p-Cu collisions. We obtain B(Xi(-)-->pmu(-)mu(-))<4.0x10(-8) at 90% confidence, improving on the best previous limit by 4 orders of magnitude. 相似文献
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Mosley RT Culberson JC Kraker B Feuston BP Sheridan RP Conway JF Forbes JK Chakravorty SJ Kearsley SK 《Journal of chemical information and modeling》2005,45(5):1439-1446
Reagent Selector is an intranet-based tool that aids in the selection of reagents for use in combinatorial library construction. The user selects an appropriate reagent group as a query, for example, primary amines, and further refines it on the basis of various physicochemical properties, resulting in a list of potential reagents. The results of this selection process are, in turn, converted into synthons: the fragments or R-groups that are to be incorporated into the combinatorial library. The Synthon Analysis interface graphically depicts the chemical properties for each synthon as a function of the topological bond distance from the scaffold attachment point. Displayed in this fashion, the user is able to visualize the property space for the universe of synthons as well as that of the synthons selected. Ultimately, the reagent list that embodies the selected synthons is made available to the user for reagent procurement. Application of the approach to a sample reagent list for a G-protein coupled receptor targeted library is described. 相似文献
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