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51.
Koroush Sasan Hamid Reza Khavasi Mehdi D. Davari 《Monatshefte für Chemie / Chemical Monthly》2008,19(5):773-780
N-(2-Pyridylmethyl)-2-pyrazinecarboxamide was prepared and its crystal structure was investigated by X-ray analysis. The compound
crystallizes in the triclinic space group
P[`1]P{\bar 1}
with a = 4.262(3), b = 12.117(9), c = 20.840(18) ?, α = 91.802(6), β = 89.834(7), γ = 91.845(6)°, V = 1075.2(16) ?3, Z = 4, and D = 1.323 Mg/m3. The structure was solved by direct method and refined to R = 0.0699 and wR
2 = 0.1268 by full matrix anisotropic least-squares method. Using the Hartree-Fock and density functional method (B3LYP) with 6-31G(d) basis set, the molecular geometry and vibrational frequencies of the title compound has been investigated
and compared with experimental ones from experimental studies. The optimized bond lengths obtained by RHF method and bond angles obtained by B3LYP method show better agreement with the experimental values. The vibrations computed of the title compound by the RHF and DFT methods are in good agreement with the observed IR spectra data. 相似文献
52.
Koroush Sasan Hamid Reza Khavasi Mehdi D. Davari 《Monatshefte für Chemie / Chemical Monthly》2008,139(7):773-780
N-(2-Pyridylmethyl)-2-pyrazinecarboxamide was prepared and its crystal structure was investigated by X-ray analysis. The compound crystallizes in the triclinic space group \(P{\bar 1}\) with a = 4.262(3), b = 12.117(9), c = 20.840(18) Å, α = 91.802(6), β = 89.834(7), γ = 91.845(6)°, V = 1075.2(16) Å3, Z = 4, and D = 1.323?Mg/m3. The structure was solved by direct method and refined to R = 0.0699 and wR 2 = 0.1268 by full matrix anisotropic least-squares method. Using the Hartree-Fock and density functional method (B3LYP) with 6-31G(d) basis set, the molecular geometry and vibrational frequencies of the title compound has been investigated and compared with experimental ones from experimental studies. The optimized bond lengths obtained by RHF method and bond angles obtained by B3LYP method show better agreement with the experimental values. The vibrations computed of the title compound by the RHF and DFT methods are in good agreement with the observed IR spectra data. 相似文献
53.
If a hexacyclic graph G represents a benzenoid, a perfect matching corresponds to a configuration of π-bonds. We present an algorithm for counting the number of configurations of π-bonds for parallelogram-like benzenoids with parallelogram-like holes by counting descending paths in a corresponding rectangular
mesh with rectangular holes. 相似文献
54.
Sasan?KarimiEmail author Anthony?Delgado Marty?Lewinter 《Journal of mathematical chemistry》2012,50(4):904-913
We recently reported an algorithm to count Kekulé (resonance) structures for convex cyclofusenes using a combinatorial/geometric
approach. Previously, we presented an algorithm for counting resonance structures for parallelogram-like benzenoids with holes
by counting descending paths using rectangular meshes with holes. In this article, we employ a similar combinatorial/geometric
approach to determine algorithms that will facilitate counting of the resonance structures in parallelogram-like benzenoids
with no holes. 相似文献