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61.
Temporary threshold shift in bottlenose dolphins (Tursiops truncatus) exposed to mid-frequency tones
Finneran JJ Carder DA Schlundt CE Ridgway SH 《The Journal of the Acoustical Society of America》2005,118(4):2696-2705
A behavioral response paradigm was used to measure hearing thresholds in bottlenose dolphins before and after exposure to 3 kHz tones with sound exposure levels (SELs) from 100 to 203 dB re 1 microPa2 s. Experiments were conducted in a relatively quiet pool with ambient noise levels below 55 dB re 1 microPa2/Hz at frequencies above 1 kHz. Experiments 1 and 2 featured 1-s exposures with hearing tested at 4.5 and 3 kHz, respectively. Experiment 3 featured 2-, 4-, and 8-s exposures with hearing tested at 4.5 kHz. For experiment 2, there were no significant differences between control and exposure sessions. For experiments 1 and 3, exposures with SEL=197 dB re 1 microPa2 s and SEL > or = 195 dB re 1 microPa2 s, respectively, resulted in significantly higher TTS4 than control sessions. For experiment 3 at SEL= 195 dB re 1 microPa2 s, the mean TTS4 was 2.8 dB. These data are consistent with prior studies of TTS in dolphins exposed to pure tones and octave band noise and suggest that a SEL of 195 dB re 1 microPa2 s is a reasonable threshold for the onset of TTS in dolphins and white whales exposed to midfrequency tones. 相似文献
62.
From the stem bark of Albizzia julibrissin DURAZZ (Leguminosae), two new phenolic glycosides (albibrissinosides A and B) were isolated. Their structures were determined by spectroscopic analysis. The albibrissinoside B was found to be a radical scavenger on the 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical. 相似文献
63.
Barlow SM Louafi S Le Roux D Williams J Muryn C Haq S Raval R 《Langmuir : the ACS journal of surfaces and colloids》2004,20(17):7171-7176
The bonding and self-assembly of a chirally organized monolayer of alanine on the Cu(110) surface has been investigated using reflection-absorption infrared spectroscopy, low-energy electron diffraction (LEED), and scanning tunneling microscopy (STM). This multitechnique approach has enabled an in-depth understanding of the hierarchy of chirality transfer: from a single adsorbed molecule, to size-defined chiral clusters, and then to an overall chiral assembly. The data have indicated that the alanine is in its anionic form, bound to the copper surface through the oxygens of the ionized carboxylate group and the nitrogen of the neutral amino group. Importantly, the methyl group is held away from the surface, resulting in direct chirality transfer into the footprint of the adsorbed alanine molecules, with the local adsorption motif for S-alanine being the mirror image of that created for R-alanine. STM has shown that S-alanine molecules self-organize to form size-defined chiral clusters of six or eight molecules at the surface, interspersed with chiral channels of bare metal. Together, these clusters and channels further self-assemble into a chiral array with one unique chiral domain sustained across the entire surface. A similar chiral assembly, but with the mirror organization, has been observed for R-alanine. Structural models for the individual clusters are proposed, and in conjunction with LEED data, overall models for these chiral phases of both S- and R-alanine have been constructed. Overall, this adsorption system has been found to be both strongly chemisorbed and capable of extensive intermolecular H-bonding, causing stresses that lead not only to the chiral self-organization of molecules but also to a specific self-organization of the empty chiral channels and spaces that intersperse the structure which, in turn, chirally assemble across macroscopic length scales to give a surface with global organizational chirality. 相似文献
64.
Quantum adiabatic pumping of charge and spin between two reservoirs (leads) has recently been demonstrated in nanoscale electronic devices. Pumping occurs when system parameters are varied in a cyclic manner and sufficiently slowly that the quantum system always remains in its ground state. We show that quantum pumping has a natural geometric representation in terms of gauge fields (both Abelian and non-Abelian) defined on the space of system parameters. Tunneling from a scanning tunneling microscope tip through a magnetic atom could be used to demonstrate the non-Abelian character of the gauge field. 相似文献
65.
Pan Y Huang N Cho S MacKerell AD 《Journal of chemical information and computer sciences》2003,43(1):267-272
Virtual database screening allows for millions of chemical compounds to be computationally selected based on structural complimentary to known inhibitors or to a target binding site on a biological macromolecule. Compound selection in virtual database screening when targeting a biological macromolecule is typically based on the interaction energy between the chemical compound and the target macromolecule. In the present study it is shown that this approach is biased toward the selection of high molecular weight compounds due to the contribution of the compound size to the energy score. To account for molecular weight during energy based screening, we propose normalization strategies based on the total number of heavy atoms in the chemical compounds being screened. This approach is computationally efficient and produces molecular weight distributions of selected compounds that can be selected to be (1) lower than that of the original database used in the virtual screening, which may be desirable for selection of leadlike compounds or (2) similar to that of the original database, which may be desirable for the selection of drug-like compounds. By eliminating the bias in target-based database screening toward higher molecular weight compounds it is anticipated that the proposed procedure will enhance the success rate of computer-aided drug design. 相似文献
66.
A new, conceptually simple model of crystal packing is proposed which uses "packing patterns" to describe unit cells in terms of molecular building blocks. 相似文献
67.
de Visser SP Ogliaro F Shaik S 《Angewandte Chemie (International ed. in English)》2001,40(15):2871-2874
68.
Francis Jordan Sam B. Nadler Jr. 《Proceedings of the American Mathematical Society》2001,129(4):1219-1228
It is shown that a continuum that is an space in the sense of Michael must be hereditarily decomposable. This improves known results, thereby providing more evidence that such continua must be dendrites.
69.
The identification of tyre induced vehicle interior noise 总被引:2,自引:0,他引:2
Sound transmission into a vehicle is classified as either airborne or structure borne sound. From the point view of noise control, the reduction of noise transferred by different paths requires different solutions. Coherence function analysis is often used to identify transmission paths. However it can be difficult to separate the airborne from structure borne components. The principle of acoustic reciprocity offers a convenient method for overcoming this difficulty. The principal states that the transfer function between an acoustic volume velocity source and an acoustic receiver is independent of a reversal of the position of source and receiver. The work done on this study involves exciting a stationary tyre and measuring the surface velocity of the tyre at a number of discrete points. The acoustic transfer functions between each point on the tyre and a receiver point are measured reciprocally. Two sets of measurements are then combined to yield a measure of the sound pressure due to a point force on the tyre via the acoustic transmission path only. This technique also provides information on the relative contributions of various regions of the tyre wall to the resultant noise. Also the sound radiation characteristics, the horn effect, and resonance at the wheel housing are identified through the reciprocal measurement. 相似文献
70.