Electrical and optical properties of silver doped indium oxide thin films prepared by reactive DC magnetron sputtering

Silver doped indium oxide (In_2−x Ag_x O_3−y) thin films have been prepared on glass and silicon substrates at room temperature (300 K) by reactive DC magnetron sputtering technique using an alloy target of pure indium and silver (80: 20 atomic %. The magnetron power (and hence the metal atom sputter flux) is varied in the range 40-80 W. The energy dispersive analysis of X-ray (EDAX) results show that the silver content in the film decreases with increasing magnetron power. The grain size of these films is of the order of 100 nm. The resistivity of these films is in the range 10⁻²-10⁻³ Ω cm. The work function of the silver-indium oxide films (by Kelvin Probe) are in the range: 4.64-4.55 eV. The refractive index of these films (at 632.8 nm) varies in the range: 1.141-1.195. The optical band gap of indium oxide (3.75 eV) shrinks with silver doping. Calculations of the partial ionic charge (by Sanderson's theory) show that silver doping in indium oxide thin films enhance the ionicity.     

无限横观各向同性弹性圆柱中刚性圆盘的扭转振动

分析了无限横观各向同性弹性圆柱中，刚性圆盘的扭转振动问题．绘制的图形显示了材料的各向异性性质对应力强度因子的影响．     

Analysis for optimal pattern synthesis of time modulated concentric circular antenna array using memetic firefly algorithm

In this paper the optimal performance of time modulated nine-ring concentric circular antenna array with isotropic elements has been studied based on an evolutionary optimization algorithm hybridized with local heuristic search called memetic firefly algorithm (MFA). The firefly algorithm has been applied followed by Nelder–Mead simplex method for the local heuristic search to achieve the optimal fine tuning. Other algorithms like real coded genetic algorithm (RGA) and particle swarm optimization (PSO) have been used for the comparison purpose. The comparisons among the algorithms have been made with two case studies as Case-1 and Case-2, and with two different fitness functions \((f_{{ fitness}1}, f_{{ fitness}2})\) and three control parameters like inter-element uniform/non-uniform spacing in rings, inter-ring radii and the switching-on times of rings. The simulation results show that the MFA outperforms RGA and PSO for both the cases Case-1, Case-2 and \(f_{{ fitness}1}\), \(f_{{ fitness}2}\), respectively with respect to better side lobe level (SLL). The fitness function \(f_{{ fitness}2}\) is better than the \(f_{{ fitness}1}\) with respect to sideband level. Apart from this, powers radiated at the centre/fundamental frequency and the first two sideband frequencies, and dynamic efficiency have been computed. It is found that power radiated by any sideband frequency is much less as compared to the power radiated at the centre frequency. It has been observed that as the sideband frequency increases, SBL decreases to the greater extent as compared to SLL. As per authors’ knowledge there is a little research contribution by any other previous researcher regarding numerical computation of radiation characteristics as SBLs, powers radiated at the fundamental frequency and its two sideband frequencies, directivity, and dynamic efficiency for time-modulated CCAA.     

Synthesis,characterization and magnetostructural correlation studies on three binuclear copper complexes of pyrimidine derived Schiff base ligands

Three binuclear Cu(II) complexes of two pyrimidine derived Schiff base ligands, 2-S-methyl-6-methyl-4-formyl pyrimidine-N(4)-ethyl thiosemicarbazone (HL₁) and salicyl hydrazone of 2-hydrazino-4,6-dimethylpyrimidine (HL₂), have been prepared. HL₁ produces a bis(μ-thiolato) Cu(II) complex co-crystallizing with its mononuclear analog, [Cu₂(L₁)₂(NO₃)₂][Cu(L₁)(NO₃)] (1). On the other hand HL₂ shows versatility by producing two different classes of binuclear Cu(II) complexes, a bis(μ-phenoxo) complex [Cu₂(L₂)₂(NO₃)₂] (2) and another a (μ-4,4′-bipyridyl) complex, [Cu₂(L₂)₂(μ-4,4′-bipyridyl)(NO₃)₂] (3) under suitable conditions. All the three complexes show distorted square pyramidal geometry around each Cu atom but to a varied extent. Magnetic behavior of complex 1 shows that it is strongly ferromagnetic in nature whereas compounds 2 and 3 are weakly antiferromagnetic in nature. A magnetostructural correlation study combined with molecular modelling on complexes 1 and 2 has thrown light on the difference on magnetic interaction between the Cu atoms in these two complexes. Various factors that may be responsible for such differences are also explored. A novel and potentially useful pH dependant conversion of 3 to 2 has also been noticed.     

Modulation of fluorescence emission of 1-(2-pyridyl) pyrazole derived Schiff base ligands by exploiting their metal ion sensitive binding modes

Dioxomolybdenum(VI) complexes [MoO₂(B¹)H₂O] (1), [MoO₂(B²)EtOH] (2), [MoO₂(B³)EtOH] (3) and [MoO₂(B⁴)EtOH] (4) were synthesized using the Schiff base ligands H₂B¹(previously reported), H₂B², H₂B³ and H₂B⁴, respectively. These ligands were prepared by condensation of 1-(2-pyridyl) 5-methyl 3-pyrazole carbohydrazide with salicylaldehyde, o-hydroxy acetophenone, 5-bromo salicylaldehyde and 5-nitro salicylaldehyde respectively. Due to the presence of a substituted 1-(2-pyridyl) pyrazole unit, ligands H₂B¹, H₂B² and H₂B³ exhibit fluorescent emissions, and the most intense emission was obtained for H₂B³. H₂B⁴ is incapable of showing fluorescence emission. As the ligands are capable of using different binding modes, according to the demands of the guest metal ions, their emission properties also change accordingly. The dioxomolybdenum(VI) complex of the ligand H₂B¹, i.e. complex 1, shows quenched emission compared to H₂B¹. Again when Cu²⁺, Co²⁺ or Ni²⁺ ions are added to a solution of 1, in each case a new complex of Cu²⁺ Co²⁺ or Ni²⁺ is formed in solution and further quenching was observed. However, with Zn²⁺ input to a solution of 1, fluorescence recovery was observed up to the level of the free ligand. The copper(II) complex of H₂B¹ (complex 5), produced by adding equivalent amount of Cu²⁺ salt to a solution of 1, was isolated and characterized. One of the dioxomolybdenum(VI) complexes, 3, when subjected to an oxo-transfer reaction with PPh₃ produces complex [MoO(B³)CH₃CN] (6). Complex 6 shows reduced fluorescence emissions compared to 3 in the solid phase. These observations open up the possibilities for these ligands to work as fluorescent signaling system with different metal ion inputs. All the complexes are characterized by elemental analyses, electronic spectra, IR, ¹H NMR, magnetic measurements, EPR and by cyclic voltammetry. Complexes 1 and 5, as well as the ligands H₂B² and H₂B³, have been crystallographically characterized.     

Octet baryons in the independent-quark-model approach based on the dirac equation with a power-law potential

Several properties of octet baryons such as (i) the magnetic moment, (ii) (G_A/G_v)_n for neutron β-decay and (iii) the charge radius of the proton have been calculated in a simple independent-quark model under the assumption that the individual constituent quarks are confined, in first approximation, by a relativistic power-law potential V_q(r)=(1+β)(a^v+1r^v+V₀) with a, v>0. In view of the simplicity of the model, the results obtained are quite encouraging.     

A non-coulombic effective power-law potential for the heavy quarkoniums

An effective power-law potential of the form V(r) = 6.08 r^0.106?6.41 is found to describe satisfactorily the gross features of the mass spectra and the leptonic width ratios of the c$\text{c}$ and b$\text{b}$ systems in a flavour-independent manner.     

Magnetic moments of octet baryons in a chiral potential model

Incorporating the lowest-order pionic correction, the magnetic moments of the nucleon octet have been calculated in a chiral potential model. The potential, representing phenomenologically the nonperturbative gluon interactions including gluon self-couplings, is chosen with equally mixed scalar and vector parts in a power-law form. The results are in reasonable agreement with experiment.     

Anharmonic quantum contribution to vibrational dephasing

Based on a quantum Langevin equation and its corresponding Hamiltonian within a c-number formalism we calculate the vibrational dephasing rate of a cubic oscillator. It is shown that leading order quantum correction due to anharmonicity of the potential makes a significant contribution to the rate and the frequency shift. We compare our theoretical estimates with those obtained from experiments for small diatomics N(2), O(2), and CO.     

X-ray structures of iron(III) and cobalt(III) complexes containing 2-<Emphasis Type="Italic">S</Emphasis>-methyl-6-methyl-4-formylpyrimidine-<Emphasis Type="Italic">N</Emphasis>(4)-ethylthiosemicarbazone

Iron(III) and cobalt(III) complexes of types [Fe(LEt)₂]ClO₄·3/2C₆H₆ (1) and [Co(LEt)₂]ClO₄·2CH₂Cl₂ (2) with a new pyrimidine-derived thiosemicarbazone ligand, 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethylt-hiosemicarbazone (HLEt), having N, N, S donor centers have been synthesized and characterized by X-ray crystallography. The structural study shows distorted octahedral geometry for both 1 and 2 with MN₄S₂ chromophores. The space group of 1 is C2/c (monoclinic) and that of 2 is P2₁2₁2₁ (orthorhombic). The electrochemical electron transfer study in MeCN solutions shows a one-electron reductive response presumably due to a metal(III)–metal(II) couple.