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91.
Mehta VP Sharma Ak Modha SG Sharma S Meganathan T Parmar VS Van der Eycken E 《The Journal of organic chemistry》2011,76(8):2920-2925
The N-heterocyclic carbene catalyzed chemoselective C3-aroylation of 3,5-dichloro-2(1H)-pyrazinones with various aldehydes is reported. We herein describe results of this remarkable mild and efficient procedure. 相似文献
92.
Sachin Rawalekar Sreejith Kaniyankandy Sandeep Verma Dr. Hirendra N. Ghosh 《Chemphyschem》2011,12(9):1729-1735
Herein, we report the synthesis of aqueous CdTe/CdSe type‐II core–shell quantum dots (QDs) in which 3‐mercaptopropionic acid is used as the capping agent. The CdTe QDs and CdTe/CdSe core–shell QDs are characterized by X‐ray diffraction (XRD), high‐resolution transmission electron microscopy (HR‐TEM), steady‐state absorption, and emission spectroscopy. A red shift in the steady‐state absorption and emission bands is observed with increasing CdSe shell thickness over CdTe QDs. The XRD pattern indicates that the peaks are shifted to higher angles after growth of the CdSe shell on the CdTe QDs. HR‐TEM images of both CdTe and CdTe/CdSe QDs indicate that the particles are spherical, with a good shape homogeneity, and that the particle size increases by about 2 nm after shell formation. In the time‐resolved emission studies, we observe that the average emission lifetime (τav) increases to 23.5 ns for CdTe/CdSe (for the thickest shell) as compared to CdTe QDs (τav=12 ns). The twofold increment in the average emission lifetime indicates an efficient charge separation in type‐II CdTe/CdSe core–shell QDs. Transient absorption studies suggest that both the carrier cooling and the charge‐transfer dynamics are affected by the presence of traps in the CdTe QDs and CdTe/CdSe core–shell QDs. Carrier quenching experiments indicate that hole traps strongly affect the carrier cooling dynamics in CdTe/CdSe core–shell QDs. 相似文献
93.
We demonstrate a photoactivated surface coupling scheme for achieving spatial overlap between biomolecules of interest and optical near field excitation. Using aluminium nanoapertures, we obtained increased coupling efficiency of biotinylated capture probe oligos to the photoactivated surface due to ~3× nanoaperture enhancement of UV light. We further validate DNA sensor functionality via the hybridization of Cy-5 labeled target oligos, with up to 8× fluorescence enhancement obtained from a commercial microarray scanner. This generic photoimmobilization strategy is an essential step to realizing miniaturized plasmon enhanced detection arrays by virtue of localizing capture molecules to the region of plasmonic enhancement. 相似文献
94.
Navdeep Goyal 《Pramana》1993,40(2):97-105
In this paper we report the electrical and photoelectrical properties of AgInSe2. Nyquist plots for AgInSe2, obtained at different temperatures, are perfect arcs of a semicircle with their centres lying below the abscissa at an angleα. Finite values ofα (the distribution parameter) clearly indicate a multirelaxation behaviour. Transient and steady state photoconductivity of
AgInSe2 has been studied at different temperatures and illumination levels. The lnI
ph vs lnF curves at different temperatures follow the empirical relation:I
ph ∝F
γ. Values of γ are close to 0.5 at all the temperatures, suggesting a bimolecular recombination. Decay of the photocurrent,
when the illumination is switched off, shows that during decay, photocurrent has two components, i.e. a fast decay in the
beginning and a slow decay thereafter. Decay time constant for slow decay process decreases with increasing temperature, suggesting
that recombination is a thermally activated process in the temperature range studied. 相似文献
95.
S. K. Goyal D. Morin F. Nebebe 《The Journal of the Operational Research Society》1992,43(12):1173-1178
A new type of replenishment policy is suggested for an inventory item having a finite shortage cost and linear trend in demand over a finite time horizon. The optimal solution of the suggested replenishment policy has a lower total cost as compared with the optimal solution for the traditional replenishment policies. 相似文献
96.
97.
We report a combined use of small-angle neutron scattering (SANS) and small-angle X-ray scattering (SAXS) to the study of
counterion condensation in ionic micelles. Small-angle neutron and X-ray scattering measurements have been carried out on
two surfactants cetyltrimethylammonium bromide (CTABr) and cetyltrimethylammonium chloride (CTACl), which are similar but
having different counterions. SANS measurements show that CTABr surfactant forms much larger micelles than CTACl. This is
explained in terms of higher condensation of Br− counterions than Cl− counterions. SAXS data on these systems suggest that the Br− counterions are condensed around the micelles over smaller thickness than those of Cl− counterions. 相似文献
98.
This communication points out a couple of early publications on the power-of-two scheduling scheme that has been consistently ignored by researchers in the past. 相似文献
99.
Balaji V. S. Iyer Sachin Shanbhag Vinay A. Juvekar Ashish K. Lele 《Journal of Polymer Science.Polymer Physics》2008,46(21):2370-2379
In a topologically constraining environment the size of a flexible nonconcatenated ring polymer (macrocycles) and its dynamics are known to differ from that of linear polymers. Hence, the diffusion coefficient of ring polymers can be expected to be different from linear chains. We present here scaling arguments for the concentration and molecular weight dependence of self‐diffusion coefficient of ring polymers in semidilute solutions, and show that contrary to expectations these scaling relations are identical to what is known for linear polymers. At higher concentrations excluded volume interactions arising from possibilities of segmental overlap can become effective for large ring polymers. In this regime the diffusion coefficient of large ring polymers shows a relatively weaker dependence on concentration and molecular weight. ©2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 2370–2379, 2008 相似文献
100.
This paper deals with the problem of determining economic maintenance frequency for a group of machines. The operating cost for each machine is assumed to increase with time since the last maintenance work carried out on the machine. The cost of carrying out maintenance work is known and assumed constant. A fixed cost is incurred whenever maintenance work is carried out, and this fixed cost is assumed to be independent of the number of machines on which maintenance work is carried out. The total cost of the system is given by the sum of maintenance and operating costs for all the machines. A heuristic method is proposed for determining the economic maintenance frequency of each machine. An example is given to illustrate the method. 相似文献