Study on the Tautomerism of an Indoline Spiropyran in Compressed CO_2 and Ethanol Mixture

Thesolubilityofcompressedgasesinliquidscanbeveryhigh,whichresultsintheexpansionoftheliquids.Thes0lubilitiesofsolutesinliquidscanbereducedconsiderablybydissolutionofthegases'i.e.,thegasesactasantisolvents.Recently,somecompressedgaseshavebeenusedinmanygasantisolventpr0cesses.Understandingofthepropertiesofthecompressedgas-liquidmixtUresisofgreatimportancetoboththeoreticalstUdyandindustrialprocesses.ThetautomerismofspiropyransandtheirderivativeshasbeenstUdiedbydifferentauthors"',whichindicatedth…     

Application of Small-World Measures to Multichannel Event-Related Potential Activity during Generation of Global and Local Imagery

The Small world model has been successfully used to explore the abnormal pattern of brain information processing in some neuropsychiatric diseases, but not engaged in the study of cognitive functions. We apply the small-world measures： the clustering coefficient and average path length, to evaluate multi-channel event-related potential activity during the generation of global and local imagery. Results show that the brain functional networks of the global and local imagery generation are both small-world ones. In addition, the local imagery generation has a larger clustering coefficient, while the global imagery generation has a shorter average path length. These results support the global precedence in the global-local imagery generation, and reflect the different processing modes in which global imagery emphasizes particularly on global integration, while local imagery on local specialization. Our results indicate that small-world measures could be applied to quantify the difference of brain activities in different cognitive tasks, and further provide some explanations for cognitive behavior.     

相位调制边带失衡问题研究

 高功率激光系统中一般利用相位调制器对单纵模激光进行频谱展宽以避免受激布里渊散射，当后继系统中的滤波器存在中心波长偏差时，则会导致相位调制产生的边带失衡，使光信号出现较为严重的高频起伏。基于前端系统模拟平台对此问题进行了数值模拟研究，结果表明滤波后的高频起伏随滤波器带宽变窄和中心波长偏差增大而加剧。分析表明0.2 nm带宽的滤波器出现0.05 nm左右的波长偏差时，将引起24.3%左右的顶部起伏。实验中根据分析将滤波器带宽从0.2 nm加大到0.4 nm，成功将脉冲顶部起伏从25.2%减小到了4.4%，对前端系统的研制起到了很好的指导作用。     

正烷基单胺对层状甘氨酸-N，N-双甲基膦酸锆的插层

The layered zirconium glycine-N,N-dimethylphosphonate (ZGDMP) was prepared and the intercalation behavior of n-alkylmonoamines was investigated. The X-ray diffraction powder patterns demonstrated that the n-alkylmonoamines were taken up in one step and there were no other intermediate phases. The interlayer distance correlated with the number of carbon atoms of the n-alkylmonoamine chains. The n-alkylmonoamines were intercalated into ZGDMP in such a way that the protons of the interlayer -CO₂H groups were replaced by the terminal -NH₃⁺ of the protonated n-alkylmonoamines. The intercalated n-alkylmonoamines were released from the lamellar ZGDMP at temperature of 150 to 250 ℃.     

静电纺丝方法制备a2-K8 P2W17 MnO61纳米纤维

运用高压静电纺丝和程序升温焙烧的方法制备了a2-K8P2W17MnO61纳米纤维．通过红外光谱（FT-IR）和X射线粉末衍射（XRD）对纤维进行了表征．结果表明，制备的纳米纤维为纯杂多酸盐a2—K8P2W17MnO61,扫描电子显微镜（SEM）图形显示焙烧后获得纳米纤维的平均直径大约为140nm。     

Immunogenicity and Efficacy of Liposome-encapsulated Influenza Split Vaccine in BALB/c Mice

The cellular immunity of current influenza split vaccine is relatively low. It is necessary to develop a novel vaccine to improve the cellular immunity. Thes of this study prepared liposome-encapsulated influenza split vaccine and tested it in BALB/c mice. The mice were immunized once with 4 μg of haemagglutinin of monovalent A/New Caledonia/20/99(H1N1) encapsulated with liposomes or the split virus vaccine only through intrastomach injection. In a comparative study, it was observed that the liposome-encapsulated vaccine elicited a higher neutralizing antibody response, more effectively stimulated spleen cell proliferation, increased cell subsets like CD4 and CD4 /CD8 , and triggered IL-4 and IFN-γ production.     

Organophosphonotungstic HPA of Keggin Type with Sulfo,Taurine and Glycine Substituted Ethylphosphonic Acids as the Coordinate Center

Recent years, heteropoly acids (HPA)and their derivatives have received current attention due to their potential applications in analytical chemistry, catalysis, material sciences and medicine1-2. Usually, the core or coordinate center for most of the heteropoly compounds (HPC) are inorganic acids such as H3PO4, H3SiO3 etc. Although HPC with organophosphonic acids as coordinate center have been confirmed about 15 years ago, in which the molar ratio x: m for most of the heteropoly anion…     

数值模拟自然对流对直拉单晶硅的影响

在直拉单晶硅生长的过程中,自然对流对晶体界面的形状、温度场及应力分布影响很大。本文采用二维模型对熔体内自然对流对单晶硅的影响作了数值模拟,在低雷诺数时采用层流模型,高雷诺数时采用紊流模型,Gr的变化范围从3×106到3×1010,这样涵盖了从小尺寸到大尺寸的直拉单晶硅生长系统。数值结果表明熔体的流动状态不仅与熔体的Gr有关,还与熔体高度和坩埚半径的比值密切相关。当Gr>108时,熔体内确实存在紊流现象,层流模型不再适合,随着Gr的增大,紊流现象加剧,轴心处的等温线变得更为陡峭,不利于晶体生长。     

用于ICF的新型单色退偏器

 设计了一种三元结构的双折射型退偏器,将两个这样的退偏器组合使用（两退偏器光轴成45°）对单色线偏光进行退偏,无论是用洛匈棱镜和红外感光卡对退偏效果进行观察,还是用偏振分析仪对退偏光束进行偏振分析,所得的结果表明退偏效果很好,且退偏效果对入射线偏光的偏振方向不敏感。