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101.
This paper presents an analytical approach using higher order plate theories to determine wave reflections from and transmissions through a damaged region in a beam. The damaged region is either treated as two split beams or as an inhomogeneity. The reflection ratios and transmission ratios are found to depend strongly on the frequency of the incident flexural waves, as well as the size of the damage, which gives rise to strong stop/pass band behaviour. Using the spectral analysis method, the transient wave propagation in a beam with a part-through delamination is predicted and compared with experimental results, indicating a good agreement in the phases and amplitudes of both the reflected and transmitted waves. 相似文献
102.
Ulrich Rose 《Journal of heterocyclic chemistry》1992,29(2):551-557
In the course of investigations on structure-activity relationships of calcium antagonists analogous to fostedil, a series of 2-aryl- and 2-arylvinyl-substituted 1,3-henzothiazoles and 1,3-benzoxazoles bearing a phosphonate group on the phenyl ring has been synthesized by cyclization, bromination, and subsequent Michaelis-Arbuzow reaction. Pharmacological investigations on isolated organs from guinea pigs revealed both negative inotropic effects and a relaxing action on smooth musculature; these activities were particularly pronounced in the 1,3-benzothiazole compound group. 相似文献
103.
The propagation of perturbations on a spatially flat Robertson-Walker background is studied within linear perturbation theory in deDonder gauge and for comparison in synchronous gauge. The metric perturbations should be determined uniquely by the density/pressure perturbations, therefore only two initial conditions, namely for the density contrast and its time derivative, should be needed. Since the number of fundamental solutions for the density perturbations is higher than 2 in both gauges (6 resp. 3) an additional reduction of possible initial conditions, resp. a physically motivated exclusion of solutions, is needed. It is shown that the common treatment of excluding the so-called gauge solutions (solutions which can be gauged to zero in an already chosen gauge) leads to unphysical results. If gauge solutions are excluded the density perturbation solutions are the same in both gauges. But the correct Newtonian limit — which is present in deDonder gauge but not in synchronous gauge — is bound to the differences in the two gauges for large spatial scales of perturbations. Furthermore, compressional wave solutions should vanish for infinite spatial scales of perturbations (isotropy), but this is guaranteed in deDonder gauge by gauge solutions again. Gauge solutions should therefore not be taken as unphysical. 相似文献
104.
Assumpta C Nwanya Daniel Obi Rose U. Osuji R. Bucher Malik Maaza Fabian I. Ezema 《Journal of Solid State Electrochemistry》2017,21(9):2567-2576
We used a simple chemical synthesis route to deposit nanorod-like cobalt oxide thin films on different substrates such as stainless steel (ss), indium tin oxide (ITO), and microscopic glass slides. The morphology of the films show that the films were uniformly spread having a nanorod-like structure with the length of the nanorods shortened on ss substrates. The electrochemical properties of the films deposited at different time intervals were studied using cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). The film deposited after 20 cycles on ss gave the highest specific capacity of 67.6 mAh g?1 and volumetric capacity of 123 mAh cm?3 at a scan rate 5 mV s?1 in comparison to 62.0 mAh g?1 and 113 mAh cm?3 obtained, respectively, for its counterpart on ITO. The film electrode deposited after 20 cycles on ITO gave the best rate capability and excellent cyclability with no depreciation after 2000 charge–discharge cycles. 相似文献
105.
A strain-optic law for a certain class of birefringent fiber-reinforced composite materials is developed. The strain-optic law requires both mechanical and optical characterization of the material. Previous investigations have hypothesized the existence of three independent optical properties for the anisotropic birefringent material. The strain-optic relation developed in this study, however, requires only a single strain-optic coefficient, coupled with four independent mechanical material properties, for prediction of the optical response of a birefringent anisotropic material. Experimental results are presented which show good agreement with the developed strain-optic relation. Finally, the isoclinic parameter is investigated and preliminary evidence is presented which indicates a correspondence between principal-strain direction and optical isoclinic angle. 相似文献
106.
Experimental techniques are developed to study and measure the shear-wave velocity in an aluminum cylindrical shell subjected to a radial impact. The radial impact is obtained by exploding an electrical detonator inserted in plastic plugs mounted on the end of the shell. Strain gages, mounted on the outside surface of the shell at various axial locations, are used to obtain oscilloscope traces from which the shear-wave velocity can be calculated. 相似文献
107.
Planar chiral arenetricarbonylchromium complexes have been intensively investigated and they have been applied as valuable building blocks for asymmetric synthesis and as ligands for asymmetric catalysis. In contrast, in the field of the isoelectronic cationic [(η(6)-arene)Mn(CO)(3)](+) complexes, until these last 10 years, very few studies were published involving nonracemic planar chiral cationic complexes and their potential applications, certainly because of the difficult access to enantiopure starting material. In 2009, however, the discovery of the first resolution of such compounds opened a new area for their application in the field of organic as well as of organometallic enantioselective syntheses. We felt it important to write a review on this subject to give an up-to-date summary of the methodologies used to prepare enantiomerically pure planar chiral neutral [(η(5)-cyclohexadienyl)Mn(CO)(3)] and cationic [(η(6)-arene)Mn(CO)(3)](+) complexes as well as their potential in enantioselective synthesis. 相似文献
108.
Here we report the syntheses and crystal structures of a series of cobalt(II) and nickel(II) complexes derived from (R)NP2 ligands (where R = OMe(Bz), H(Bz), Br(Bz), Ph) bearing ethylene linkers between a single N and two P donors. The Co(II) complexes generally adopt a tetrahedral configuration of general formula [(NP2)Co(I)(2)], wherein the two phosphorus donors are bound to the metal center but the central N-donor remains unbound. We have found one case of structural isomerism within a single crystal structure. The Co(II) complex derived from (Bz)NP2 displays dual coordination modes: one in the tetrahedral complex [((Bz)NP2)Co(I)(2)]; and the other in a square pyramidal variant, [((Bz)NP2)Co(I)(2)]. In contrast, the Ni(II) complexes adopt a square planar geometry in which the P(Et)N(Et)P donors in the ligand backbone are coordinated to the metal center, resulting in cationic species of formula [((R)NP2)Ni(I)](+) with iodide as counterion. All Ni(II) complexes exhibit sharp (1)H and (31)P spectra in the diamagnetic region. The Co(II) complexes are high-spin (S = 3/2) in the solid state as determined by SQUID measurements from 4 to 300 K. Solution electron paramagnetic resonance (EPR) experiments reveal a high-spin/low-spin Co(II) equilibrium that is dependent on solvent and ligand substituent. 相似文献
109.
Rose RA Greaves SJ Oliver TA Clark IP Greetham GM Parker AW Towrie M Orr-Ewing AJ 《The Journal of chemical physics》2011,134(24):244503
The dynamics of reactions of CN radicals with cyclohexane, d(12)-cyclohexane, and tetramethylsilane have been studied in solutions of chloroform, dichloromethane, and the deuterated variants of these solvents using ultraviolet photolysis of ICN to initiate a reaction. The H(D)-atom abstraction reactions produce HCN (DCN) that is probed in absorption with sub-picosecond time resolution using ~500 cm(-1) bandwidth infrared (IR) pulses in the spectral regions corresponding to C-H (or C-D) and C≡N stretching mode fundamental and hot bands. Equivalent IR spectra were obtained for the reactions of CN radicals with the pure solvents. In all cases, the reaction products are formed at early times with a strong propensity for vibrational excitation of the C-H (or C-D) stretching (v(3)) and H-C-N (D-C-N) bending (v(2)) modes, and for DCN products there is also evidence of vibrational excitation of the v(1) mode, which involves stretching of the C≡N bond. The vibrationally excited products relax to the ground vibrational level of HCN (DCN) with time constants of ~130-270 ps (depending on molecule and solvent), and the majority of the HCN (DCN) in this ground level is formed by vibrational relaxation, instead of directly from the chemical reaction. The time-dependence of reactive production of HCN (DCN) and vibrational relaxation is analysed using a vibrationally quantum-state specific kinetic model. The experimental outcomes are indicative of dynamics of exothermic reactions over an energy surface with an early transition state. Although the presence of the chlorinated solvent may reduce the extent of vibrational excitation of the nascent products, the early-time chemical reaction dynamics in these liquid solvents are deduced to be very similar to those for isolated collisions in the gas phase. The transient IR spectra show additional spectroscopic absorption features centered at 2037 cm(-1) and 2065 cm(-1) (in CHCl(3)) that are assigned, respectively, to CN-solvent complexes and recombination of I atoms with CN radicals to form INC molecules. These products build up rapidly, with respective time constants of 8-26 and 11-22 ps. A further, slower rise in the INC absorption signal (with time constant >500 ps) is attributed to diffusive recombination after escape from the initial solvent cage and accounts for more than 2/3 of the observed INC. 相似文献
110.
Yun JH Ng YH Huang S Conibeer G Amal R 《Chemical communications (Cambridge, England)》2011,47(40):11288-11290
The CuInS(2) (CIS) nanoparticles were wrapped uniformly throughout the inner and outer walls of TNTs (TNT) by using square wave pulsed-electrodeposition. This structure enables the CuInS(2)-TiO(2) (CIS-TNT) to exhibit p-n junction diode behavior and enhanced photoelectrochemical properties. 相似文献