全文获取类型
收费全文 | 544902篇 |
免费 | 4590篇 |
国内免费 | 1202篇 |
专业分类
化学 | 258678篇 |
晶体学 | 8330篇 |
力学 | 29666篇 |
综合类 | 10篇 |
数学 | 75805篇 |
物理学 | 178205篇 |
出版年
2021年 | 5074篇 |
2020年 | 5401篇 |
2019年 | 6313篇 |
2018年 | 9432篇 |
2017年 | 9794篇 |
2016年 | 12572篇 |
2015年 | 6611篇 |
2014年 | 11585篇 |
2013年 | 24214篇 |
2012年 | 19673篇 |
2011年 | 22924篇 |
2010年 | 17743篇 |
2009年 | 18044篇 |
2008年 | 21047篇 |
2007年 | 20793篇 |
2006年 | 18983篇 |
2005年 | 18695篇 |
2004年 | 17844篇 |
2003年 | 15291篇 |
2002年 | 14252篇 |
2001年 | 15641篇 |
2000年 | 11929篇 |
1999年 | 9153篇 |
1998年 | 8045篇 |
1997年 | 7722篇 |
1996年 | 7160篇 |
1995年 | 6321篇 |
1994年 | 6295篇 |
1993年 | 6177篇 |
1992年 | 6518篇 |
1991年 | 7049篇 |
1990年 | 6761篇 |
1989年 | 6696篇 |
1988年 | 6321篇 |
1987年 | 6501篇 |
1986年 | 6073篇 |
1985年 | 7391篇 |
1984年 | 7671篇 |
1983年 | 6468篇 |
1982年 | 6637篇 |
1981年 | 6212篇 |
1980年 | 6001篇 |
1979年 | 6624篇 |
1978年 | 6661篇 |
1977年 | 6806篇 |
1976年 | 6818篇 |
1975年 | 6383篇 |
1974年 | 6199篇 |
1973年 | 6383篇 |
1972年 | 4988篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
961.
962.
A. V. Kibal'nyi Yu. A. Nikolyukin V. I. Dulenko 《Chemistry of Heterocyclic Compounds》1994,30(8):895-900
Summary The reaction of acyl perchlorates with 1 phenacylskatole affords the previously unknown 1-R-lamethyl-3phenylindolo[2,1-c1-1,4oxazinium salts, which undergo recyclization by the action of ammonia to the corresponding indolo[2,1-alpyrazines. It is found that the salts (R = CHj, CZHS) also form dimers of their anhydro bases. The perchlorate (R = Ph) is converted to indolo[2,141-1, 2, S-triazepine by the action of hydrazine.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1041-1047, August, 1994. 相似文献
963.
James V. Crivello 《Journal of polymer science. Part A, Polymer chemistry》2007,45(18):4331-4340
The irradiation of hybrid photopolymer systems consisting of a free radically polymerizable multifunctional acrylate monomer and a cationically polymerizable epoxide or oxetane monomer was conducted under conditions where only the free radical polymerization takes place. This results in the formation of a free‐standing polyacrylate network film containing quiescent oxonium ions along with the unreacted cyclic ether monomer. The subsequent application of a point source of heat to the film ignites a cationic ring‐opening frontal polymerization that emanates from that site and propagates to all portions of the irradiated sample. This article examines the impact of various molecular structural and experimental parameters on these novel hybrid frontal polymerizations that produce interpenetrating network polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4331–4340, 2007 相似文献
964.
With the use of an analytical approach developed, the influence of distribution of a tangential load on the stress concentration
in uniaxially tensioned flat specimens of high-strength unidirectional composites near the grips of a testing machine is evaluated.
In view of singularity of the analytical solution derived at the points of discontinuity of boundary conditions, for estimating
the stress concentration, it is suggested to employ the averaged value of longitudinal stresses, which is calculated by means
of an improper integral across the thickness of a near-surface layer.
__________
Translated from Mekhanika Kompozitnykh Materialov, Vol. 42, No. 6, pp. 787–796, November–December, 2006. 相似文献
965.
I. V. Gaishun 《Proceedings of the Steklov Institute of Mathematics》2006,255(2):S47-S53
For a linear nonautonomous system with one output, the existence conditions for an identifier that estimates the current state with exponential rate are established. An algorithm for constructing such an identifier is described and its dependence on small perturbations of coefficients is studied. 相似文献
966.
Mathematical models with stage structures are proposed to describe the process of awareness, evaluation and decision-making. First, a system of ordinary differential equations is presented that incorporates the awareness stage and the decision-making stage. If the adoption rate is bilinear and imitations are dominant, we find a threshold above which innovation diffusion is successful. Further, if the adoption rate has a higher nonlinearity, it is shown that there exist bistable equilibria and a region such that an innovation diffusion is successful inside and is unsuccessful outside. Secondly, a model with a time delay is proposed that includes an evaluation stage of a product. It is proved that the system exhibits stability switches. The bifurcation direction of equilibria is also discussed. 相似文献
967.
968.
M. N. Vidyakin Yu. N. Lazareva Yu. P. Yampolskii A. Yu. Alentiev D. Yu. Likhachev A. L. Rusanov O. V. Kozlova 《Polymer Science Series A》2006,48(6):596-600
The correlation between chemical structure and gas transport properties is considered for a new class of membrane materials based on structurally similar polyphenylquinoxalines that are characterized by different numbers of flexible-O-ether bonds in the repeating unit and different chain rigidities. Permeability, diffusion, and solubility coefficients have been estimated for the gases H2, He, O2, N2, CO, CO2, and CH4; separation factors for various gas pairs have been determined. For the materials with a similar level of cohesive energy density, which characterizes interchain interactions, permeability decreases with a decrease in chain rigidity, whereas selectivity of gas separation increases. 相似文献
969.
The energies of negative-parity levels based on two-particle states exhibit a nonlinear behavior at low spins versus the core-rotation energy because the alignment process has not yet been completed for them. This behavior of negative-parity levels in the low-spin region is satisfactorily described upon the inclusion of octupole-octupole interactions. This is demonstrated within the rotational model involving the Coriolis mixing of states for the even-even isotopes 162–168Hf. 相似文献
970.
The energy band structure, equation of state, density of states, and elastic moduli of a new allotropic carbon modification, namely, fullerite C24 with a simple cubic lattice (known previously as cubic graphite), are calculated by the full-potential linearized augmented-plane-wave (FLAPW) method with geometry optimization for the first time. The dependence of the total energy on the lattice constant exhibits a minimum for a 0 = 0.60546 nm. In this case, the lengths of the C-C bonds between fullerene molecules, the lengths of the 6,6-bonds shared by hexagons, and the lengths of the 4,6-bonds shared by a square and a hexagon are equal to 0.1614, 0.1503, and 0.1637 nm, respectively. An analysis of the energy band structure and the density of states demonstrates that the simple cubic fullerite C24 is a direct-band-gap insulator or a semiconductor with a band gap of 1.6 eV. The calculated bulk modulus B 0 = 196 GPa and the elastic moduli C 11 = 338 GPa, C 12 = 139 GPa, and C 44 = 30 GPa indicate that the fullerite under investigation is a mechanically stable material. The inference is made that the simple cubic fullerite C24 is a new diamond-like molecular zeolite with a unique combination of properties, such as the porosity and nonpolarizability, on the one hand, and the mechanical strength, chemical inertness, and high thermal conductivity, on the other hand. The simple cubic fullerite C24 can be considered a promising low-dielectric-constant (low-k) material (?0 < 5.7) for use in fabricating interconnections and substrates intended for integrated circuits and nanoelectronics. 相似文献