Syntheses and structures of three complexes of formulas [L3Co(μ2-O2P(Bn)2)3CoL'][L"], featuring octahedral and tetrahedral cobalt(II) geometries; variable-temperature magnetic susceptibility measurement and analysis on [(py)3Co(μ2-O2PBn2)3Co(py)][ClO4

The syntheses and structural properties of three dinuclear complexes [L(3)Co(μ(2)-O(2)P(Bn)(2))(3)CoL'][L"] [one ionic L(3) = py(3), L' = py, L" = ClO(4)(-) (1) and two molecular L(3) = py(3), L' = Cl (2) and L(3) = py, μ(2)-NO(3)(-), L' = py (3)] are reported. Complexes feature octahedral Co(II) sites bridged by three dibenzylphosphinate ligands to a tetrahedrally ligated Co(II) site, with the remaining coordination sites occupied by py, nitrato, and Cl ligands. The Co-Co distances are 4.248 ? at 291 K and 4.265 ? at 100 K for 1 and 4.278 and 4.0313(7) ? for 2 and 3, respectively at 100 K. A fit of the low-temperature magnetic susceptibility data was derived for complex 1 with g = 2.25, TIP = 700 × 10(-6) cm(3) mol (-1), λ = -173 cm(-1), κ = 0.93, ν = -3.9, Δ = 630 cm(-1), J = 0.15 cm(-1), and θ = -1.8 resulting in R(χ(M)) = 2.5 × 10(-5) and R(χ(M)T) = 5.8 × 10(-5).     

Synthesis and Structural Characterization of a Dimolybdenum Complex Bridged by the Hydroxymethylphenylphosphinate Ligand

Abstract  

Hydroxymethylphenylphosphinic acid, 1 was synthesized and structurally characterized by single crystal X-ray diffraction. Ligand 1 crystallized in the monoclinic P2₁ space group with two molecules comprising the unit cell and cell dimensions a = 7.5587(13) ?, b = 5.9019(8) ?, c = 8.808(3) ? and β = 90.90(2)°. Molecules were linked up by hydrogen bonding involving all three oxygen atoms of 1 resulting in 2-dimensional sheets. Reacting 1 with MoO₂Cl₂ in a mixture of ethanol and dichloromethane afforded the dinuclear molybdenum complex Mo₂O₄Cl₂[(HOCH₂)PhPOO]₂, 2 where the two molybdenum atoms were bridged by the phosphinate ligand. Complex 2 crystallized in the P2_1/C space group as a dietherate with a = 9.208(3) ?, b = 14.353(4) ?, c = 12.805(4) ? and β = 98.64(3)° and contained terminal O and Cl atom disorder. The two crystallographically identical molybdenum centers are in distorted octahedral environments. Complexes were analyzed by IR, ³¹P NMR and X-ray crystallography.     

Multifractal description of wind power fluctuations using arbitrary order Hilbert spectral analysis

The objectives are to study and model the aggregate wind power fluctuations dynamics in the multifractal framework. We present here the analysis of aggregate power output sampled at 1 Hz during three years. We decompose the data into several Intrinsic Mode Functions (IMFs) using Empirical Mode Decomposition (EMD). We use a new approach, arbitrary order Hilbert spectral analysis, a combination of the EMD approach with Hilbert spectral analysis (or Hilbert–Huang Transform) and the classical structure-function analysis to extract the scaling exponents or multifractal spectrum ζ(q)$\zeta \left(q\right)$: this function provides a full characterization of a process at all intensities and all scales. The application of both methods, i.e. structure-function and arbitrary-order Hilbert spectral analyses, gives similar results indicating that the aggregate power output from a wind farm, possesses intermittent and multifractal properties. In order to check this result, we generate stochastic simulations of a Multifractal Random Walk (MRW) using a log-normal stochastic equation. We show that the simulation results are fully compatible with the experimental results.     

Vector bundles and regulous maps

Let $X$ be a compact nonsingular affine real algebraic variety. We prove that every pre-algebraic vector bundle on $X$ becomes algebraic after finitely many blowing ups. Using this theorem, we then prove that the Stiefel-Whitney classes of any pre-algebraic $\mathbb{R }$ -vector bundle on $X$ are algebraic. We also derive that the Chern classes of any pre-algebraic $\mathbb{C }$ -vector bundles and the Pontryagin classes of any pre-algebraic $\mathbb{R }$ -vector bundle are blow- $\mathbb{C }$ -algebraic. We also provide several results on line bundles on $X$ .     

Microcalorimeter arrays for ultra-high energy resolution X- and gamma-ray detection

Microcalorimeter detectors provide superior energy resolution for the detection of X-rays and gamma-rays. The technology utilizes a cryogenic transition-edge sensor (TES) coupled to a tin bulk absorber. We are working on fabrication methods for the production of arrays with many sensors. In this paper, we present data collected with an array of microcalorimeters using as many as 26 sensor elements simultaneously. Advances in sensor design have extended the useful dynamic range to photon energies up to ～200 keV, while providing resolution performance in the 80–90 eV FWHM range, significantly better than planar high-purity germanium. These sensor arrays have applications in the measurement of nuclear materials. We present data collected from ¹⁵³Gd, a highly-enriched uranium sample, and a plutonium isotopic standard source. We also demonstrate clean separation of the ²³⁵U 185.715 keV peak from the ubiquitous ²²⁶Ra 186.211 keV background peak interference.     

Evaporation of polydispersed droplets in a highly turbulent channel flow

A model experiment for the study of evaporating turbulent two-phase flows is presented here. The study focuses on a situation where pre-atomized and dispersed droplets vaporize and mix in a heated turbulent flow. The test bench consists in a channel flow with characteristics of homogeneous and isotropic turbulence where fluctuations levels reach very high values (25% in the established zone). An ultrasonic atomizer allows the injection of a mist of small droplets of acetone in the carrier flow. The large range diameters ensure that every kind of droplet behavior with regards to turbulence is possible. Instantaneous concentration fields of the vaporized phase are extracted from fluorescent images (PLIF) of the two phase flow. The evolution of the mixing of the acetone vapor is analyzed for two different liquid mass loadings. Despite the high turbulence levels, concentration fluctuations remain significant, indicating that air and acetone vapor are not fully mixed far from the injector.     

Synthesis of 4-Aminopyrazol-5-ols as Edaravone Analogs and Their Antioxidant Activity

One of the powerful antioxidants used clinically is Edaravone (EDA). We synthesized a series of new EDA analogs, 4-aminopyrazol-5-ol hydrochlorides, including polyfluoroalkyl derivatives, via the reduction of 4-hydroxyiminopyrazol-5-ones. The primary antioxidant activity of the compounds in comparison with EDA was investigated in vitro using ABTS, FRAP, and ORAC tests. In all tests, 4-Amino-3-pyrazol-5-ols were effective. The lead compound, 4-amino-3-methyl-1-phenylpyrazol-5-ol hydrochloride (APH), showed the following activities: ABTS, 0.93 TEAC; FRAP, 0.98 TE; and ORAC, 4.39 TE. APH and its NH-analog were not cytotoxic against cultured normal human fibroblasts even at 100 μM, in contrast to EDA. According to QM calculations, 4-aminopyrazolols were characterized by lower gaps, IP, and η compared to 4-hydroxyiminopyrazol-5-ones, consistent with their higher antioxidant activities in ABTS and FRAP tests, realized by the SET mechanism. The radical-scavenging action evaluated in the ORAC test occurred by the HAT mechanism through OH bond breaking in all compounds, directly dependent on the dissociation energy of the OH bond. All the studied compounds demonstrated the absence of anticholinesterase activity and moderate inhibition of CES by some 4-aminopyrazolols. Thus, the lead compound APH was found to be a good antioxidant with the potential to be developed as a novel therapeutic drug candidate in the treatment of diseases associated with oxidative stress.     

Five-nucleon transfer in the12C(d,7Li)7be reaction atE lab=78.0 MeV

Angular distributions of the¹²C(d,⁷Li)⁷Be reaction to the ground and to the unresolved first excited states of⁷Li or⁷Be nuclei were measured in the entire angular region in the centre of mass system atE _lab=78.0 MeV. Both the one-step five-nucleon cluster transfer as well as two-step sequential transfers were considered in the theoretical analysis. The former mechanism was found to dominate, but the latter is also not negligible.