Hydromagnetic flow and heat transfer adjacent to a stretching vertical sheet

An analysis is made for the steady two-dimensional magneto-hydrodynamic flow of an incompressible viscous and electrically conducting fluid over a stretching vertical sheet in its own plane. The stretching velocity, the surface temperature and the transverse magnetic field are assumed to vary in a power-law with the distance from the origin. The transformed boundary layer equations are solved numerically for some values of the involved parameters, namely the magnetic parameter M, the velocity exponent parameter m, the temperature exponent parameter n and the buoyancy parameter λ, while the Prandtl number Pr is fixed, namely Pr = 1, using a finite difference scheme known as the Keller-box method. Similarity solutions are obtained in the presence of the buoyancy force if n = 2m−1. The features of the flow and heat transfer characteristics for different values of the governing parameters are analyzed and discussed. It is found that both the skin friction coefficient and the local Nusselt number decrease as the magnetic parameter M increases for fixed λ and m. For m = 0.2 (i.e. n = −0.6), although the sheet and the fluid are at different temperatures, there is no local heat transfer at the surface of the sheet except at the singular point of the origin (fixed point).     

Association Behavior of 3,4-Dihydroxy-9,10-dioxo-2-anthracenesulfonic Acid Sodium Salt in Cationic Surfactant Medium Under Different pH Conditions

Ultraviolet (UV)-visible behavior of 3,4-dihydroxy-9,10-dioxo-2-anthracenesulfonic acid sodium salt (ARS) has been studied at pH 4.0, aqueous medium, and at pH 10.0. The effects of cetyl trimethylammoniumbromide (CTAB) on the UV-visible spectra of ARS have been evaluated qualitatively as well as quantitatively in the different concentration regions of CTAB. The shift in the UV-visible spectrum of ARS, due to CTAB, at its low concentration is comparable to the shift shown by the same at pH 10.0. In acidic and basic pH, effect of CTAB is significantly lowered on the UV-visible spectra than ARS in the purely aqueous medium. In aqueous and basic medium, lower values of partition and binding constant are obtained compared to the one obtained in acidic medium. Conductivity studies show that increasing dye concentrations have no effect on its partitioning behavior nevertheless critical micelle concentration of CTAB is lowered.     

Luminescence bands in natural brown diamonds

We report on new luminescence bands exhibited by natural brown/mauve diamonds. We describe detailed absorption and luminescence measurements in the visible spectral region. The structured bands with ZPL at 2.424 eV, 2.114 eV, 1.819 eV and 1.707 eV, and a broad band with a maximum at 1.8 eV are shown to be the main components of the visible luminescence. Bands with ZPL at 2.114 eV, 1.819 eV and 1.707 eV are shown to correspond to forbidden transitions with lifetimes of the order of msec. Energy absorbed by the 2.424 eV centre is transferred into the 1.819 eV centre.     

Synergetic Effect of Mo6 Clusters and Gold Nanoparticles on the Photophysical Properties of Both Components

Photodynamic and photothermal therapies (PDT, and PTT, respectively) are promising candidates for multimodal anticancer therapies (i.e., combinations of therapies), since their action is based on mechanisms that generally cannot be resisted by cancer cells, that is, generation of highly oxidizing oxygen species and high temperature, respectively. Herein, hybrid materials that combine octahedral molybdenum clusters as potential PDT agents and plasmonic spherical gold nanoparticles (AuNPs) as PTT agents are reported. Partial overlap of the photoemission spectrum of the cluster and the surface plasmon resonance band of the AuNPs facilitates energy transfer between the photoactive components, which resulted in synergetic enhancement of their photophysical properties. Specifically, by careful selection of the spacing between the cluster and the gold nanoparticle, a significant increase in luminescence and photosensitizing properties of the cluster was achieved in comparison with similar, but gold-free, particles. On the other hand, the cluster complex facilitated energy conversion to heat by gold particles and hence increased the heating rate under laser irradiation.     

A general and mild domino approach to substituted 1-aminoindoles

A versatile and efficient palladium catalyzed domino reaction leading to a broad range of substituted 1-aminoindoles has been developed. The title compounds were prepared from 2-halo-phenylacetylenes and simple hydrazines in good to excellent yields in just a few hours under mild conditions.     

Influence of particle size on solid solution formation and phase interfaces in Li0.5FePO4 revealed by 31P and 7Li solid state NMR spectroscopy

Here we report the observation of electron delocalization in nano-dimension xLiFePO(4):(1 - x)FePO(4) (x = 0.5) using high temperature, static, (31)P solid state NMR. The (31)P paramagnetic shift in this material shows extreme sensitivity to the oxidation state of the Fe center. At room temperature two distinct (31)P resonances arising from FePO(4) and LiFePO(4) are observed at 5800 ppm and 3800 ppm, respectively. At temperatures near 400 °C these resonances coalesce into a single narrowed peak centered around 3200 ppm caused by the averaging of the electronic environments at the phosphate centers, resulting from the delocalization of the electrons among the iron centers. (7)Li MAS NMR spectra of nanometre sized xLiFePO(4):(1 - x)FePO(4) (x = 0.5) particles at ambient temperature reveal evidence of Li residing at the phase interface between the LiFePO(4) and FePO(4) domains. Moreover, a new broad resonance is resolved at 65 ppm, and is attributed to Li adjacent to the anti-site Fe defect. This information is considered in light of the (7)Li MAS spectrum of LiMnPO(4), which despite being iso-structural with LiFePO(4) yields a remarkably different (7)Li MAS spectrum due to the different electronic states of the paramagnetic centers. For LiMnPO(4) the higher (7)Li MAS paramagnetic shift (65 ppm) and narrowed isotropic resonance (FWHM ≈ 500 Hz) is attributed to an additional unpaired electron in the t(2g) orbital as compared to LiFePO(4) which has δ(iso) = -11 ppm and a FWHM = 9500 Hz. Only the delithiated phase FePO(4) is iso-electronic and iso-structural with LiMnPO(4). This similarity is readily observed in the (7)Li MAS spectrum of xLiFePO(4):(1 - x)FePO(4) (x = 0.5) where Li sitting near Fe in the 3+ oxidation state takes on spectral features reminiscent of LiMnPO(4). Overall, these spectral features allow for better understanding of the chemical and electrochemical (de)lithiation mechanisms of LiFePO(4) and the Li-environments generated upon cycling.     

Investigation of hydrogen absorption in Li7VN4 and Li7MnN4

The hydrogen storage properties of Li(7)VN(4) and Li(7)MnN(4) were investigated both by experiment and by density functional theory calculations. Li(7)VN(4) did not sorb hydrogen under our experimental conditions. Li(7)MnN(4) was observed to sorb 7 hydrogen atoms through the formation of LiH, Mn(4)N, and ammonia gas. An applied pressurized mixture of H(2)/Ar and H(2)/N(2) gases was helpful to mitigate the release of NH(3) but could not prevent its formation. The introduction of N(2) also caused weight gain of the sample by re-nitriding the absorbed products LiH and Mn(4)N, which correlated with the presence of Li(2)NH, LiNH(2), and Mn(2)N detected by X-ray diffraction. While our observed results for Li(7)VN(4) and Li(7)MnN(4) differ in detail, they are in overall qualitative agreement with our theoretical work, which strongly suggests that both compounds are unlikely to form quaternary hydrides.     

MHD boundary layer flow and heat transfer over a stretching sheet with induced magnetic field

In this paper, the problem of steady magnetohydrodynamic boundary layer flow and heat transfer of a viscous and electrically conducting fluid over a stretching sheet is studied. The effect of the induced magnetic field is taken into account. The transformed ordinary differential equations are solved numerically using the finite-difference scheme known as the Keller-box method. Numerical results are obtained for various values of the magnetic parameter, the reciprocal magnetic Prandtl number and the Prandtl number. The effects of these parameters on the flow and heat transfer characteristics are determined and discussed in detail. When the magnetic field is absent, the closed analytical results for the skin friction are compared with the exact numerical results. Also the numerical results for the heat flux from the stretching surface are compared with the results reported by other authors when the magnetic field is absent. It is found that very good agreement exists.     

Experimental analysis of convergence of the numerical solution to a generalized solution in fluid dynamics

Convergence of the approximate solution of fluid dynamics problems obtained using Godunov’s scheme to the discontinuous solution is investigated.     

New organosulfur metallic compounds as potent drugs: synthesis,molecular modeling,spectral, antimicrobial,drug likeness and DFT analysis

Molecular Diversity - During the present investigation, two new sulfonamide-based Schiff base ligands, 4-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}-N-(1,3-thiazol-2-yl)benzene-1-sulfonamide...