On a Microscopic Representation of Space-Time VIII—On Relativity

Physics of Atomic Nuclei - Based on the previous work on the Dirac algebra and su*(4) Lie algebra generators, using Lie transfer we have associated spin to line and Complex reps. Here, we discuss...     

Hyperflock determining line sets and totally regular parallelisms of PG (3, \mathbbR){(3,\,{\mathbb{R}})}

By a totally regular parallelism of the real projective 3-space P₃:=PG(3, \mathbb R){\Pi_3:={{\rm PG}}(3, \mathbb {R})} we mean a family T of regular spreads such that each line of Π ₃ is contained in exactly one spread of T. For the investigation of totally regular parallelisms the authors mainly employ Klein’s correspondence λ of line geometry and the polarity π ₅ associated with the Klein quadric H ₅ (for details see Chaps. 1 and 3). The λ-image of a totally regular parallelism T is a hyperflock of H ₅, i.e., a family H of elliptic subquadrics of H ₅ such that each point of H ₅ is on exactly one subquadric of H. Moreover, {p₅(span  l(X))|X ? T}=:H_T{\{\pi_5({{\rm span}} \,\lambda(\mathcal {X}))\vert\mathcal {X}\in\bf{T}\}=:\mathcal {H}_{\bf{T}}} is a hyperflock determining line set, i.e., a set Z{\mathcal {Z}} of 0-secants of H ₅ such that each tangential hyperplane of H ₅ contains exactly one line of Z{\mathcal {Z}} . We say that dim(span H_T)=:d_T{{{\rm dim}}({{\rm span}}\,\mathcal {H}_{\bf{T}})=:d_{\bf{T}}} is the dimension of T and that T is a d _T - parallelism. Clifford parallelisms and 2-parallelisms coincide. The examples of non-Clifford parallelisms exhibited in Betten and Riesinger [Result Math 47:226–241, 2004; Adv Geom 8:11–32, 2008; J Geom (to appear)] are totally regular and of dimension 3. If G{\mathcal{G}} is a hyperflock determining line set, then {l^-1 (p₅(X) ?H₅) | X ? G}{\{\lambda^{-1}\,{\rm (}\pi_5(X){\,\cap H_5)\,|\, X\in\mathcal{G}\}}} is a totally regular parallelism. In the present paper the authors construct examples of topological (see Definition 1.1) 4- and 5-parallelisms via hyperflock determining line sets.     

Cumulant approach to the two-dimensional magneto-conductivity problem

The validity of assumptions involved in experimental evaluations of the g-factor of electrons in (100) surface inversion layers of p-silicon from Shubnikov-De Haas oscillations of the surface conductivity by the method of tilted megnetic fields is discussed on the basis of the transport theory of a two-dimensional electron-impurity system. The self-consistent Born approximation is shown to be insufficient to this task, and an alternative cumulant approach is discussed. Contrary to recent work, the cumulant approach is introduced in a simple manner, avoiding the path-integral formalism.     

Walking an unknown street with bounded detour

A polygon with two distinguished vertices, s and g, is called a street if the two boundary chains from s to g are mutually weakly visible. For a mobile robot with on-board vision system we describe a strategy for finding a short path from s to g in a street not known in advance, and prove that the length of the path created does not exceed 1 + π times the length of the shortest path from s to g. Experiments suggest that our strategy is much better than this, as no ratio bigger than 1.8 has yet been observed. This is complemented by a lower bound of 1.41 for the relative detour each strategy can be forced to generate.     

Aliphatic hydroxylation and epoxidation of capsaicin by cytochrome P450 CYP505X

Microbial cytochrome P450 enzymes (CYPs) are able to mimic the metabolism of human CYPs. One challenge is to identify the respective drug metabolites and to compare substrate specificities to those of the human enzymes. In this study, a class VIII self-sufficient CYP from Aspergillus fumigatus (CYP505X) and variants of this enzyme were heterologously expressed in E. coli. The substrate scope of the variants was determined using active pharmaceutical ingredients (APIs) and (hetero)cyclic compounds. Capsaicin – the active compound in chili peppers – was oxidized most efficiently (4.36?μM/min) in a whole cell mediated biotransformation. The products were isolated, purified and their structures elucidated by 1D and 2D NMR. The two major metabolites showed modifications on the lipophilic side chain. Specifically, capsaicin was hydroxylated at position 8 to give (E)-8-hydroxy-N-(4-hydroxy-3-methoxybenzyl)-8-methylnon-6-enamide and epoxidized at the double bond to give N-(4-hydroxy-3-methoxybenzyl)-5-(3-isopropyloxiran-2-yl)-pentanamide.     

A novel methodological approach for δ18O analysis of sugars using gas chromatography-pyrolysis-isotope ratio mass spectrometry

Although the instrumental coupling of gas chromatography-pyrolysis-isotope ratio mass spectrometry (GC-Py-IRMS) for compound-specific δ¹⁸O analysis has been commercially available for more than a decade, this method has been hardly applied so far. Here we present the first GC-Py-IRMS δ¹⁸O results for trimethylsilyl-derivatives of plant sap-relevant sugars and a polyalcohol (glucose, fructose, sucrose, raffinose and pinitol). Particularly, we focus on sucrose, which is assimilated in leaves and which is the most important transport sugar in plants and hence of utmost relevance in plant physiology and paleoclimate studies. Replication measurements of sucrose standards and concentration series indicate that the GC-Py-IRMS δ¹⁸O measurements are not stable over time and that they are amount (area) dependent. We, therefore, suggest running sample batch replication measurements in alternation with standard concentration series of reference material. This allows for carrying out (i) a drift correction, (ii) a calibration against reference material and (iii) an amount (area) correction. Tests with ¹⁸O-enriched water do not provide any evidence for oxygen isotope exchange reactions affecting sucrose and raffinose. We present the first application of GC-Py-IRMS δ¹⁸O analysis for sucrose from needle extract (soluble carbohydrate) samples. The obtained δ¹⁸O_{sucrose/ Vienna Standard Mean Ocean Water (VSMOW)} values are more positive and vary in a wider range (32.1–40.1 ‰) than the δ¹⁸O_{bulk/ VSMOW} values (24.6–27.2 ‰). Furthermore, they are shown to depend on the climate parameters maximum day temperature, relative air humidity and cloud cover. These findings suggest that δ¹⁸O_sucrose of the investigated needles very sensitively reflects the climatically controlled evaporative ¹⁸O enrichment of leaf water and thus highlights the great potential of GC-Py-IRMS δ¹⁸O_sucrose analysis for plant physiology and paleoclimate studies.     

Experimental Observations on Superelastic NiTi-Shape Memory Alloys and Suggestions for Modelling

During stress-induced transformation NiTi shows a distinct generation of transformation bands. A simple one-dimensional model for superelastic NiTi wires has been developed to show exemplarily methods to account for these bands in plasticitybased models. To clarify the dependence of the transformation bands on the distribution of latent heat and therefore on the mechanical behaviour, optical and thermographical experiments have been performed. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

A Novel Route to the Fused Maleic Anhydride Moiety of CP Molecules

A seven‐step cascade reaction —in which selective mesylation, epoxide formation, epoxide lysis, cyclization, reiterative oxidation, and nitrogen–oxygen exchange occur sequentially—facilitates the construction of the maleic anhydride moiety of CP molecules 1 and 2 (>93% yield per step). Unstable intermediates of this reaction sequence were detected, providing evidence for the proposed mechanism and resulting in the discovery of a new chemical entity.