Fragmentation during the formic acid/formaldehyde (eschweiler-clarke) methylation of polyamines

Eschweiler-Clarke methylations of both acyclic and cyclic polyamines can lead to methylation products of fragments of the original polyamine; thus 1,5,9,13-tetra-azatridecane yields 1,1,3,3-tetramethylpropanediamine exclusively and 1,5,9-triazacyclododecane gives 45% 1,5,9-trimethyl-1,5,9-triazacyclodecane and 45% 2,6,10-trimethyl-2,6,10-triazaundecane.     

Positive Schatten(-Herz) Class Toeplitz Operators on the Half-space

On the harmonic Bergman space of the half-space, we give characterizations for an arbitrary positive Toeplitz operator to be a Schatten (or Schatten-Herz) class operator in terms of averaging functions and Berezin transforms. Examples are provided to show that various results are sharp. This research was supported by KOSEF(R01-2003-000-10243-0).     

Nusselt number correlations for heat transfer to small spheres in thermal plasma flows

Seven different equations predicting heat transfer rates to small spheres in plasma flows are examined considering argon and nitrogan as plasma gases from 300 to 21,000 K at 1 atm. For argon there is a general consensus up to 9000 K, beyond which wide deviations in behavior occur. For nitrogen, the seven correlations are in good agreement up to 4000 K, but show substantial deviations beyond this value. Comparisons with the sparsely available experimental data are made for argon from 300 to 17,000 K and for nitrogen up to 5500 K. Disagreement between the various correlations and experiment can exceed one order of magnitude.     

Regularization procedures of mixed finite element approximations of the stokes problem

We propose a theoretical framework for the study of regularization of the Stokes problem. This enables us to perform a general error analysis and to apply it to known schemes as well as to a new one pertaining to the use of the P1-P1 element. Finally we show that in the P1-case the theory can also be used to get convergence results for elements obtained by addition of bubble functions, without using the usual mixed finite element machinery.     

A family of maximal surfaces in Lorentz-Minkowski three-space

We prove the existence of an infinite family of complete spacelike maximal surfaces with singularities in Lorentz-Minkowski three-space and study their properties. These surfaces are distinguished by their number of handles and have two elliptic catenoidal ends.

     

O− and OH− chemical ionization of some fatty acid methyl esters and triacylglycerols

O^? and OH^? react with fatty acid methyl esters (FAMES) under chemical ionization conditions both as Bronsted bases to form [M - H]^? and as nucleophiles to form the carboxylate ion RCOO^?. O^? shows a much greater tendency to react as a nucleophile than does OH^?. The [M - H]^? ions fragment by elimination of CH³OH, with unsaturation in certain positions in the fatty acid hydrocarbon chain promoting this elimination for unknown reasons. The reaction of O^? and OH^? with triacylglycerols leads to [M - H]^?, characteristic of the molecular mass, and to carboxylate ions characteristic of the fatty acid(s) present in the lipid. The presence of the three ester functions in the lipids greatly enhances the formation of carboxylate ions compared to the FAMES.     

Wilcoxon signed rank test using ranked-set sample

Ranked-set sampling is useful when measurements are destructive or costly to obtain but ranking of the observations is relatively easy. The Wilcoxon signed rank test statistic based on the ranked-set sample is considered. We compared the asymptotic relative efficiencies of the RSS Wilcoxon signed rank test statistic with respect to the SRS Wilcoxon signed rank test statistic and the RSS sign test statistic. Throughout the ARE’s, the proposed test statistic is superior to the SRS Wilcoxon signed rank test statistic and the RSS sign test statistic.