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91.
A. La Ginestra C. Ferragina P. Patrono R. Dl Rocco 《Journal of Thermal Analysis and Calorimetry》1981,20(1):205-213
The thermal and redox behaviours of some Ag-low-converted zirconium phosphates have been investigated by thermoanalytical and X-ray methods: the conditions for obtaining Ag solid solutions in
phases are reported.
Paper in part presented at the 6th ICTA, in Bayreuth (Germany), July 1980.
We thank Dr. M. A. Massucci, of our Institute, for helpful discussions and suggestions. 相似文献
Zusammenfassung Das thermische und Redoxverhalten einiger Zirkoniumphosphate niedriger Ag-Konversion wurde durch thermoanalytische und Röntgenmethoden studiert; über die Bedingungen zum Erhalten von Ag-Festphasenlösungen in HH-Phasen wird berichtet
Résumé On a étudié le comportement thermique et oxydo-réducteur de quelques phosphates de zirconium faiblement converti par Ag, en se servant des méthodes d'analyse thermique et des rayons X: on communique les conditions permettant d'obtenir des solutions solides d'Ag dans les phases .
- Ag- . HH.
Paper in part presented at the 6th ICTA, in Bayreuth (Germany), July 1980.
We thank Dr. M. A. Massucci, of our Institute, for helpful discussions and suggestions. 相似文献
92.
The exoergic Eley-Rideal hydrogen recombination on graphite surfaces is known to produce vibrationally hot product molecules. Realistic quantum scattering calculations at normal incidence over a wide range of collision energies show that the degree of vibrational excitation of the reaction product is a steep decreasing function of the collision energy. This results in selective population of the lower-lying vibrational levels and gives rise to an oscillating structure in the total reaction cross-sections at high energies, which cannot be reproduced by classical and quasi-classical trajectory calculations. An analogous quantum structure appears in the total collision-induced desorption cross-sections and is assigned to selective population of the metastable states of the transient molecular hydrogen. 相似文献
93.
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96.
The paper summarizes the knowledge acquired from the analytical studies and the experimental implementation of a longitudinal non-collocated control strategy for the reduction of cable oscillations. The control is introduced by imposing a longitudinal action at one support based on the knowledge of transverse displacements and velocities of a few selected points. A spatially one-dimensional continuous model of a suspended cable has been used to describe the main features of the non-collocated longitudinal active control strategy. A discrete modal representation has permitted the introduction of suitable non-linear state-feedback controllers. The results have been used to derive an implementable strategy, based on direct output feedback, which preserves the main previous control features. A physical model of an actively controlled cable has been used to demonstrate the control effectiveness of the proposed strategy through a large campaign of experiments, conducted in various frequency ranges and amplitude levels including meaningful external resonance conditions. The responses predicted by the analytical model and the experimental results show good qualitative agreement with one another, in both the uncontrolled and controlled experienced cable dynamics. 相似文献
97.
An experimental model of an elastic cable carrying eight concentrated masses and hanging at in-phase or out-of-phase vertically moving supports is considered. The system parameters are adjusted to approximately realize multiple 1:1 and 2:1 internal resonance conditions involving planar and nonplanar, symmetric and antisymmetric modes. Response measurements are made in various frequency ranges including meaningful external resonance conditions. A local analysis of the system response is made on the basis of numerous amplitude-frequency and amplitude-forcing plots obtained in different ranges of the control parameter space. Attention is mainly devoted to the detection of the main features of the regular motions exhibited by the system, and to the analysis of the relevant phenomena of nonlinear modal interaction, competition, and local bifurcation between planar and nonplanar regular responses. The resulting picture appears very rich and varied. 相似文献
98.
Claudio De Rosa Finizia AuriemmaOdda Ruiz de Ballesteros Rocco Di GirolamoMartina Pepe Oreste TaralloAnna Malafronte 《European Polymer Journal》2013
A study of the thermodynamic stability and the related polymorphic transformations induced by thermal treatments of the mesomorphic form that crystallizes in stereodefective metallocene isotactic polypropylene (iPP) is presented. We show that the mesomorphic form of the more isotactic samples is stable at room temperature, whereas the mesomorphic form crystallizing in the more stereoirregular sample is unstable and crystallizes at room temperature in the crystalline α form. In any case, the mesomorphic form transforms during heating or by annealing at temperatures higher than 60–80 °C always in the α form, regardless of the stereoregularity, even in the case of stereoirregular samples generally crystallizing from the melt in the γ form. These data confirm the proposed model of structure of the mesomorphic form as small aggregates of chains in three-fold helical conformation packed with lateral correlations similar to the α form of iPP. 相似文献
99.
Rosario Caltabiano Rocco De Pasquale Eliana Piombino Giorgia Campo Ferdinando Nicoletti Eugenio Cavalli Katia Mangano Paolo Fagone 《Molecules (Basel, Switzerland)》2021,26(1)
Discoid Lupus Erythematosus (DLE) is a chronic cutaneous disease of unknown etiology and of immunoinflammatory origin that is characterized by inflammatory plaques and may lead to disfiguring scarring and skin atrophy. Current treatments are limited, with a large proportion of patients either poorly or not responsive, which makes DLE an unmet medical need. Macrophage migration inhibitory factor (MIF) is the prototype of a pleiotropic family of cytokine that also includes the recently discovered homologue D-dopachrome tautomerase (DDT) or MIF2. MIF and DDT/MIF-2 exert several biological properties, primarily, but not exclusively of a proinflammatory nature. MIF and DDT have been suggested to play a key role in the pathogenesis of several autoimmune diseases, such as multiple sclerosis and type 1 diabetes, as well as in the development and progression of certain forms of cancers. In the present study, we have performed an immunohistochemistry analysis for the evaluation of MIF in DLE lesions and normal skin. We found high levels of MIF in the basal layer of the epidermis as well as in the cutaneous appendage (eccrine glands and sebocytes) of normal skin. In DLE lesions, we observed a significant negative correlation between the expression of MIF and the severity of inflammation. In addition, we performed an analysis of MIF and DDT expression levels in the skin of DLE patients in a publicly available microarray dataset. Interestingly, while these in silico data only evidenced a trend toward reduced levels of MIF, they demonstrated a significant pattern of expression and correlation of DDT with inflammatory infiltrates in DLE skins. Overall, our data support a protective role for endogenous MIF and possibly DDT in the regulation of homeostasis and inflammation in the skin and open up novel avenues for the treatment of DLE. 相似文献
100.
Rocco Alessio Daniela Belli Dell'Amico Fausto Calderazzo Ulli Englert Alessandro Guarini Luca Labella Peter Strasser 《Helvetica chimica acta》1998,81(2):219-230
The reaction of CuO'Bu with CO2, and iPr2NH in the presence of PPh3, gives the dialkylcarbamato complex [Cu(O2CNiPr2)(PPh3)2] ( 1 ). The CO2/R2NH system (R = Me, Et) in an appropriate organic medium reacts with Ag2O giving the corresponding N,N-dialkylcarbamato complexes of analytical formula [Ag(C2CNR2)] (R = Me, 2 ; R = Et, 3 ). The methyl derivative 2 was characterized by X-ray diffraction methods. Crystal data of 2 : for [Ag2(O2CNMe2)2], C6H12Ag2N2O4, mol. wt. 391.9; monoclinic, space group P21/c, a = 12.08(1), b = 3.797(2), c = 11.316(7) Å, β = 113.37(6)°, V = 476.3 Å3, Z = 2, Dc = 2.732 g cm?3; μ(MoKα) = 40.64 cm?1, F(000) = 376.0; R = 0.059, Rw = 0.067; g.o.f. 1.27. The structure consists of dinuclear [(Ag2OCNMe2)2] units with slightly distorted linearly two-coordinated Ag-atoms containing bridging carbamato groups to form a substantially planar eight-membered ring with an intra-annular Ag? Ag distance of 2.837(2) Å; the dinuclear units are further joined by Ag? O bonds to form an infinite array. Compound 3 , which is presumably dinuclear, as suggested by cryoscopic measurements in benzene, undergoes a structural fission with PPh3, giving the mononuclear triphenylphosphine derivative [Ag(O2CNEt2)(PPh3)2] ( 4 ). The amine-catalyzed conversion of Ag2O into Ag2CO3, in the presence of the iPr2NH/CO2 system, is also reported. Cl-Exchange from [AuCl(PPh3)] with [Ag(O2CNEt2)] ( 3 ) gives the first N,N-dialkylcarbamato complex of gold, namely [Au(O2CNEt2)(PPh3)] ( 5 ), which crystallizes in the monoclinic system: C23H25AuNO2P · 0.5 C7H16, mol. wt. 625.5, space group P21/c; a = 13.212(5), b = 12.25(1), c = 16.795(6) Å, β = 109.09(2)°, V = 2568(2) Å3, Z = 4, Dc, = 1.618 g cm?3; μ(AgKα) = 31.40 cm?1, F(000) = 1236.0; R = 0.058; Rw = 0.064; g.o.f. 2.121. The compound contains two-coordinated Au-atom, namely to the P-atom and to the O-atom of the monodentate carbamato group, the P? Au? O bond angle being 174.7(3)°. The reaction with MeI showed these compounds to react predominantly at the carbamato O-atom giving the corresponding urethanes R2NCO2Me. Evidence was gathered for the transient coordination of CO to Ag in 3 . 相似文献