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131.
Jim Bashkin Clive E. Briant D. Michael P. Mingos Robert W. M. Wardle 《Transition Metal Chemistry》1985,10(3):113-114
Summary [(Ph3P)AuCo(CO)3(PPh3)] has been synthesised from [(Ph3P)AuCo(CO)4], PPh3v and Me3NO in acetonitrile. Its molecular structure, determined by single-crystal x-ray crystallography, consists of an almost linear
P-Au-Co-P arrangement in which the Co atom is in a slightly distorted trigonalbipyramidal geometry, with the Au and P atoms
occupying the apical sites. The Au-Co bond length of 2.450(1) ? is shorter than that reported for [(Ph3P)AuCo(CO)4]. The carbonyl ligands are bent towards the Au atom and the mean Au-Co-C angle is 81(1)°. 相似文献
132.
133.
Robert F. Tichy 《Rendiconti del Circolo Matematico di Palermo》1987,36(2):332-342
LetX be a compact metric space, le μ be a non-negative normalized Borel measure onX and letf be a measurable bounded real-valued function defined onX such thatf is μ-almost everywhere continuous and different from zero. It is proved that a sequence (x n ),n=1,2, … of points inX is μ-uniformly distributed if and only if for every Borel setE?X with μ(Bd(E))=0 we have \(\mathop {\lim }\limits_{N \to \infty } \frac{1}{N}\sum\limits_{n = 1}^N {f(x_n )} 1_E (x_n ) = \int\limits_E {f(x)d\mu (x)} ,\) where 1 E denotes the characteristic function ofE andbdE the boundary ofE. Furthermore some quantitative aspects and generalizations of this theorem are discussed. 相似文献
134.
In this work, some results related to superatomic Boolean interval algebras are presented, and proved in a topological way. Let x be an uncountable cardinal. To each I
x, we can associate a superatomic interval Boolean algebra B
I of cardinality x in such a way that the following properties are equivalent: (i) I
I
x, (ii) B
I is a quotient algebra of B
J, and (iii) there is an homomorphism f from B
J into B
I such that for every atom b of B
I, there is an atom a of B
J satisfying f(a)=b. As a corollary, there are 2
x
isomorphism types of superatomic interval Boolean algebras of cardinality x. This case is quite different from the countable one. 相似文献
135.
Robert A. Leacock 《Foundations of Physics》1987,17(8):799-807
The quantum harmonic oscillator is described in terms of two basic sets of coordinates: linear coordinates x, px and angular coordinates ei, P (action-angle variables). The angular coordinate ei is assumed unitary, the conjugate momentum p is assumed Hermitian, and ei and p are assumed to be a canonical pair. Two transformations are defined connecting the angular coordinates to the linear coordinates. It is found that x, px can be physical, i.e., Hermitian and canonical, only under constraints on the p eigenvalue spectrum. The conclusion is that ei can be a unitary operator. A parallel analysis of the classical harmonic oscillator is done with equivalent results. 相似文献
136.
Robert Kosler 《Numerische Mathematik》1986,50(1):45-55
Summary Operator equationsTu=f are approximated by Galerkin's method, whereT is a monotone operator in the sense of Browder and Minty, so that existence results are available in a reflexive Banach spaceX. In a normed spaceY error estimates are established, which require a priori bounds for the discrete solutionsu
h in the norm of a suitable space
. Sufficient conditions for the uniform boundedness u
h
Z
=O(1) ash0 are proved. Well-known error estimates in [3] for the special caseX=Y=Z are generalized by this. The theory is applied to quasilinear elliptic boundary value problems of order 2m in a bounded domain
. The approximating subspaces are finite element spaces. Especially the caseX=W
0
m, p
(), 1<p<,Y=W
0
m. 2
(),Z=W
0
m. max (2,p)
()Wm, () is treated. Some examples for 1<p<2 are considered. Forp2 a refined technique is introduced in the author's paper [7]. 相似文献
137.
J Robert Huber 《Chemphyschem》2004,5(11):1663-1669
This Minireview gives an account of the photochemical decay of nitric acid HNO3 in the gas phase, which has been well investigated under bulk and molecular-beam conditions. Due to the importance of this molecule in atmospheric chemistry, attention was paid to the irradiation regions around 300 and 200 nm, where solar photolysis of HNO3 is expected to be particularly efficient. While the low-energy region is characterized by the products OH and NO2, the high-energy region gives rise to a variety of photochemical decay pathways, dominated by channels which lead to the products HONO + O in different electronic states. 相似文献
138.
D. Beese R. Steiner H. Scheer A. Angerhofer B. Robert M. Lutz 《Photochemistry and photobiology》1988,47(2):293-304
Abstract— Reaction centers from Rhodobacter sphaeroides have been modified by treatment with sodium borohydride similar to the original procedure [Ditson et al., Biochim. Biophys. Acta 766 , 623 (1984)], and investigated spectroscopically and by gel electrophoresis.
(1) Low temperature (1.2 K) absorption, fluorescence, absorption- and fluorescence-detected ODMR, and microwave-induced singlet-triplet absorption difference spectra (MIA) suggest that the treatment produces a spectroscopically homogeneous preparation with one of the 'additional' bacteriochlorophylls being removed. The modification does not alter the zero field splitting parameters of the primary donor triplet (T P870).
(2) From the circular dichroism and Raman resonance spectra in the1500–1800 cm-1 region, the removed pigment is assigned to BchlM , e.g. the "extra" Bchl on the "inactive" M-branch.
(3) A strong coupling among all pigment molecules is deduced from the circular dichroism spectra, because pronounced band-shifts and/or intensity changes occur in the spectral components assigned to all pigments. This is supported by distinct differences among the MIA spectra of untreated and modified reaction centers, as well as by Raman resonance.
(4) The modification is accompanied by partial proteolytic cleavage of the M-subunit. The preparation is thus spectroscopically homogeneous, but biochemically heterogenous. 相似文献
(1) Low temperature (1.2 K) absorption, fluorescence, absorption- and fluorescence-detected ODMR, and microwave-induced singlet-triplet absorption difference spectra (MIA) suggest that the treatment produces a spectroscopically homogeneous preparation with one of the 'additional' bacteriochlorophylls being removed. The modification does not alter the zero field splitting parameters of the primary donor triplet (
(2) From the circular dichroism and Raman resonance spectra in the1500–1800 cm
(3) A strong coupling among all pigment molecules is deduced from the circular dichroism spectra, because pronounced band-shifts and/or intensity changes occur in the spectral components assigned to all pigments. This is supported by distinct differences among the MIA spectra of untreated and modified reaction centers, as well as by Raman resonance.
(4) The modification is accompanied by partial proteolytic cleavage of the M-subunit. The preparation is thus spectroscopically homogeneous, but biochemically heterogenous. 相似文献
139.
Odd/even effect in the chain length on the enthalpy of micellization of gemini surfactants in aqueous solution 总被引:1,自引:0,他引:1
Li Y Li P Wang J Wang Y Yan H Thomas RK 《Langmuir : the ACS journal of surfaces and colloids》2005,21(15):6703-6706
The micellization properties of cationic symmetric gemini surfactants, [CmH(2m+1)(CH3)2N(CH2)6N(CH3)2CmH(2m+1)]Br2 (designated as CmC6CmBr2, with m = 7, 8, 9, 10, 11, 12, and 16), has been investigated by isothermal titration microcalorimetry. The critical micelle concentration (CMC) and enthalpy of micellization (DeltaHmic) were determined from calorimetric titration curves. The linear decreasing of log CMC with increasing the length of the hydrophobic chain is consistent with an increase in the hydrophobicity of the alkyl chain. Interestingly, with increasing the length of the alkyl chain, the DeltaHmic values of the surfactants with even numbered alkyl chains vary from endothermic to exothermic, whereas the DeltaHmic values of the surfactants with odd numbered alkyl chains are all endothermic and tend to become more endothermic. The pronounced even/odd effect in DeltaHmic is discussed with respect to the "donor-acceptor" interaction. 相似文献
140.
Sivaramakrishnan R Tranter RS Brezinsky K 《The journal of physical chemistry. A》2005,109(8):1621-1628
Density functional theory (DFT) has been used along with isodesmic reaction schemes to estimate heats of formation for aromatics and polynuclear aromatic hydrocarbons (PAHs). Calculations have been performed for 42 molecules, 12 of which have uncertain or unknown experimental values, using the B3-LYP functional with the small 6-31G(d) basis set. Heats of formation for the group of test molecules were estimated using both conventional bond separation (BS) isodesmic reactions as well as a new technique of ring conserved (RC) isodesmic reactions which is able to correct systematic errors in B3-LYP calculations. When a ring conserved isodesmic reaction based on delocalization energies is used, the estimated heat of formation is more accurate than that obtained by the bond separation technique. The methodology for creating and using appropriate ring conserved isodesmic reactions is discussed. The present scheme also compares favorably against a recently developed bond centered group additivity scheme that was tested against a large number of PAH molecules. 相似文献