Magic angle carbon-13 NMR study of solid poly(ethylene naphthalene-2,6-dicarboxylate)

Amorphous (1) and semicrystalline (2) samples of poly(ethylene naphthalene-2,6-dicarboxylate) (PEN) have been investigated by cross-polarization/magic angle spinning (CP/MAS) ¹³C NMR at 26°C (1 and 2), 100°C (1) and 120°C (2) in order to study the phase structure and the local motion of polymer chain segments at temperatures below and close to T_g (120°C). The lineshape of the ethylene unit ¹³C signal in sample 2 is consistent with the presence of two components which were assigned to trans and gauche conformations. The first component arises mainly from the crystalline regions and the second one from the amorphous part. Cross-polarization curves were traced by changing the contact time between carbon and proton reservoirs. T_CH (cross relaxation time) and proton T_1p (spin-lattice relaxation time in the rotating frame) values were obtained as best fit parameters by fitting calculated curves to the experimental data. All ¹³C NMR data are consistent with the presence of highly rigid ethylene units in both semicrystalline and amorphous samples within the temperature range (T) investigated. This result is in disagreement with the ¹H NMR wide line spectra which showed a noticeable narrowing of the linewidth with increasing temperature in the same range, hence indicating a great mobility of the chain segments. To account for this discrepancy a qualitative model based on the existence of two distinct dynamic regions, one where motion is highly restricted and the other one where large reorientations of ethylene group torsional angles take place, is suggested. The NMR results led to the conclusion that three structural phases are present in PEN: crystalline, very rigid amorphous, and very mobile amorphous. © 1995 John Wiley & Sons, Inc.     

Diffusion of interacting particles in one-dimensional heterogeneous systems

The equilibrium and transport properties of interacting ad-particles on bivariate heterogeneous chains are studied by combining analytical and simulation approaches. Heterogeneity is introduced in the way of patches of shallow and deep adsorbing sites distributed in a deterministic alternating way. Adsorption isotherms and mean-square fluctuations of the surface coverage, as well as the jump and collective diffusion coefficients, are calculated for different values of lateral interactions between ad-particles and substrate heterogeneity. In addition, different elementary jump mechanisms are introduced and their influence in the coverage dependence of the collective diffusion coefficient is investigated.     

Exact Statics and Approximate Dynamics of Adhering Lipid Tubules

In this paper we are concerned with the adhesion of lipid tubules to a plane wall: we treat both the statics and the dynamics of this phenomenon. Though we provide an exact solution to the equilibrium problem, our treatment of the dynamical problem is approximate, as it is based on a simplified model, which, nevertheless allows us to obtain quantitative information about the detachment dynamics of tubules. Received September 1, 1997     

Experimental determination of cw dye laser parameters by loss variation

The behavior of a cw dye laser under variation of the output coupling has been investigated. By studying the dependence of laser threshold, output power and slope efficiency on the degree of outcoupling, numerical values for macroscopic and microscopic laser parameters have been obtained. The macroscopic data comprise values for internal cavity losses and mode matching conditions, the microscopic data refer to molecular parameters of the dye used, such as cross-sections for stimulated emission and triplet-triplet absorption.     

A bimetric machian approach to gravitation

We propose a bimetric machian approach to gravitation with a mathematical structure much simpler than the one of Rosen's bimetric theories. We obtain two cosmological models based on the simplest assumption that the Universe be filled of pure dust matter. One of the two cosmological models is compatible with the currently observed value of the density of dust matter, and provides an age of the Universe which is of the order of the inverse of the present Hubble parameter. One also obtains the Schwarzschild-like solution and its Newtonian limit together with the modified three Kepler laws which allow us to find that presently 0.5×10^?10 (yr)^?1 δ(A/A)δ 0.625×10^?10 (yr)^?1, a denoting the semimajor axis of the orbit of the test particle. Lastly we obtain the Newtonian limit of the theory.     

Mouse brain expression patterns of <Emphasis Type="Italic">Spg7</Emphasis>, <Emphasis Type="Italic">Afg3l1</Emphasis>, and <Emphasis Type="Italic">Afg3l2</Emphasis> transcripts,encoding for the mitochondrial <Emphasis Type="Italic">m</Emphasis>-AAA protease

Background  

The m-AAA (ATPases Associated with a variety of cellular Activities) is an evolutionary conserved metalloprotease complex located in the internal mitochondrial membrane. In the mouse, it is a hetero-oligomer variably formed by the Spg7, Afg3l1, and Afg3l2 encoded proteins, or a homo-oligomer formed by either Afg3l1 or Afg3l2. In humans, AFG3L2 and SPG7 genes are conserved, whereas AFG3L1 became a pseudogene. Both AFG3L2 and SPG7 are involved in a neurodegenerative disease, namely the autosomal dominant spinocerebellar ataxia SCA28 and a recessive form of spastic paraplegia, respectively.