Preparation and characterization of microcapsules loaded with polyphenols-enriched Uncaria tomentosa extract using spray-dryer technique

Journal of Thermal Analysis and Calorimetry - This work prepared and characterized microcapsule of Uncaria tomentosa (UT) in order to standardize a spray-dryer Uncaria tomentosa extract. The UT...     

Room Temperature Ionic Liquids in Asymmetric Hetero-Ene Type Reactions: Improving Organocatalyst Performance at Lower Temperatures

Room temperature ionic liquids (RTILs) have been widely used as (co)solvents in several catalytic processes modifying, in most of the cases, the catalyst activity and/or the selectivity for the studied reactions. However, there are just a few examples of their use in hydrogen bonding organocatalysis. In this paper, we show the positive effect of a set of imidazole-based ionic liquids ([bmim]BF₄ and [hmim]PF₆) in the enantioselective addition of formaldehyde tert-butylhydrazone to prochiral α-keto esters catalyzed by a sugar-based chiral thiourea. Reactions performed in the presence of low percentages of RTILs led to an increase of the catalyst activity, thereby making possible to work at lower temperatures. Thus, the chiral tert-butyl azomethyl tertiary alcohols could be obtained with moderate to good conversions and higher enantioselectivities for most of the studied substrates when using up to 30 vol% of [hmim]PF₆ as a cosolvent in processes performed in toluene.     

Slow dynamics in a turbulent von Kármán swirling flow

An experimental study of a turbulent von Kármán flow in a cylinder is presented. The mean flow is stationary up to a Reynolds number Re=10(4) where a bifurcation takes place. The new regime breaks some symmetries of the problem and becomes time dependent because of equatorial vortices moving with a precession movement. In the exact counterrotating case, a bistable regime appears and spontaneous reversals of the azimuthal velocity are registered. A three-well potential model with additive noise reproduces this dynamic. A regime of periodic response is observed when a very weak forcing is applied.     

Measurement of tensor analyzing powers in deuteron photodisintegration

A new accurate measurement of the tensor analyzing powers T20, T21, and T22 in deuteron photodisintegration has been performed. Wide-aperture nonmagnetic detectors allowed broad kinematic coverage in a single set up: E(gamma)=25 to 600 MeV, and theta(p)(cm)=24 degrees to 48 degrees and 70 degrees to 102 degrees . The new data provide a significant improvement over the few existing measurements. The angular dependency of the tensor asymmetries in deuteron photodisintegration is extracted for the first time.     

Static and dynamic heterogeneities in a model for irreversible gelation

We study the structure and the dynamics in the formation of irreversible gels by means of molecular dynamics simulation of a model system where the gelation transition is due to the random percolation of permanent bonds between neighboring particles. We analyze the heterogeneities of the dynamics in terms of the fluctuations of the self-intermediate scattering functions: in the sol phase close to the percolation threshold, we find that this dynamic susceptibility increases with the time until it reaches a plateau. At the gelation threshold this plateau scales as a function of the wave vector k as k(eta-2), with eta being related to the decay of the percolation pair connectedness function. At the lowest wave vector, approaching the gelation threshold it diverges with the same exponent gamma as the mean cluster size. These findings suggest an alternative way of measuring critical exponents in a system undergoing chemical gelation.     

Production of ball-lightning-like luminous balls by electrical discharges in silicon

We performed electric arc discharges in pure Si to generate luminous balls with lifetime in the order of seconds and several properties usually reported for natural ball lightning. This simple experiment does not rely on energy sources and excitation mechanisms that are improbable in the natural phenomenon and clearly demonstrates the role of vaporization and oxidation of Si, as proposed by the Abrahamson-Dinniss theory for ball-lightning formation.     

Numerical experiments on quantum chaotic billiards

A recently proposed numerical technique for generation of high-quality unstructured meshes is combined with a finite-element method to solve the Helmholtz equation that describes the quantum mechanics of a particle confined in two-dimensional cavities. Different shapes are treated on equal footing, including Sinai, stadium, annular, threefold symmetric, mushroom, cardioid, triangle, and coupled billiards. The results are shown to be in excellent agreement with available measurements in flat microwave resonator counterparts with nonintegrable geometries.     

Angle-resolved three-dimensional analysis of surface films by coherence scanning interferometry

The Fourier components of interference signals generated by scanning a high-numerical-aperture objective orthogonal to an object surface correspond to different angles of incidence on the surface. The phase and amplitude of these Fourier components relate to the structure of the object, including in particular the 3D topography and thickness profiles of thin-film layers.     

Theory of the time reversal cavity for electromagnetic fields

We derive a general expression of the electric dyadic Green function in a time-reversal cavity, based on vector diffraction theory in the frequency domain. Our theory gives a rigorous framework to time-reversal experiments using electromagnetic waves and suggests a methodology to design structures generating subwavelength focusing after time reversal.