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Molecular dynamics simulation has been used in exploring the crystal nucleation behaviour of a single chain touching a substrate surface. It shows that a polyethylene chain (980 CH2) changed its overall shape from an isotropic coil to an oriented one in the case of touching a substrate surface of amorphous carbons at 300 K. Most repeats of the chain were aligned and ordered in a zigzag package. Surprisingly, the direction of the package is not parallel to the plane of the substrate, but almost perpendicular to it. This is in accordance with experimental observations. 相似文献
43.
Renyuan Qian Zhicai Wu Zhaohong Xue Ruifang Yan 《Macromolecular rapid communications》1995,16(1):19-23
The length of chain segment motion needed for the crystallization of guttapercha from rubbery state was found to be around 180 C C bonds of the backbone chain. Thus, the crystallization process from the rubbery state or from the melt is not through chain folding, and the solidification model is a more appropriate physical picture of the process. 相似文献
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The phenomenon of band texture formation of sheared main chain liquid crystalline polymers is reviewed. The bands seen in a polarizing microscope are optical effects. The macromolecular chains are aggregated into zig-zag bent fibrils perpendicular to the bands. The band texture is formed during shear relaxation. The induction period depends on the shear rate applied, the shearing time, solution concentration (lyotropic), solution layer thickness, temperature and the nature of the polymer. There exists a critical shear deformation to bring a multi-domain nematic or cholesteric phase into a monodomain continuous phase, from which the band texture is formed. These two phases show quite different rheological behavior. In certain cases randomly oriented regions of bands can also be formed during quenching of a thermotropic nematic polymer melt or during standing of a lyotropic nematic polymer solution, where the nematic domains in the melt or in the solution have grown to a sufficient size. 相似文献
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高温相变储能换热器中传热模型的研究 总被引:2,自引:1,他引:1
1前言利用相变材料在发生相变时有很高的潜热释放或吸收的特点,将相变材料作为储热介质用于相变储能换热器中,可以大大地提高热储存的容量。本文研究的这种壳管式相变储能换热器壳内布置换热管,管壳之间填充高温储热材料,管内通以空气作为热交换流体提取储存在相变材料中的热量。定义输出功率为单位时间内热交换流体所提取到的热量,那么输出功率就成为评价这类换热器换热性能的指标。2理论模型的建立下面几点,概括了求解本文相变储能装置中传热问题的特点:a.相变储能换热器的壳侧填充的AI-Si合金属高温相变储能材料,实验始末其温… 相似文献
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以红霉素为模板分子,甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂,在水相中采用悬浮聚合法制备了红霉素分子印迹聚合物微球。利用扫描电镜对其表面形貌进行了表征,探讨了不同分散剂浓度、水油比、搅拌速度等参数对聚合物微球粒径及粒径分布的影响,重点对聚合工艺进行了优化,并将所得的聚合物用作吸附剂研究了其分子识别与选择性能。研究表明,该方法合成的聚合物微球平均粒径为40~130μm,对模板分子具有较高吸附性能和选择性识别能力,其分离因子达1.83,而动态吸附饱和吸附量则达到了42.59μmol/g。 相似文献
49.
This work presents the effect of elastic anisotropy and disclination interaction on wedge disclinations in the nematic phase of thermotropic polymers, by combining experimental measurements, (this paper part I), with numerical simulation (part II [1]). In part I, the decoration provided by spontaneous banded texture gives much information about the defect structure of polymeric nematics. Working with a semi-rigid polyester, the optical images of +1/2 disclinations revealed by banding enable the distortion to be determined as a function of polar coordinates from the cores. Continuum theory allows the apparent elastic anisotropy, εa, of bend and splay constants of the copolyester to be determined from the distortion measurement. The values of εa, are seen to vary greatly in the range -1 to +1 between different +1/2 disclinations in the same sample. The statistics of the measurement indicate that the distribution of the values of εa is random. The implication of these observations is that the curvature of wedge disclinations is affected not only by the elastic anisotropy of the material, but also by other factors. The possible reasons are discussed: the interaction of neighbouring disclinations has been numerically analysed to be the predominant factor in [1]. This work also implies that values of the intrinsic elastic anisotropy obtained by measuring the distortion of individual wedge disclinations must be viewed with some circumspection. 相似文献
50.
Wan Meixiang Wang Ping Cao Yong Qian Renyuan Wang Fosong Zhao Xiaojian Gong Zhi 《Solid State Communications》1983,47(10):759-761
The true metallic temperature dependence of the conductivity of various doped polyacetylene films of both fibrillar and granular morphology has been experimentaly demonstrated by voltage shorted compaction measurements. 相似文献