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31.
Back Cover: Formal Total Synthesis of Diazonamide A by Indole Oxidative Rearrangement (Chem. Eur. J. 31/2016)
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32.
Starting with the Vlasov-Boltzmann equation for a binary fluid mixture, we derive an equation for the velocity field u when the system is segregated into two phases (at low temperatures) with a sharp interface between them. u satisfies the incompressible Navier-Stokes equations together with a jump boundary condition for the pressure across the interface which, in turn, moves with a velocity given by the normal component of u. Numerical simulations of the Vlasov-Boltzmann equations for shear flows parallel and perpendicular to the interface in a phase segregated mixture support this analysis. We expect similar behavior in real fluid mixtures. 相似文献
33.
Raffaele Battistuzzi 《Polyhedron》1985,4(6):933-941
Contrary to earlier reports in which no adducts of Co(II) metal ion with 4,6-dimethylpyrimidine-2(1H)-thione(HL) could be isolated starting from Co(ClO4)2 · 6H2O, we now report bis- and tris-ligand Co(II) complexes of the type [Co(HL)2(H2O)2]X2 · H2O (X = ClO4, BF4), [Co(HL)2NO3]NO3, [Co(HL)2SO4] · 0.5H2O and [Co(HL)3]X2 · 0.5H2O (X = ClO4, BF4). They have been synthesized by refluxing 2:1 and 3:1 mixtures of HL and CoX2 · nH2O in ethanol-triethyl orthoformate. We also describe new Co(HL)2X2 · nH2O complexes in which for X2 = ClBr, ClI and BrI, n = 2; for X2 = I2, n = 1 and for X2 = (SCN)2, n = 0. Structural characterization of the complex species is made from electronic and vibrational spectra, magnetic susceptibility measurements in the solid state and conductivity measurements in DMF solution. The magnetic and electronic spectral data together with ligand-field parameters suggest a pseudo-octahedral environment for all the Co(II) complexes, with the exception of Co(HL)2SO4 · 0.5H2O in which the Co(II) ion appears to be pentacoordinated. The IR spectra are consistent with a coordination involving N,S-chelation of the ligand through the non-protonated ring nitrogen atom and the exocyclic sulphur atom. 相似文献
34.
Synthesis of Pseudocyphellarins A and B, Two Depsides from the Lichen Pseudocyphellaria endochrysea The total synthesis of the depsides pseudocyphellarin A (= 3-hydroxy-4-methoxycarbonyl-2,5,6-trimethyl-phenyl 3-formyl-2,4-dihydroxy-5,6-dimethylbenzoate; 11 ) and pseudocyphellarin B (3-hydroxy-4-methoxycarbonyl-2,5,6-trimethylphenyl 2,4-dihydroxy-3-hydroxymethyl-5,6-dimethyl benzoate; 12 ) is described. 相似文献
35.
Raffaele Cerulli Paola Festa Giancarlo Raiconi 《Computational Optimization and Applications》2003,26(2):191-208
In this paper, the problem of finding a shortest path tree rooted at a given source node on a directed graph (SPT) is considered. A new efficient algorithm based on a primal-dual approach is presented, which improves both the convergence and the complexity of the best known auction-like algorithm. It uses the virtual source (VS) concept based on the following consideration: when a node i is visited for the first time by any algorithm which preserves verified the dual admissibility conditions, then the shortest path (SP) from the source node to i is found. Therefore, the SP from the source to the remaining nodes may be computed by considering i as a virtual source.We propose a very efficient implementation of an auction-like algorithm that uses this concept and enables us to obtain a computational cost of O(n
2), where n is the number of nodes.Numerical experimentsare reported showing that the new method outdoes previously proposed auction-like algorithms and is highly competitive with other state-of-art SP approaches. 相似文献
36.
Raffaele Cimmino 《Fresenius' Journal of Analytical Chemistry》1899,38(7):429-431
Ohne Zusammenfassung 相似文献
37.
Jean-Marc Renaud Georges Tsoupras Helen Stoeckli-Evans Raffaele Tabacchi 《Helvetica chimica acta》1989,72(6):1262-1267
The novel allenic epoxycyclohexanes 1 , and related compounds 2 and 3 have been isolated from the culture medium of Eutypa lata. Their structures were established by combination of spectroscopic and chemical techniques. Biogenetic origin and biological activity of these compounds are also discussed. 相似文献
38.
39.
Dragonetti R Ianniello C Romano RA 《The Journal of the Acoustical Society of America》2011,129(2):753-764
Air-flow resistivity is a main parameter governing the acoustic behavior of porous materials for sound absorption. The international standard ISO 9053 specifies two different methods to measure the air-flow resistivity, namely a steady-state air-flow method and an alternating air-flow method. The latter is realized by the measurement of the sound pressure at 2 Hz in a small rigid volume closed partially by the test sample. This cavity is excited with a known volume-velocity sound source implemented often with a motor-driven piston oscillating with prescribed area and displacement magnitude. Measurements at 2 Hz require special instrumentation and care. The authors suggest an alternating air-flow method based on the ratio of sound pressures measured at frequencies higher than 2 Hz inside two cavities coupled through a conventional loudspeaker. The basic method showed that the imaginary part of the sound pressure ratio is useful for the evaluation of the air-flow resistance. Criteria are discussed about the choice of a frequency range suitable to perform simplified calculations with respect to the basic method. These criteria depend on the sample thickness, its nonacoustic parameters, and the measurement apparatus as well. The proposed measurement method was tested successfully with various types of acoustic materials. 相似文献
40.