Boric acid as an efficient catalyst for the synthesis of 1,1-diacetate under solvent-free condition

Boric acid (BO₃H₃) is an inexpensive, efficient and mild catalyst for the synthesis of 1,1-diacetate (acylal) from the various aromatic and heteroaryl aldehydes with acetic anhydride at room temperature under solvent-free condition. The present method does not involve any hazardous organic solvents or catalysts. This method gives notable advantages such as excellent chemoselectivity, mild reaction condition, short reaction times and excellent yield.     

A New Cycloartane Triterpene Glycoside from Souliea vaginata

Souliea vaginata (Maxim.) Franch. (Ranunculaceae) is widely distributed in the southwest and northwest of China. It possesses anti-inflammatory analgesic functions as a well-known Chinese folk medicine. Its rhizomes or the whole plant are used to treat conjunctivitis, stomatitis, pharyngitis, enteritis, and diarrhea1. Previously, we have reported the isolation and structural elucidation of suolieasides A-C from the ethanol extract of the rhizomes of this plant2. In our further investigation…     

The influence of impurity on the critical thickness of the CeO_2 buffer layer for coated conductors

The lattice parameters, band structure, density of state and elastic constant of RE-doped CeO2 (RE=Sm, Gd, Dy), the buffer material for coated HTS conductors, are calculated using the plane-wave method with pseudopotentials based on the density functional theory (DFT) of first-principle. The rule and mechanism of the effect of rare earth impurity on the critical thickness of the CeO2 buffer layer are investigated. It is found that, in the range of the calculation, the changes of the lattice volume V and ela...     

Synthesis of 17-OH-Isosteviol

Stevioside(1), an ent-kaurene glycoside commer-cially extracted from Stevia rebaudiana Bertoni[1] is used as a non-caloric sweetener for food in many countries[2]. The increasing demand for low calory and natural food contributes to the increasing popularity of     

杂交稻种宜香725纯度的可见-近红外反射光谱鉴定

提出了一种基于可见-近红外光谱技术快速、无损鉴定杂交稻种纯度的新方法.以FieldSpec(R)3地物光谱仪采集纯度在90%～99%范围内的杂交稻种(宜香725)光谱数据90份,随机分成校正集(75份)和检验集(15份).根据其在380～2 400 nm的反射光谱,以偏最小二乘算法(PLS)建立了回归模型,并比较了不同光谱预处理方法对模型的影响.分析表明采用一阶导数结合标准归一化处理能最有效地提取光谱信息,此时PLS模型校正集决定系数与检验集决定系数分别为0.988 4与0.922 7,校正标准误差(SEC)与预测标准误差(SEP)分别为0.002 5与0.006 6.将经一阶导数结合标准归一化处理后的光谱进行PCA降维,以前20个主成份(含原始光谱86.09%的特征信息)为输入变量,建立杂交稻种纯度鉴定的BP-ANN模型.分析表明BP-ANN模型校正集决定系数与检验集决定系数分别为0.995 2与0.936 9,SEC与SEP分别为0.001 7与0.006 1,具有比PLS模型更高的精度.结果表明以可见-近红外技术进行杂交稻种纯度的快速、无损鉴定是可行的,且PCA结合BP-ANN是一种优选方法.     

YBCO在热冲击条件下的失超特性研究

在实际的超导电力装置运行过程中,超导带材可能由于电力系统中诸如系统短路故障等各种动态过程,承受短路大电流、不平衡电流的冲击,以及由此而产生的电磁、机械应力、热量的作用而失超,因此,研究热冲击对超导材料性能的影响对超导电力装置失超保护非常重要.本文以第二代高温超导(YBCO)带材为样品,模拟实际超导电力装置中带材的绝热环境,通过外加电源对超导带材进行热冲击,研究YBCO带材在不同情况的热冲击条件下的失超过程以及带材温度和超导性能的变化.试验结果表明:对于美国Superpower公司生产的YBCO工程带材,瞬时温度超导300K后,带材的临界电流下降,瞬时温度超过500K,带材可能出现烧断现象.     

Nonlinear properties of fractal growth of thin films at low temperature

Introduction 'The physics of thin film growth has been a topic of much current illterest. The application ofimproved and novel surfaCe science techniques such as field ion microscopy (FIM) and scanningtunneling microscopy (STM), has indeed revealed many atomic details of the film growthlll.A variety of fractal and dendritic structures have been observed in thin-film systemst2-7]. Forexample, STM images Of An on Ru(0001) grown at room temperatureI2] and Pt or Ag growthon Pt(111) at low…     

光谱多元校正中的模型传递

本文介绍了解决化学计量学多校正中的模型传递问题的原理和一些常用算法,并对目前模型传递的实际应用进行评述,为以后深入研究并完善模型传递理论与算法提供帮助。     

荧光法研究司帕沙星与白蛋白的作用

本文用荧光光谱法、分光光度法研究了水溶液中喹诺酮类药物司帕沙星与牛血清白蛋白 (BSA)、鸡蛋白 (CEA)的相互作用 ,求得它们间的结合常数为K鸡 =8 2 9× 10 6,K牛 =4 41× 10 7;结合位点数分别为n鸡=0 5 88,n牛 =0 793,并根据F rster非辐射能量转移机制 ,测定了司帕沙星与两种血清白蛋白相互结合时其给体 受体间距离 (R鸡 =1 99nm ,R牛 =2 0 9nm)和能量转移效率 (E鸡 =0 76 6 ,E牛 =0 714)。实验表明 ,随着温度升高 ,BSA及CEA的猝灭曲线斜率降低 ,证实了司帕沙星与BSA和CEA的相互结合作用为单一的静态猝灭过程 ,其作用机制属能量转移机制。通过两种血清白蛋白与抗菌药物司帕沙星结合反应 ,探讨了药物司帕沙星在生物体内与蛋白质的相互作用的生物学效应及其作用机理。     

新型吡咯甲川-BF2化合物的光谱和激光性能研究

合成了6个最大吸收波长位于517nm-524nm的新型吡咯甲川－BF2化合物,测量了它们在无水乙醇溶液中的电子吸收光谱,测试结果表明,6个化合物的激光性能全部优于若丹明6G。