全文获取类型
收费全文 | 6502篇 |
免费 | 893篇 |
国内免费 | 890篇 |
专业分类
化学 | 4864篇 |
晶体学 | 79篇 |
力学 | 370篇 |
综合类 | 59篇 |
数学 | 790篇 |
物理学 | 2123篇 |
出版年
2024年 | 24篇 |
2023年 | 92篇 |
2022年 | 174篇 |
2021年 | 212篇 |
2020年 | 217篇 |
2019年 | 225篇 |
2018年 | 211篇 |
2017年 | 186篇 |
2016年 | 303篇 |
2015年 | 275篇 |
2014年 | 339篇 |
2013年 | 476篇 |
2012年 | 497篇 |
2011年 | 522篇 |
2010年 | 375篇 |
2009年 | 364篇 |
2008年 | 431篇 |
2007年 | 383篇 |
2006年 | 394篇 |
2005年 | 298篇 |
2004年 | 281篇 |
2003年 | 243篇 |
2002年 | 260篇 |
2001年 | 193篇 |
2000年 | 186篇 |
1999年 | 159篇 |
1998年 | 123篇 |
1997年 | 109篇 |
1996年 | 80篇 |
1995年 | 95篇 |
1994年 | 80篇 |
1993年 | 65篇 |
1992年 | 63篇 |
1991年 | 38篇 |
1990年 | 51篇 |
1989年 | 26篇 |
1988年 | 24篇 |
1987年 | 20篇 |
1986年 | 34篇 |
1985年 | 28篇 |
1984年 | 21篇 |
1983年 | 17篇 |
1982年 | 14篇 |
1981年 | 12篇 |
1980年 | 7篇 |
1979年 | 11篇 |
1977年 | 4篇 |
1974年 | 9篇 |
1973年 | 7篇 |
1969年 | 4篇 |
排序方式: 共有8285条查询结果,搜索用时 31 毫秒
11.
Xin‐Gui Li Run‐Feng Chen Mei‐Rong Huang Mei‐Fang Zhu Qun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2073-2092
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004 相似文献
12.
A Nafion-modified glassy carbon electrode incorporated with tobramycin for the voltammetric stripping determination of Cu2+ has been explored. The electrode was fabricated by tobramycin containing Nafion on the glassy carbon electrode surface. The modified electrode exhibited a significantly increased sensitivity and selectivity for Cu2+ compared with a bare glassy carbon electrode and the Nafion modified electrode. Cu2+ was accumulated in HAc-NaAc buffer (pH 4.6) at a potential of -0.6 V (vs. SCE) for 300 s and then determined by differential pulse anodic stripping voltammetry. The effects of various parameters, such as the mass of Nafion, the concentration of tobramycin, the pH of the medium, the accumulation potential, the accumulation time and the scan rate, were investigated. Under the optimum conditions, a linear calibration graph was obtained in the concentration range of 1.0 x 10(-9) to 5.0 x 10(-7) mol l(-1) with a correlation coefficient of 0.9971. The relative standard deviations for eight successive determinations were 4.3 and 2.9% for 1.0 x 10(-8) and 2.0 x 10(-7) mol l(-1) Cu2+, respectively. The detection limit (three times signal to noise) was 5.0 x 10(-10) mol l(-1). A study of interfering substances was also performed, and the method was applied to the direct determination of copper in water samples, and also in analytical reagent-grade salts with satisfactory results. 相似文献
13.
Study on the Superhydrophilicity of the SiO2-TiO2 Thin Films Prepared by Sol-Gel Method at Room Temperature 总被引:2,自引:0,他引:2
Dasen Ren Xiaoli Cui Jie Shen Qun Zhang Xiliang Yang Zhuangjian Zhang Lu Ming 《Journal of Sol-Gel Science and Technology》2004,29(3):131-136
Nanoscale SiO2-TiO2 composite thin films with the thickness of about 100 nm were prepared by sol-gel method at room temperature in air. The chemical states of the elements on the surface and near the surface were measured by XPS. The results showed that the Ti on/near the surface of the thin films existed not only as TiO2 but also as Ti2O3. Part of the TiO2 was changed to Ti2O3 after UV irradiation. The crystalline structure of the TiO2 in the SiO2-TiO2 thin films was anatase with the crystallite size of 14–20 nm. It was found that the thin film prepared at room temperature in air has good superhydrophilic property and has strong adherence to the substrate. 相似文献
14.
Cr3+:MgAl2O4晶体EPR参量及其电子精细光谱的研究 总被引:4,自引:0,他引:4
考虑了SS(Spin-Spin)作用和SOO(Spin-Other-Orbit)作用,采用完全对角化方法,结合自旋Hamiltonian理论,研究了Cr3+∶MgAl2O4晶体EPR参量及其吸收光谱,理论与实验符合甚好. 在此基础上,进一步研究了4A2(3d3)离子EPR参量的微观起源. 研究表明,EPR参量起源于四种微观机制:(1) SO(Spin-Orbit) 耦合机制;(2) SS耦合机制;(3)SOO耦合机制;(4) SO~SS~SOO总联合作用机制. 在这些机制中,SO机制是最主要的. 相似文献
15.
16.
研究了多壁碳纳米管(MWNTs)薄膜的湿敏特性,实验所用的多壁碳纳米管是用热灯丝化学气相沉积法(CVD)合成的.分别对未修饰和修饰的多壁碳纳米管膜温度和湿度特性进行研究后发现,修饰的多壁碳纳米管对温度和湿度非常敏感,且对湿度的响应时间和恢复时间短,重复性好.而未修饰的多壁碳纳米管对温度和湿度不太敏感.对修饰多壁碳纳米管的湿敏特性进行了理论分析,给出了其理论表示式.
关键词:
多壁碳纳米管
化学修饰
湿敏特性
物理吸附 相似文献
17.
DongXiangLI WanGuoHOU ShuPingLI MingTuHAO GaoYongZHANG 《中国化学快报》2004,15(2):224-227
The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations. 相似文献
18.
Daqing Wan 《Inventiones Mathematicae》1998,133(2):449-463
A quadratic bound is obtained for a conjecture of Gouvêa-Mazur on arithmetic variation of dimensions of classical and p-adic modular forms.
Oblatum 22-VIII-1996 & 8-X-1997 相似文献
19.
本文介绍了EltctronicWorkbench软件和计算机虚拟仪器系统,采用计算机模拟仿真技术对电子线路实验加以辅助设计和探索。 相似文献
20.
属性区间识别理论模型研究及其应用 总被引:15,自引:3,他引:12
根据程乾生教授创立的属性识别理论模型[1] ,提出了属性测度区间的概念 ,建立了属性区间识别理论模型 ,并在自然科学学术期刊质量评价中进行了应用 . 相似文献