铈掺杂高密度硼硅酸盐玻璃光谱性质研究

实验制备了一种密度为5.2 g.cm-3的高密度铈离子掺杂硼硅酸盐闪烁玻璃,该玻璃具有较高的析晶稳定性。测试了该闪烁玻璃的激发和发射光谱,其峰值波长分别对应于325和385 nm,斯托克斯位移为60 nm。当氧化铈掺杂浓度小于1%(质量分数)时,325 nm激发下的发射光谱强度随浓度的增加而提高,而掺杂浓度的进一步提高,由于三价态铈离子的自吸收等吸收猝灭效应导致380 nm的发射强度出现严重降低。掺杂1%(质量分数)的玻璃样品经245Gy的伽马射线辐照后,其可见波段的透过率并未出现明显降低,说明该玻璃具有较好的耐辐照性能。     

Existence of infinitely many large solutions for the nonlinear Schrödinger-Maxwell equations

In this paper, we study the nonlinear stationary Schrödinger-Maxwell equations

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Ladder-Type Heteroheptacenes with Different Heterocycles for Nonfullerene Acceptors

The design, synthesis, and characterization of two novel nonfullerene acceptors (M8 and M34) based on ladder-type heteroheptacenes with different heterocycles are reported. Replacing the furan heterocycles with the thiophene heterocycles in the heteroheptacene backbone leads to a hypsochromically shifted absorption band and greatly improved carrier transport for the resulting nonfullerene acceptor (M34) although the π–π-stacking distances are barely affected. Bulk-heterojunction polymer solar cells fabricated from M34 and a wide band gap polymer (PM6) as the donor showed a best power conversion efficiency (PCE) of 15.24 % with an open circuit voltage (V_OC) of 0.91 V, much higher than a PCE of 4.21 % and a V_OC of 0.83 V for the counterparts based on M8:PM6. These results highlight the importance of key atoms in the construction of high-performance nonfullerene acceptors.     

液体表面张力系数测定仪器的改进

对FD-NST-I型液体表面张力系数测定仪进行了改进,把单金属吊环改为用绝缘体接起的入水通电吊环,把玻璃容器更换为双层变温水池,利用STM32来进行力敏传感器数据的输出和对液体温度的控制,可以有效地减小误差和更好研究温度对此液体表面张力系数的影响.     

表面双重后处理方法提升三元NiMgO半导体界面层及其有机太阳能电池的性能※

采用溶胶-凝胶法制备了Mg掺杂氧化镍(NiO)的三元氧化物半导体NiMgO薄膜, 研究了不同表面后处理方法对薄膜结构、性质和能级的影响. 利用NiMgO薄膜作为新型空穴传输界面层构建了非富勒烯有机太阳能电池, 研究了器件性能变化及其物理机制. 结果表明, 以未表面处理NiMgO为界面层时, 器件的能量转化效率(PCE)为5.90%; 使用紫外-臭氧(UVO)表面后处理的NiMgO界面层, 器件PCE大幅提升至12.67%. 而NiMgO在UVO处理前进行润洗, 可以去除表面残留物, 薄膜变平整且透光率增加. 因此, 采用润洗与UVO结合的表面双重后处理新策略后, 器件的开路电压不变, 但短路电流密度和填充因子分别提高到23.48 mA•cm^–2和64.29%, 最终PCE达到13.17%. 该研究为半导体氧化物薄膜及器件的优化提供了一条有效途径.     

FCT有限元法数值求解三维可压缩高速无粘流问题

从Euler方程出发,利用流量修正有限元法(FEM-FCT)求解三维无粘流动的高速流场。通过对圆球、简化航天飞机和双子星座飞船返回舱外形的数值模拟证明,这种方法对激波有较高的分辨能力,是一种有效的方法。     

农机化对农业经济发展影响程度的分析

本文利用统计数据，对影响农业经济发展的诸因素进行了分段关联分析。结果表明了农业机械化对农业经济发展的作用逐步增大。根据关联度所确定的判断矩阵进行层次分析，也得出同样的结论。     

A Comparison and Unification of Ellipsoidal Statistical and Shakhov BGK Models

The Ellipsoidal Statistical model (ES-model) and the Shakhov model (S-model) were constructed to correct the Prandtl number of the original BGK model through the modification of stress and heat flux. With the introduction of a new parameter to combine the ES-model and S-model, a generalized kinetic model can be developed. This new model can give the correct Navier-Stokes equations in the continuum flow regime. Through the adjustment of the new parameter, it provides abundant dynamic effect beyond the ES-model and S-model. Changing the free parameter, the physical performance of the new model has been tested numerically. The unified gas kinetic scheme (UGKS) is employed for the study of the new model. In transition flow regime, many physical problems, i.e., the shock structure and micro-flows, have been studied using the generalized model. With a careful choice of the free parameter, good results can be achieved for most test cases. Due to the property of the Boltzmann collision integral, the new parameter in the generalized kinetic model cannot be fully determined. It depends on the specific problem. Generally speaking, the S-model predicts more accurate numerical solutions in most test cases presented in this paper than the ES-model, while ES-model performs better in the cases where the flow is mostly driven by temperature gradient, such as a channel flow with large boundary temperature variation at high Knudsen number.