Ab initio calculations on the spectroscopic constants, vibrational levels and classical turning points for the 21∏u state of dimer 7Li2

The accurate dissociation energy and harmonic frequency for the highly excited 2^1Пu state of dimer ^7Li2 have been calculated using a symmetry-adapted-cluster configuration-interaction method in complete active space. The calculated results are in excellent agreement with experimental measurements. The potential energy curves at numerous basis sets for this state are obtained over a wide internuclear separation range from about 2.4a0 to 37.0a0. And the conclusion is gained that the basis set 6-311＋＋G（d,p） is a most suitable one. The calculated spectroscopic constants De, Re, ωe, ωeχe, ae and Be at 6-311＋＋G（d,p） are 0.9670 eV, 0.3125 nm, 238.6 cm^-1, 1.3705 cm^-1, 0.0039 cm^-1 and 0.4921 cm^-1, respectively. The vibrational levels are calculated by solving the radial SchrSdinger equation of nuclear motion. A total of 53 vibrational levels are found and reported for the first time. The classical turning points have been computed. Comparing with the measurements, in which only the first nine vibrational levels have been obtained so far, the present calculations are very encouraging. A careful comparison of the present results of the parameters De and We with those obtained from previous theories clearly shows that the present calculations are much closer to the measurements than previous theoretical results, thus representing an improvement on the accuracy of the ab initio calculations of the potentials for this state.     

Broadband and high efficiency metal multi-layer dielectric grating based on non-quarter-wave coatings as a reflective mirror

This article deals with designing a broadband and high efficiency metal multi-layer dielectric grating (MMDG) used to compress and stretch an ultrashort laser pulse. The diffraction characteristics of the MMDG are analysed by using the rigorous coupled-wave method. The multi-layer dielectric used as the reflective mirror is made up of non- quarter-wave coatings. Taking the diffraction efficiency of the 1 order as the value of merit function, the parameters such as groove depth, residual thickness, duty cycle, and reflective mirror are optimized to obtain broadband and high diffraction efficiency. The optimized MMDG shows an ultra-broadband working spectrum with the average efficiency exceeding 97% over 160 nm wavelength centred at 1053 nm and TE polarization. The optimized MMDG should be useful for chirped pulse amplification.     

Sr位Nd掺杂对SrBi$lt;sub$gt;2$lt;/sub$gt;Nb$lt;sub$gt;2$lt;/sub$gt;O$lt;sub$gt;9$lt;/sub$gt;性能的影响及机理研究

采用传统固相法制备了（Sr_1-3x/2A_x/2Nd_x）Bi₂Nb₂O₉（x=0,0.05,0.1和0.2）陶瓷,并系统研究了Nd离子取代Sr离子对SrBi₂Nb₂O₉性能的影响及其作用机理.研究结果表明：Sr_1-3x/2A_x/2Nd_xBi₂Nb₂O₉的介电常数和介电损耗随温度变化的行为具有明显的离子松弛极化特征.Nd³⁺对Sr²⁺的部分取代,导致Sr_1-3x/2A_x/2Nd_xBi₂Nb₂O₉剩余极化强度P_r稍有下降,但其压电系数d₃₃却有所增加,根据铁电热力学理论,这是Nd³⁺对Sr²⁺取代导致材料介电常数增大所致.Sr_1-3x/2A_x/2Nd_xBi₂Nb₂O₉的居里温度（T_C）没有随Nd含量的增加而变化,拉曼光谱技术分析表明这是其NbO₆八面体畸变程度没有发生变化所致.Nd³⁺取代Sr²⁺提高了材料的介电常数ε_r、压电系数d₃₃、机电耦合系数K_p,同时降低了机械品质因数Q_m,但是谐振频率温度系数C值没有改变. 关键词： 压电陶瓷 介电性能 压电性能 拉曼光谱     

多台阶器件结构深层表面光刻工艺优化

针对多台阶器件结构深层表面光刻工艺中存在的问题,对不同台阶高度分别测量了台阶表面及台阶底部沉积的光刻胶厚度,并对台阶高度与光刻胶厚度的关系进行数值描述与分析.基于Beer定律对薄光刻胶光吸收系数的描述,分析了通过实验得到的不同曝光时间下光刻胶的光强透过率曲线,解释了随着曝光时间的增加光刻胶光强透过率发生变化的原因,同时认为光刻胶光吸收系数与光刻胶厚度密切相关.在此基础上,确定了台阶底部堆积光刻胶完全曝光所需时间.优化平面光刻工艺,在不同台阶高度的深台阶表面及底部同时制作出窄线条的高质量图形.     

Temperature independent 80 Gb/s transmission system using spectral phase modulation-based TDC

A temperature independent 80-Gb/s 100-km transmission system is demonstrated with the use of spectral phase modulation-based tunable dispersion compensator (TDC). The principle of dispersion compensation based on spectral phase modulation as well as the relationship between spectral phase modulation function and group velocity dispersion (GVD) are theoretically studied. TDC based on spectral phase modulation is implemented. The performance of 80-Gb/s transmission system is experimentally evaluated. The nonlinear relationship between temperature and temperature-induced dispersion fluctuations is demonstrated through the asymmetric temperature-induced power penalty without dispersion compensation. With respect to the low temperature area, the temperature-induced dispersion fluctuations are smaller than those in the high temperature area. By using the proposed TDC, temperature independent 80-Gb/s transmission is successfully demonstrated under a temperature range of -20 - 60 ?C with a power penalty of less than 0.8 dB.     

25倍中红外连续变焦光学系统设计

针对制冷型320pixel×240pixel凝视焦平面阵列探测器,设计了一个25倍中红外连续变焦光学系统。该系统由变焦系统和二次成像系统构成。变焦系统由两个子变焦系统串联而成,可以实现高变焦比;二次成像系统的作用是压缩物镜口径和实现冷光阑效率的要求。该中波红外连续变焦系统光学系统的工作波段位于3.7～4.8μm,可以实现12～300mm连续变焦,F数达到2.5,满足100%冷光阑效率的要求。该系统具有变焦比大、相对孔径大、变焦行程短和变焦轨迹平滑等优点。     

Preparation of Pt–CeO2/MWNT nano-composites by reverse micellar method for methanol oxidation

We report the preparation of Pt–CeO₂ nanoparticles on the multi-walled carbon nanotubes (MWNTs) by a reverse micellar method. Transmission electron microscopy (TEM) analysis indicated that well-dispersed small Pt–CeO₂ nanoparticles were formed on the MWCNTs. X-ray diffraction (XRD) analysis confirmed the formation of the Pt–CeO₂ nanoparticles on the MWNTs. Cyclic voltammetry (CV) results demonstrated that the Pt–CeO₂/MWNT exhibited a higher methanol oxidation than did the Pt/MWNT catalyst. The CO stripping test showed that CeO₂ can make CO stripped at a lower potential, which is helpful for CO and methanol electro-oxidation.     

Characteristics of holographic scattering and its application in determining kinetic parameters in PQ-PMMA photopolymer

This paper characterizes holographic scattering and demonstrates its application in determining the kinetic parameters in materials with high transmittance and strong holographic scattering like phenanthrenequinone doped poly (methyl methacrylate) (PQ-PMMA). We define a polymerization rate parameter which can be determined by the temporal evolution of the scattering losses. Two basic kinetic parameters, quantum yield and molar-absorption coefficient, are obtained by nonlinear fitting the curve of the polymerization rate parameter as a function of the thickness, which are 1.9×10⁻⁶ mol/einstein and 2.1×10⁴ cm²/mol for a wavelength of 532 nm respectively. These results improve the understanding of photochemical behaviors and allow us to describe the grating formation in the photopolymer reasonably.     

掺锡As2S8薄膜光折变效应及其在条波导制备中的应用研究

实验研究了Sn₁As₂₀S₇₉非晶态半导体薄膜的光折变效应及其膜厚变化的现象,归纳了沉积态样品、退火态样品和光饱和态样品的实验规律,提出和采用紫外光激励的方法试制了Sn₁As₂₀S₇₉条形波导,632.8 nm波长导模激励显示该波导具有良好的导波特性. 关键词： 光波导技术 硫属化合物玻璃 光阻断效应 光折变效应