水力机械内鲤鱼草鱼的压力损伤模拟试验

通过试验人工模拟水力机械内压力变化过程,测量压力时间变化,观察并解剖分析不同压力变化过程对鲤鱼和草鱼造成损伤的情况。试验发现,负压状态下的压力变化过程会对鱼的生存构成直接威胁,并得到了新型环保水力机械设计中应采用的压力时变导数极限值。     

用反射法自动测量大尺寸样品的折射率分布

针对大尺寸样品的折射率分布测量,引入自动扫描装置和适时数据处理系统,研究出一种高灵敏度的智能化反射法折射率分布测量仪,可进行快速、自动、准确的折射率分布测量.经理论分析和实验研究提出了一套合理的实验数据处理方法.并具体介绍和详尽分析了实验装置,讨论了有关理论和实验误差,给出了消除各种误差的有效方法,最终得出较为理想的实验结果.     

基于悬臂梁调谐技术的光纤光栅无源振动监测

采用匹配光纤光栅设计了一种结构简单的振动信号无源监测装置.该装置利用悬臂梁调谐技术能够将微小振动信号转化为光电探测器可探测的光强信号,利用示波器实现实时监测.实验中对振幅为3mm的简谐振动信号进行了监测,测量结果与振动频率一致,可测量7～20Hz的振动,信噪比不低于14.9dB.监测频率受限是因为悬臂梁的性质,如采用金属材料或者采用齿轮组对转子进行减速,该装置可探测更高的频率.     

空间非相干多分量光束构成的非相干耦合屏蔽孤子对

两束本身具有空间非相干性的非相干多分量光束可以在光折变介质中形成非相干耦合 屏蔽孤子对，利用相干密度法得到了亮 亮、暗 暗型耦合孤子对的解，并研究了构成 非相干孤子对分量光束的相干组分的传播特性. 关键词： 空间非相干多分量光束 耦合孤子对 相干密度 相干组分     

Controlling the gain shape of Er^3＋—doped fluorozirconate fibre amplifier by a coherent field

We proposed a four-level system to explore the quantum interference effects on optical amplification.We found that the gain of the probe.including positions and values of gain peaks,can be adjusted by changing the coherent field and the incoherent pumping.At the same time,we can also modify the absorption profile of electromagnetically induced transparency by the incoherent pump.The results provide a method to flatten the gain of Erbium-doped fibre amplifiers.     

An efficient synthesis of cyanoarenes and cyanoheteroarenes via lithiation followed by electrophilic cyanation

A one-pot procedure for the conversion of mono-substituted arenes and heteroarenes into the ortho-cyano derivatives was achieved through directed lithiation followed by electrophilic cyanation with phenyl cyanate. This reaction method proved to be applicable to halogen-lithium exchanged intermediates, so especially useful for the synthesis of benzonitriles. The scope of the reaction sequence was explored using a number of substrates.     

磁性钴纳米晶的二维自组装

在两种表面活性剂存在下，采用高温醇还原，合成出单分散、平均颗粒尺寸为14±19nm，直径标准偏差小(～18%)的磁性金属Co纳米晶.利用x射线衍射、紫外吸收光谱、x射线光电子能谱及透射电子显微镜对其结构和表面价态进行了分析.并将磁性金属Co纳米晶自组织形成有序的二维(2D)六方紧密堆积结构. 关键词： Co纳米晶 单分散 自组装     

光照下meso-四(4-磺基苯基)卟啉(H_2TPPS)形成锌配合物的光-极谱研究

在氨性溶液中,光照射对ZnTPPS的形成影响很大。光-极谱试验表明:光电流(i_p)与浓度(c)间有以下的关系:对Zn(NH_3)_4~(2+),i_p∝C_((Zn)(NH_3)_4)~(2+)_~(1/2),对H_2TPPS,i_p∝C_(H_2TPPS),ZnTPPS络合物还原波的i_p不明显。本文对其差异性和光电流产生的原因做了初步探讨。     

Fundamental reactions in TiO2 nanocrystallite aqueous solutions studied by pulse radiolysis

Reactions of the hydrated electron, H atoms, 2-propanol, and methanol radicals with the TiO₂ nano-particles have been studied either directly or by competition kinetics. The radicals were produced by radiolysis of 2-propanol, t-butanol, or methanol aqueous solutions in acid pH's. The reactions involve electron injection to the conduction band. As expected, the t-butanol radical is inert towards TiO₂ under our conditions, while the other reducing radicals react with TiO₂. The reactivity decreases in the order: e_aq⁻>H>CH₃COHCH₃>CH₂OH. Two TiO₂ nanocrystallite sizes, with average diameters of 1.0 and 4.7 nm were compared. For equal concentrations (in terms of TiO₂ molecules), the rate of electron injection shows relatively little dependency on particle size. The rates of interfacial electron transfer and transfer coefficient are also reported.     

Synthesis of single crystalline layered lithium manganese oxide nanorods

Single-crystalline layered lithium manganese oxide nanorods were prepared via a low-temperature molten salt synthesis method. The material was investigated by a variety of techniques, including X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectrum (XPS).