北京自由电子激光摇摆磁铁场分布测量装置

我们设计加工了一套测量摇摆磁铁整体场分布的测量装置，并对北京自由电子激光（ＢＦＥＬ）摇摆磁铁进行了实际测量，定态测量误差优于１×１０￣（－４），动态测量误差５×１０￣（－４）。     

9-cell TESLA超导加速腔研制中Dumb-Bells的测量与调整

为了保证9-cell超导加速腔在场的平滑度、TM010的频率以及加速器的总长度达到TESLA国际标准,必须确保每个Dumb-Bell在以上各方面达到标准要求.由于冲压、机加工以及电子束焊接等过程会引起形变,因此,必须在完成iris和加强筋的电子束焊接之后对Dumb-Bells进行微波和机械测量,并根据测量的结果对其腔形和长度等作必要的调整.北京大学已经建立了一套完整的测量和调整Dumb-Bells的装置,本文深入研究了Dumb-Bells的测量与调整的方法.     

可变参数磁压缩系统设计

北京大学30MeV超导加速器包含3个RF加速单元: 自主研发的1.5cell DC-SC(直流-超导)注入器, 经过升级的3.5cell DC-SC注入器, 以及1.3GHz 2×9cell Telsa型超导加速腔. 为充分利用该装置上高品质电子束, 计划压缩1.5cell注入器出口电子束用于产生相干THz光, 以及压缩2×9cell超导加速腔出口电子束产生红外自由电子激光. 通过理论计算及模拟计算相结合设计了一套可变参数磁压缩系统, 该系统可以同时满足两个RF加速单元后束团压缩的要求.     

最大偏向角法测光栅常量

结合光栅衍射实验中±1级衍射光随光栅片转动而分别向左右移动到某一位置消失的具体现象,在光栅实验中提出了“最大偏向角”的概念,并给出了通过测量最大偏向角来计算光栅常量的方法.     

微分代数系统稳定性及镇定新判据

本文利用矩阵迹不等式讨论了微分代数系统的稳定性,并给出了微分代数系统容许的充分条件.提出了用此方法设计状态反馈控制器使微分代数系统容许的新方法,并设计了矩阵迹不等式组的计算机求解程序,并用例子说明了主要定理的有效性.     

湿法消解-FAAS测定4省区藏药南寒水石中的钙及5种微量元素

使用湿法消解-FAAS测定4省区（西藏、青海、甘肃、四川）藏药南寒水石中钙及5种微量元素铁、锰、锌、铜、镁的含量。采用空气-乙炔火焰原子吸收光谱法对微量元素进行测定。该方法快速、准确,以期所测数据为藏药南寒水石实际用药及其质量标准的制定提供参考。     

1 + 1] photodissociation of CS(2)(+)(X̃2Π(g)) via the vibrationally mediated B̃2Σ(u)+ state: multichannels exhibiting and mode specific dynamics

Dissociation dynamics of CS(2)(+) vibrationally mediated via its B?(2)Σ(u)(+) state, was studied using the time-sliced velocity map imaging technique. The parent CS(2)(+) cation was prepared in its X?(2)Π(g) ground state through a [3 + 1] resonance enhanced multiphoton ionization process, via the 4pσ(3)Π(u) intermediate Rydberg state of neutral CS(2) molecule at 483.14 nm. CS(2)(+)(X?(2)Π(g)) was dissociated by a [1?+?1] photoexcitation mediated via the vibrationally selected B? state over a wavelength range of 267-283 nm. At these wavelengths the C?(2)Σ(g)(+) and D?(2)Σ(u)(+) states are excited, followed by numerous S(+) and CS(+) dissociation channels. The S(+) channels specified as three distinct regions were shown with vibrationally resolved structures, in contrast to the less-resolved structures being presented in the CS(+) channels. The average translational energy releases were obtained, and the S(+)∕CS(+) branching ratios with mode specificity were measured. Two types of dissociation mechanisms are proposed. One mechanism is the direct coupling of the C? and D? states with the repulsive satellite states leading to the fast photofragmentation. The other mechanism is the internal conversion of the C? and D? states to the B? state, followed by the slow fragmentation occurred via the coupling with the repulsive satellite states.     

高效液相色谱法测定猪组织中咪唑苯脲残留研究

建立了高效液相色谱(HPLC)测定猪可食性组织中咪唑苯脲残留的方法。猪组织经β-葡萄糖苷酶水解后,用1 mol/L盐酸提取,再用正己烷-异戊醇(3:2, v/v)混合溶剂萃取净化。以乙腈和0.0075 mol/L戊烷磺酸钠水溶液(含0.1%三乙胺,pH 3.0)作为流动相,经C18反相色谱柱分离后用紫外检测器检测。结果表明: 该方法在咪唑苯脲含量为10～10000 μg/L范围内呈现良好的线性关系,相关系数大于0.999;空白组织中加标样品的检出限(LOD)为10 μg/kg,定量限(LOQ)为20 μg/kg。在定量限、最高残留限量(MRL)、2倍MRL添加水平下,不同组织的平均回收率为80.04%～110.32%,相对标准偏差为0.82%～10.00%。表明该检测方法简单、灵敏,适用于猪组织中咪唑苯脲残留的定量检测。     

苄醇存在下脂肪叔胺催化内酯开环聚合

为研究脂肪叔胺结构对内酯开环聚合规律的影响,以三乙胺( TEA)、N,N,N′,N′-四甲基乙二胺(TMEDA)、N,N,N′,N″,N″-五甲基二亚乙基三胺(PM DTA)3种不同结构的叔胺催化碳酸三亚甲基酯(TMC)和左旋丙交酯( L-LA)开环聚合.结果显示,在55℃的THF溶液中,以苄醇为引发剂,3种叔胺均能催...     

Excess thermodynamic properties of thin water films confined between hydrophobized gold surfaces

Surface forces between gold surfaces were measured in pure water at temperatures in the range of 10-40 °C using an atomic force microscope (AFM). The surfaces were hydrophobized by self-assembly of alkanethiols (C(n)SH) with n=2 and 16 in ethanol solutions. The data were used to determine the changes in excess free energies (ΔG(f)) of the thin water films per unit area by using the Derjaguin approximation [1]. The free energy data were then used to determine the changes in excess film entropy (ΔS(f)) and the excess film enthalpy (ΔH(f)) per unit area. The results show that both ΔS(f) and ΔH(f) decrease with decreasing film thickness, suggesting that the macroscopic hydrophobic interaction involves building some kind of structures in the intervening thin films of water. It was found that |ΔH(f)|>|TΔS(f)|, which is a necessary condition for an attractive force to appear when the enthalpy and entropy changes are both negative. That macroscopic hydrophobic interaction is enthalpically driven is contrary to the hydrophobic interactions at molecular scale. The results obtained in the present work are used to discuss possible origins for the long-range attractions observed between hydrophobic surfaces.