Effect of Precipitation Temperature and Number of Iron Atoms per Molecule on the Structure of Hydrated Iron(III) Oxyhydroxide Ferritin Cores Synthesised in vitro

Hyperfine Interactions - Horse spleen apoferritin was reconstituted with varying numbers of iron atoms per protein shell at 25 and 50°C. Samples with mean particle sizes ranging from...     

Comparison between lattice Boltzmann method and Navier–Stokes high order schemes for computational aeroacoustics

Computational aeroacoustic (CAA) simulation requires accurate schemes to capture the dynamics of acoustic fluctuations, which are weak compared with aerodynamic ones. In this paper, two kinds of schemes are studied and compared: the classical approach based on high order schemes for Navier–Stokes-like equations and the lattice Boltzmann method. The reference macroscopic equations are the 3D isothermal and compressible Navier–Stokes equations. A Von Neumann analysis of these linearized equations is carried out to obtain exact plane wave solutions. Three physical modes are recovered and the corresponding theoretical dispersion relations are obtained. Then the same analysis is made on the space and time discretization of the Navier–Stokes equations with the classical high order schemes to quantify the influence of both space and time discretization on the exact solutions. Different orders of discretization are considered, with and without a uniform mean flow. Three different lattice Boltzmann models are then presented and studied with the Von Neumann analysis. The theoretical dispersion relations of these models are obtained and the error terms of the model are identified and studied. It is shown that the dispersion error in the lattice Boltzmann models is only due to the space and time discretization and that the continuous discrete velocity Boltzmann equation yield the same exact dispersion as the Navier–Stokes equations. Finally, dispersion and dissipation errors of the different kind of schemes are quantitatively compared. It is found that the lattice Boltzmann method is less dissipative than high order schemes and less dispersive than a second order scheme in space with a 3-step Runge–Kutta scheme in time. The number of floating point operations at a given error level associated with these two kinds of schemes are then compared.     

Asymptotic-Preserving Particle-In-Cell method for the Vlasov–Poisson system near quasineutrality

This paper deals with the numerical resolution of the Vlasov–Poisson system in a nearly quasineutral regime by Particle-In-Cell (PIC) methods. In this regime, Classical PIC methods are subject to stability constraints on the time and space steps related to the small Debye length and large plasma frequency. Here, we propose an “Asymptotic-Preserving” PIC scheme which is not subjected to these limitations. Additionally, when the plasma period and Debye length are small compared to the time and space steps, this method provides a consistent PIC discretization of the quasineutral Vlasov equation. We perform several one-dimensional numerical experiments which provide a solid validation of the method and its underlying concepts, and compare the method with Classical PIC and Direct-Implicit methods.     

AFM study of BSA adlayers on Au stripes

Thin narrow Au stripes suitable for propagating long-range surface plasmon-polaritons were deposited by evaporation and lift-off on a thermal oxide layer on a silicon substrate, and modified by direct adsorption of bovine serum albumin (BSA). Atomic force microscopy (AFM) measurements reveal that BSA adsorbs onto the Au stripes from phosphate buffer solutions forming an adlayer having an average thickness of about 2 nm (surface mass density of about 2 ng/mm²). Comparisons with a simple adsorption model suggest the side-on adsorption of a single monolayer of BSA followed by denaturation and flattening. The BSA-coated stripes have an increased surface roughness compared to a virgin stripe.     

Ultraviolet properties of maximal supergravity

We argue that recent results in string perturbation theory indicate that the four-graviton amplitude of four-dimensional N=8 supergravity might be ultraviolet finite up to eight loops. We similarly argue that the h-loop M-graviton amplitude might be finite for h<7+M/2.     

The ground-state rotational constants of silane

From thirty-nine combination difference equations we have determined three significant ground-vibronic state constants of silane: β ⁰/hc=2·85941 cm^-1, γ ⁰/hc=-3·82×10^-5 cm^-1 and ε ⁰/hc=-7·97×10^-7 cm^-1 or in Hecht's notation B ₀=2·85941 cm^-1, D _s=3·82×10^-5 cm^-1 and D _t=2·436×10^-6 cm^-1.     

Convergent Star Product Algebras on ‘ax+b’

We define nontempered (exponential growth) function spaces on the Lie group ax+b which are stable under some left-invariant (convergent) star product. The techniques used to achieved the latter come from symmetric spaces geometry and star representation theory.