Wet carbon-based solid acid/NaNO_3 as a mild and efficient reagent for nitration of aromatic compound under solvent free conditions

Nitro aromatic compound can be obtained in high yields via nitration of aromatic compound with wet carbon-based solid acid and NaNO_3 under solvent free oxidation at room temperature.     

A New Method for Assessment of Performing Mechanical Works of Energetic Compounds by the Cylinder Test

A new method is introduced for assessment of performing mechanical works of energetic compounds by cylinder wall velocities of CHNOFCl energetic compounds on the basis of the cylinder test. Four suitable decomposition paths are used to evaluate the number of moles of gaseous detonation products per gram of explosive, the average molecular weight of these gases, and the heat of detonation in calories per gram by considering different decomposition products HF, HCl, CO, N₂, H₂O, H₂, and CO₂. For CHNO and fluoro energetic compounds, the predicted cylinder wall velocities of these compounds give more reliable results than one of the best available empirical methods. The predicted root mean square (rms) deviations of cylinder wall velocities of the new model for some chloro explosives at actual radial expansions 0.6 and 1.9 mm are 0.010 and 0.062 km · s^–1, which show high reliability of the new method.     

Diammonium Hydrogen Phosphate as an Efficient and Inexpensive Catalyst for the Synthesis of Bis(indolyl)methanes under Solvent-Free Conditions

Bis(indolyl)methanes were synthesized by the reaction of indole derivatives and aromatic and aliphatic aldehydes in the presence of diammonium hydrogen phosphate as a solid catalyst under solvent-free conditions. This methodology offers significant improvements for the synthesis of bis(indolyl)methanes with regard to the yield of products, simplicity in operation, and green aspects by avoiding toxic catalysts and solvents.     

A new approach to the facile synthesis of mono- and disubstituted quinazolin-4(3H)-ones under solvent-free conditions

Quinazolin-4(3H)-one derivatives were synthesized successfully via a one-pot, three component reaction of isatoic anhydride and an orthoester with ammonium acetate or a primary amine catalyzed by silica sulfuric acid under solvent-free conditions. This is the first report on the synthesis of 2-substituted quinazolin-4(3H)-ones by this procedure.     

Signature of non-Fickian solute transport in complex heterogeneous porous media

We simulate transport of a solute through three-dimensional images of different rock samples, with resolutions of a few microns, representing geological media of increasing pore-scale complexity: a sandpack, a Berea sandstone, and a Portland limestone. We predict the propagators (concentration as a function of distance) measured on similar cores in nuclear magnetic resonance experiments and the dispersion coefficient as a function of Péclet number and time. The behavior is explained using continuous time random walks with a truncated power-law distribution of travel times: transport is qualitatively different for the complex limestone compared to the sandstone or sandpack, with long tailing, an almost immobile peak concentration, and a very slow approach to asymptotic dispersion.     

Coupled-mode analysis for linear fiber Bragg grating made of metamaterial

We derive the coupled-mode equations for a metamaterial fiber Bragg gratings (FBGs). The coupled-mode theory describing wave propagation in periodic structures such as FBG is generalized for studying the transmission and reflection of electromagnetic waves through a FBG containing metamaterial layers. This approach shows that the band gap becomes broader in comparison with a conventional FBG. It is observed that the central frequency of the band gap has a shift in regard of changing metamaterial thickness. We verify this investigation through attaining the transmission and reflection spectra of a conventional FBG while we are setting related parameters. Furthermore, this proposed structure can be applied as a tunable filter.     

SOME NEW EXTENSIONS OF EDELSTEIN-SUZUKI-TYPE FIXED POINT THEOREM TO G-METRIC AND G-CONE METRIC SPACES

In this paper, we prove some fixed point theorems for generalized contractions in the setting of G-metric spaces. Our results extend a result of Edelstein [M. Edelstein, On fixed and periodic points under contractive mappings, J. London Math. Soc., 37 （1962）, 74-79] and a result of Suzuki [T. Suzuki, A new type of fixed point theorem in metric spaces, Nonlinear Anal., 71 （2009）, 5313-5317]. We prove, also, a fixed point theorem in the setting of G-cone metric spaces.     

Calix[4]arene-based crab-like molecular sensors for highly selective detection of mercury and copper ions

In this work, two novel chemosensors based on calix[4]arene bearing (thio)barbituric acid groups (BC1 and BC2) were synthesised, and their structures were characterised by HRMS, NMR and FTIR. Furthermore, their binding properties towards various biologically relevant metal ions were studied by fluorescence titrations, ¹H NMR spectroscopies and Job’s plot evaluations. The chemosensor BC1 displayed excellent binding affinity and selectivity towards Cu²⁺, which was characterised using fluorescence spectroscopy. On the other hand, BC2 exhibited a very remarkable fluorescence enhancement as well as visible colour change from pale green to sunset yellow, in presence of Hg²⁺ ions. Finally, Job’s plot method revealed 1:1 binding stoichiometry for both BC1:Cu²⁺ complex and BC2:Hg²⁺ complex.     

An efficient one-pot method for the synthesis of novel ferrocene-triamide conjugates via pseudo five-component reaction

A simple and efficient one-pot synthesis of novel ferrocene-triamide conjugates from the reaction of ferrocenecarboxaldehyde with Meldrum’s acid and isocyanides in the presence of NH-containing compounds is described. This transformation proceeds through the creation of two CC bonds, two CN bonds, and one CO bond, leading to three peptide bonds, and presumably occurs via a domino sequence involving Knoevenagel condensation, [1+4] cycloaddition, deacetonation, and aminolysis reactions.     

c-capability of Lie algebras with the derived subalgebra of dimension two

The current article is devoted to classify the c-capability of finite dimensional nilpotent Lie algebras with the derived subalgebra of dimension two.