The removal of low level inorganics via electrogenerated hydrogen peroxide in the presence of catalytic amounts of Fe2+

Low level phosphites and hypophosphites were completely converted into phosphates, via hydrogen peroxide generated by cathodic reduction of oxygen in acidic aqueous medium at a reticulated vitreous carbon electrode, in the presence of little amounts of Fe2+. The contemporary regeneration of Fe2+ by cathodic reduction of Fe3+, produced by the well known Fenton reaction, furnishes an excellent way to continuously produce little amounts of the Fenton reactive and, as a consequence, of the powerful oxidant hydroxyl radical HO.. The best conditions for the complete removal of phosphorous as phosphites and hypophosphites are reported.     

Towards RGB photoelasticity: Full-field automated photoelasticity in white light

In this paper a new full-field method for the automatic analysis of isochromatic fringes in white light is presented. The method, named RGB photoelasticity, eliminates the typical drawbacks of the classical approach to photoelasticity in white light which requires a subjective analysis of colors and an experienced analyst to acquire and interpret the results. The proposed method makes it possible to determine retardations uniquely in the range of 0–3 fringe orders. For this purpose the isochromatics are acquired by means of a color video camera and the colors are decomposed in the three primary colors (red, green and blue) and compared to those stored in a calibration array in the system. Furthermore, the influence of various spurious effects on the accuracy of the proposed method is experimentally evaluated.