Portable X-ray fluorescence device reveals the artistic palette of Carlo Bononi,Baroque artist from Ferrara

The principal aim of the in situ X-ray fluorescence (XRF) analysis on the canvas “The Coronation of the Virgin” was to characterise the colour palette of Carlo Bononi (Ferrara, 1580–1632), a lesser-known artist of the early Baroque period in Ferrara. More than 100 points were collected by means of an XRF spectrometer, but the presence of many overlapping painted layers left some doubts about the preparation and the background layers. The scanning electron microscopy with energy dispersive spectrometer analysis on two samples resolved some of these doubts. The results obtained indicate the use of typical 17th century pigments, such as lead white, vermilion, azurite and a copper-based green. For yellow pigments, the artist used the yellow ochre in some cases, while in others he used lead-tin yellow. We also individuated at least three different shades of umber. Almost all the pigments have been identified and they are the first step in establishing the technical apparatus necessary to understand the modus operandi of the Ferrarese artist.     

The influence of the quarter wave plates in automated photoelasticity

During the last decades, several methods have been proposed to automate photoelastic analyses. Some procedures are based on the circularly polarised light by using quarter wave plates. However, quarter wave plates are typically matched for a specific wavelength, and an error is introduced at different wavelengths. The error of quarter wave plates affects the measurement of isochromatic and isoclinic data. In this paper, the influence of the errors of quarter wave plates in some of the most common automated photoelastic methods is reviewed. The errors in the photoelastic data are given and the procedures to reduce, or eliminate, them are also suggested.     

Crossed-beam dynamics studies of the radical-radical combustion reaction O((3)P) + CH3 (methyl)

The dynamics of the radical-radical reaction O((3)P) + CH(3), a prototypical case for the reactions of atomic oxygen with alkyl radicals of great relevance in combustion chemistry, has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 55.9 kJ mol(-1). The results have been examined in the light of previous kinetic and theoretical work. From product angular and velocity distribution measurements, the dynamics of the predominant H-displacement channel leading to formaldehyde formation has been characterized. This channel has been found to proceed via the formation of an osculating complex; a significant coupling between the product centre-of-mass angular and translational energy distributions has been noted. Experimental attempts to characterize the dynamics of the channel leading to HCO + H(2) have failed and it remains unclear whether HCO is formed by the reaction and/or, if formed, a part of HCO does not dissociate quickly into CO + H.     

Reply to “Comment on ‘Piezonuclear decay of thorium’ [Phys. Lett. A 373 (2009) 1956]” [Phys. Lett. A 373 (2009) 3795]

In a paper appearing in this issue of Physics Letters A, Ericsson et al. raise some critical comments on the experiment [F. Cardone, R. Mignani, A. Petrucci, Phys. Lett. A 373 (2009) 1956] we carried out by cavitating a solution of thorium-228, which evidenced its anomalous decay behaviour, thus confirming the results previously obtained by Urutskoev et al. by explosion of titanium foils in solutions. In this Letter, we reply to these comments. In our opinion, the main shortcomings of the criticism by the Swedish authors are due to their omitting of inserting our experiment in the wider research stream of piezonuclear reactions, and to the statistical analysis they used, which does not comply with the rules generally accepted for samples with small numbers. However, apart from any possible theoretical speculation, there is the basic fact that two different experiments (ours and that by Urutskoev et al.), carried out independently and by different means, highlight an analogous anomaly in the decay of thorium subjected to pressure waves. Such a convergence of results shows that it is worth to further carry on experimental investigations, in order to get either a confirmation or a disproof of the induced-pressure anomalous behaviour of radioactive nuclides even different from thorium.     

New measurement of (g−2) of the Muon

The g-factor anomaly, a≡(g?2)/2, has been measured for μ⁺ in the new Muon Storage Ring at CERN. The result is a = (1 165 895 ± 27) × 10^?9. This is (13 ± 29) × 10^?9 below the theoretical value which includes sixth-order QED terms and a hadronic contribution of (73 ± 10) × 10^?9.     

Automated Stress Separation Along Stress Trajectories

A procedure for the separation of principal stresses in automated photoelasticity is presented. It is based on the integration of indefinite equations of equilibrium along stress trajectories, also known as Lamè–Maxwell equations. A new algorithm for precise and reliable stress trajectory calculation, which is an essential feature of the procedure, has also been developed. Automated stress separation is carried out along stress trajectories starting from free boundaries. Experimental tests were performed on a disc in diametral compression and on a ring with internally applied pressure. Full-field principal stress values were obtained and results were compared with those from the theory of elasticity and with those obtained from the classical shear difference method. It was shown that the proposed method is more accurate and less affected by the presence of residual stresses or experimental errors at the boundaries than the shear difference method. In addition, the method requires little human interaction and is therefore well-suited for automated photoelasticity.     

Application of WDXRF in the provenance studies of Persian haft rang tiles: a statistical approach

An outstanding style of Persian tilework, which emerged from the north‐eastern Iran in the 15th century, was extensively used for decorating architectural facades during the Safavid period (from the 16th through the 18th century). This type of tilework, the so‐called haft rang, technically comprises of forming a clay body and firing two glazed layers on top of the body. In the present paper, the first analytical data concerning haft rang tiles is provided. To do so, forty three samples of Safavid haft rang bodies were analysed by wavelength dispersive x‐ray fluorescence (WDXRF) and the obtained data were handled by principal component analysis (PCA). The results showed that the 17th century haft rang tiles wherever found are local products; that is, Safavid tile‐makers have used local clay sources to make the bodies of haft rang tiles. The analytical data also showed that old tileworks, in general sense, can be simply replaced by newly manufactured tiles or, at least, all tilework revetments in an individual edifice might not have been produced in an identical workshop. Moreover, WDXRF was used as an accurate and precise method to determine the chemical composition and to support compositional classification in provenance studies and can be considered as a reliable alternative for studying the provenance of archaeological ceramics. Copyright © 2013 John Wiley & Sons, Ltd.     

A New Procedure for the Evaluation of Non-Uniform Residual Stresses by the Hole Drilling Method Based on the Newton-Raphson Technique

The hole drilling method is one of the most used semi-destructive techniques for the analysis of residual stresses in mechanical components. The non-uniform stresses are evaluated by solving an integral equation in which the strains relieved by drilling a hole are introduced. In this paper a new calculation procedure, based on the Newton-Raphson method for the determination of zeroes of functions, is presented. This technique allows the user to introduce complex and effective forms of stress functions for the solution of the problem. All the relationships needed for the evaluation of the stresses are obtained in explicit form, eliminating the need to use additional mathematical tools. The technique is based on a rather general theory that allows to obtain the formulations of various existing techniques as particular cases.     

Dynamic reaction cell ICP-MS for determination of total As, Cr, Se and V in complex matrices: still a challenge? A review

Mass interferences, caused by atomic or polyatomic species and having the same mass/charge ratio of the analyte, can be a severe limit for a reliable assay of trace and ultratrace elements by ICP-MS. The DRC? technology uses a reaction gas to overcome these interferences. Reactions of charge exchange, atom transfer, adduct formation, condensation and analyte association/condensation are the main mechanisms. Interfering ions tend to react with the gas exothermally, while, the analyte reacts endothermally. Selecting the most appropriate reaction gas in DRC-ICP-MS is the very critical point for the determination of strongly interfered elements. A careful evaluation of the reaction mechanisms and the chemistry involved are required. The DRC allows the use of different gases, among them, ammonia (NH(3)), methane (CH(4)), hydrogen (H(2)) and oxygen (O(2)) are the most known, but there are other potentially useful gases like nitrous oxide (N(2)O), nitrogen oxide (NO), carbon dioxide (CO(2)), fluoromethane (CH(3)F), sulphur hexafluoride (SF(6)) and carbon disulfide (CS(2)). This paper provides a review on the analytical challenges for a reliable assay of As, Cr, Se and V by DRC-ICP-MS and illustrates different approaches and mechanisms involved in the analysis of polymers, biological fluids (serum, urine and whole blood), rock, soil and particulate matter.