Bäcklund transformations between four Lax-integrable 3D equations

Recently a classification of contactly-nonequivalent three-dimensional linearly degenerate equations of the second order was presented by E.V. Ferapontov and J. Moss. The equations are Lax-integrable. In our paper we prove that all these equations are connected with each other by appropriate Bäcklund transformations.     

Synthesis and characterization of polymethacrylates containing conjugated oligo(phenylene ethynylene)s as side chains

In order to form suitable systems designed for resonance energy transfer, a series of monodisperse methacrylate‐based monomers containing rigid π‐conjugated oligo(phenylene ethynylenes) with different sizes of the conjugated systems ( M1 – M3 ), and therefore different optoelectronic properties, were synthesized and subsequently polymerized using the reversible addition–fragmentation chain transfer polymerization technique ( P1 – P3 ). In addition, these oligomers were also copolymerized with methyl methacrylate. The obtained polymers were characterized by ¹H NMR spectroscopy, size exclusion chromatography, and analytical ultracentrifugation. The photophysical properties of the polymers were studied by UV–vis absorption and emission spectroscopy in diluted solutions as well as in thin films and compared to the photophysics of the corresponding monomers. Thereby, changes going from monomeric to polymeric systems could be detected in fluorescence quantum yields and lifetimes pointing to energy trapping, e.g., energy transfer. Donor–acceptor copolymers containing different numbers of monomeric units within the side chain exhibit differences in the emission spectra, indicating that energy trapping in polymers is very sensitive to structural properties such as the chain length. UV–vis absorption spectroscopy as well as time‐resolved lifetime studies indicate intrapolymer and interpolymer energy transfer. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

The new frozen spin target at MAMI

The new frozen spin polarized target for experiments at the polarized beam of the real photon facility A2 of the MAMI accelerator is described. The A2-collaboration at the Mainz Microtron MAMI is measuring photon absorption cross section using circularly and linearly polarized photons up to the energy of 1.5 GeV. The photons are produced in the’ Bremsstrahlungs’ process. In the years 2005/2006 the Crystal Ball detector with its unique capability to cope with multi photon final states was set up in Mainz. Since 2010 the experimental apparatus has been completed by a polarized target. The horizontal dilution refrigerator of the Frozen-Spin Target has been constructed and is operated in close cooperation with the Joint Institute for Nuclear Research in Dubna, Russia. The system offers the opportunity to provide longitudinally and transversely polarized protons and deuteron. In this paper the operation experience of this new Frozen-Spin Target and first results from the runs in 2010 and 2011 are presented.     

Complexation and flotation of nonferrous metal ions from alkaline solutions with N-acyl-N′-(p-toluenesulfonyl)hydrazines

Surfactant properties and complexation conditions of Cu(II), Co(II), Ni(II), Zn(II), and Cd(II) ions in alkaline media with N-acyl-N′-(p-toluenesulfonyl)hydrazines, which enable their use in ion flotation processes, were studied. The efficiency of the compounds under study as collectors in aftertreatment of alkaline wastewater to remove milligram amounts of Cu(II) and other metals by ion flotation was demonstrated.     

Chemosensors and biosensors based on polyelectrolyte microcapsules containing fluorescent dyes and enzymes

The concept of enzyme-assisted substrate sensing based on use of fluorescent markers to detect the products of enzymatic reaction has been investigated by fabrication of micron-scale polyelectrolyte capsules containing enzymes and dyes in one entity. Microcapsules approximately 5 μm in size entrap glucose oxidase or lactate oxidase, with peroxidase, together with the corresponding markers Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride (Ru(dpp)) complex and dihydrorhodamine 123 (DHR123), which are sensitive to oxygen and hydrogen peroxide, respectively. These capsules are produced by co-precipitation of calcium carbonate particles with the enzyme followed by layer-by-layer assembly of polyelectrolytes over the surface of the particles and incorporation of the dye in the capsule interior or in the multilayer shell. After dissolution of the calcium carbonate the enzymes and dyes remain in the multilayer capsules. In this study we produced enzyme-containing microcapsules sensitive to glucose and lactate. Calibration curves based on fluorescence intensity of Ru(dpp) and DHR123 were linearly dependent on substrate concentration, enabling reliable sensing in the millimolar range. The main advantages of using these capsules with optical recording is the possibility of building single capsule-based sensors. The response from individual capsules was observed by confocal microscopy as increasing fluorescence intensity of the capsule on addition of lactate at millimolar concentrations. Because internalization of the micron-sized multi-component capsules was feasible, they could be further optimized for in-situ intracellular sensing and metabolite monitoring on the basis of fluorescence reporting.     

Structural Study of Membrane Glycoprotein-Precursor of β-Amyloid and Proteins Involved in Its Proteolysis

Crystallography Reports - Alzheimer’s disease is the most widespread form of neurodegenerative disease in the world. Its clinical manifestations are explained by selective degeneration of...     

Synthesis of binder-free granulated MOR-type zeolite with hierarchic pore structure

A procedure was developed for preparing an aluminosilicate with a hierarchic pore structure and granules in the form of united polycrystalline concretions of MOR-type zeolite in the Na form. The procedure includes the step of mixing of MOR-type powdered zeolite with kaolin and white carbon black, granule forming, granule calcination, and crystallization in an autoclave in a sodium silicate solution.     

Nonlinear Effects in a Viscous Wave Field Excited by a Finite-Size Plate

Technical Physics - We have numerically investigated nonlinear nonstationary velocity and pressure fields in a viscous incompressible fluid near an oscillating absolutely rigid plate of an...     

Static Limit and Penrose Effect in Rotating Reference Frames

Theoretical and Mathematical Physics - We show that effects similar to those for a rotating black hole arise for an observer using a uniformly rotating reference frame in a flat space-time: a...