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91.
Yi Liu David D. Díaz Adrian A. Accurso K. Barry Sharpless Valery V. Fokin M. G. Finn 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5182-5189
1,2,3‐Triazole‐based polymers generated from the Cu(I)‐catalyzed cycloaddition between multivalent azides and acetylenes are effective adhesive materials for metal surfaces. The adhesive capacities of candidate mixtures of azide and alkyne components were measured by a modified peel test, using a customized adhesive tester. A particularly effective tetravalent alkyne and trivalent azide combination was identified, giving exceptional strength that matches or exceeds the best commercial formulations. The addition of Cu catalyst was found to be important for the synthesis of stronger adhesive polymers when cured at room temperature. Heating also accelerated curing rates, but the maximum adhesive strengths achieved at both room temperature and high temperature were the same, suggesting that crosslinking reaches the same advanced point in all cases. Polytriazoles also form adhesives to aluminum, but copper is bound more effectively, presumably because active Cu(I) ions may be leached from the surface to promote crosslinking and adhesion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5182–5189, 2007 相似文献
92.
František Toman Ludvík Beneš 《Journal of inclusion phenomena and macrocyclic chemistry》2007,59(3-4):231-236
Differential molar adsorption enthalpies (DMAE) were determined by gas chromatographic measurements of specific retention
volume of vapors on the surface of two forms of Mg–Al hydrotalcite. A linear dependence of the DMAE on the number of the carbon
atoms in hydrocarbons was observed for both form of hydrotalcite. The dependence of the differential molar adsorption enthalpies
on the number of chlorine atoms in organic molecules is discussed. A linear dependence of DMAE on the molecular weight of
chloroderivatives of methane and ethylene on the basic form in an order monochloromethane < dichloromethane < trichloromethane
or vinylidene chloride < 1,1-dichloroethylene < trichloroethylene was found. 相似文献
93.
94.
The paper is devoted to the research of large deviation probabilities in the approximation by compound Poisson law. 相似文献
95.
96.
Oriňák Andrej Arlinghaus Heinrich Frank Vering Guido Justinová Martina Oriňáková Renáta Turčániová L’udmila Halama Maroš 《平面色谱法杂志一现代薄层色谱法》2003,16(1):23-27
JPC – Journal of Planar Chromatography – Modern TLC - Two interfaces have been tested for coupling thin-layer chromatography (TLC) with time-of-flight secondary-ion mass spectrometry... 相似文献
97.
If a and b are trace-class operators, and if u is a partial isometry, then , where ∥⋅∥1 denotes the norm in the trace class. The present paper characterises the cases of equality in this Young inequality, and
the characterisation is examined in the context of both the operator and the Hilbert–Schmidt forms of Young's inequality.
Received: 20 December 2001 / Revised version: 11 July 2002 / Published online: 10 February 2003
Mathematics Subject Classification (2000): 47A63, 15A60 相似文献
98.
Bruzón M. S. Gandarias M. L. Muriel C. Ramírez J. Saez S. Romero F. R. 《Theoretical and Mathematical Physics》2003,137(1):1367-1377
We use the classical and nonclassical methods to obtain symmetry reductions and exact solutions of the (2+1)-dimensional integrable Calogero–Bogoyavlenskii–Schiff equation. Although this (2+1)-dimensional equation arises in a nonlocal form, it can be written as a system of differential equations and, in potential form, as a fourth-order partial differential equation. The classical and nonclassical methods yield some exact solutions of the (2+1)-dimensional equation that involve several arbitrary functions and hence exhibit a rich variety of qualitative behavior. 相似文献
99.
100.
Let 1→N→G→G/N→1 be a short exact sequence of profinite groups, and let p be a prime number. We prove that if G is of finite cohomological p-dimension n:=cdp(G)<∞ and if the order of is finite for k:=cdp(N), the virtual cohomological p-dimension of G/N equals n?k. To cite this article: T. Weigel, P. Zalesskii, C. R. Acad. Sci. Paris, Ser. I 338 (2004). 相似文献