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11.
Paulo C. Rech 《中国物理 B》2013,(8):233-237
We investigate the dynamical behavior of a symmetric linear coupling of three quadratic maps with exponential terms, and identify various interesting features as a function of two control parameters. In particular, we investigate the emergence of quasiperiodic states arising from Naimark-Sacker bifurcations of stable period-l, period-2, and period-3 orbits. We also investigate the multistability in the same coupling. Lyapunov exponents, parameter planes, phase space portraits, and bifurcation diagrams are used to investigate transitions from periodic to quasiperiodic states, from quasiperiodic to mode-locked states and to chaotic states, and from chaotic to hyperchaotic states. 相似文献
12.
We study adaptive dynamics in a structured population model of asexual individuals which takes into account environmental heterogeneity among the subpopulations. The key purpose of the present work is to address how population turnovers, i.e. extinction events followed by recolonization, affect the rate of fixation of advantageous mutations. This model is a generalization of our previous model to address the interplay between environmental correlation and evolutionary forces on the adaptive process. The incorporation of population turnovers into the model enables us to make a direct correspondence between the model and host-parasite dynamics (epidemiological models). Strikingly, contrary to the intuitive and usual deleterious effect associated to extinction events, it is observed that population turnovers can in fact speed up adaptation as heterogeneity rises. On the other side, in nearly homogeneous population turnovers have a neutral effect on fixation rates, but a detrimental outcome is also achieved when extinction events become very common. In resume, population turnover outcomes on fixation rates of advantageous mutations are strongly influenced by the selective correlation among the subpopulations (demes). 相似文献
13.
Ramos CI Santana-Marques MG Ferrer-Correia AJ Barata JF Tomé AC Neves MG Cavaleiro JA Abreu PE Pereira MM Pais AA 《Journal of mass spectrometry : JMS》2012,47(4):516-522
Two new isomeric aminomethyl corrole derivatives of [5,10,15-tris(pentafluorophenyl)corrolato]gallium(III) were synthesized with pyridine (py) molecules as axial ligands. When investigated by electrospray ionization mass spectrometry, in the positive and the negative ion modes, these compounds showed an unusual gas-phase behavior that could be used for their differentiation. In the positive ion mode, the differentiation was achieved through the formation of diagnostic fragment ions formed from [M-py?+?H](+) precursors, by (CH(3) )(2) NH and HF losses. An unusual addition of water to the main fragment ions provides an alternative route for isomer identification. Semi-empirical calculations were performed to elucidate the structures and stabilities of the main ionic species formed in the positive ion mode. In the negative ion mode isomer discrimination is accomplished via the fragmentation of the methoxide adduct ions [M-py?+?CH(3) O](-) through (CH(3) )(2) N(.) and HF losses. 相似文献
14.
Mariana Sardo Ana M. Amado Paulo J. A. Ribeiro‐Claro 《Journal of Raman spectroscopy : JRS》2009,40(12):1956-1965
The importance of hydrogen‐bond formation in the molecular packing arrangements of two anhydrous forms of nitrofurantoin is investigated, combining computational methods and spectroscopic data. The overall results indicate, as expected, that the vibrational modes related to the CO, N H and C H groups are strongly affected by intermolecular hydrogen‐bond formation. Moreover, the importance of weak C‐H···O interactions in conferring additional stability to molecular associations in biological systems is evidenced in this study. The complete assignment of the Raman and infrared spectra of both polymorphs is accomplished by means of a computationally based methodology, which accounts for the effects of intermolecular interactions in the crystal. The vibrational shifts due to crystal packing interactions are evaluated from DFT calculations for a set of suitable molecular pairs, using the B3LYP/6‐31G* approach. This methodology provides an answer to the current demand for a reliable and complete assignment of the vibrational spectra of pharmaceutically active compounds such as nitrofurantoin. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
15.
S. Di Maria S. Barros J. Bento P. Teles C. Figueira M. Pereira P. Vaz G. Paulo 《Radiation measurements》2011,46(10):1103-1108
The main purpose of this study was to validate and compare Mean Glandular Dose (MGD) values obtained using Monte Carlo simulations with experimental values obtained from Entrance Surface Dose (ESD) and depth dose measurements performed in a Hospital mammography unit. ESD and depth dose were measured using ThermoLuminescent Dosimeters (TLDs), and a tissue equivalent mammography phantom recommended by the American College of Radiology (ACR). Measurements and Monte Carlo simulations were also compared with the MGD calculated using the Automatic Exposure Control (AEC) system of the mammographic unit. In the simulations the Doppler energy broadening effect was also taken into account. The simulated ESD are about 5%–10% higher than the measured ESD values. The deviation between the measured and simulated MGD values in the phantom is of about 15%. The MGD evaluated using the AEC system is smaller both with respect to the Monte Carlo simulation and experimental result by a factor of about 15% and 25% respectively. Moreover the BackScatter Factor (BSF) estimated by Monte Carlo simulations was used for the MGD calculation according to the Wu’s method. Finally the inclusion of the energy broadening effect on MGD calculation produces negligible variations on the simulated results. 相似文献
16.
17.
Jianzhong Zhang Yusheng Zhao Jiang Qian Paulo A. Rigg Carl W. Greeff Yunpeng Yang Yanbin Wang 《Journal of Physics and Chemistry of Solids》2005,66(7):1213-1219
The phase diagram of zirconium metal has been studied using synchrotron X-ray diffraction and time-of-flight neutron scattering at temperatures and pressures up to 1273 K and 17 GPa. The equilibrium phase boundary of the α-ω transition has a dT/dP slope of 473 K/GPa, and the extrapolated transition pressure at ambient temperature is located at 3.4 GPa. For the ω-β transition, the phase boundary has a negative dT/dP slope of 15.5 K/GPa between 6.4 and 15.3 GPa, which is substantially smaller than a previously reported value of −39±5 K/GPa in the pressure range of 32-35 GPa. This difference indicates a significant curvature of the phase boundary between 15.3 and 35 GPa. The α-ω-β triple point was estimated to be at 4.9 GPa and 953 K, which is comparable to previous results obtained from a differential thermal analysis. Except for the three known crystalline forms, the β phase of zirconium metal was found to possess an extraordinary glass forming ability at pressures between 6.4 and 8.6 GPa. This transformation leads to a limited stability field for the β phase in the pressure range of 6-16 GPa and to complications of high-temperature portion of phase diagram for zirconium metal. 相似文献
18.
We discuss the existence of θ-vacua in pure Yang-Mills theory in two space-time dimensions. More precisely, a procedure is given which allows one to classify the distinct quantum theories possessing the same classical limit for an arbitrary connected gauge group G and compact space-time manifold M (possibly with boundary) possessing a special basepoint. For any such G and M it is shown that the above quantizations are in one-to-one correspondence with the irreducible unitary representations (IUR's) of π1(G) if M is orientable, and with the IUR's of π1(G)/2π1(G) if M is non-orientable. 相似文献
19.
Tanay Chattopadhyay Cláudia Reis Paulo André António Teixeira 《Optics Communications》2012,285(9):2266-2275
A novel scheme for an all-optical clocked D flip-flop, with very low complexity, is proposed and numerically demonstrated. This new flip-flop configuration is based on a semiconductor optical amplifier — Mach–Zehnder interferometer (SOA-MZI), with a feedback loop, and presents two stable states determined by the phase shift between the two MZI arms. 相似文献
20.
A. M. Osorio A P. J. Iunes G. Bigazzi J. C. Hadler N. M. A. Laurenzi P. Norelli C. A. Tello S. S. Guedes S. R. Paulo 《Radiation measurements》2003,36(1-6):407-412
Two Macusanite pebbles (MB1 and MB2) were dated with the fission-track method. Six irradiations were carried out in different nuclear reactors: Pavia (Italy), IPEN-CNEN (Brazil) and IPEN-Lima (Peru). Measurements of the thorium and uranium induced-fission per target nucleus using natural thorium thin films and natural U-doped glasses calibrated against natural uranium thin films, together with a λF of 8.46×10−17 a−1 were used to determine the ages. The apparent ages were corrected using the plateau and size correction methods. Track measurements were performed by different analysts, using different counting criteria. In addition, tracks were measured on samples which had been submitted to thermal treatment as well as on samples which had not been heated. Thermal treatments were carried out to erase the fossil tracks before neutron irradiation. No significant differences have been found in individual results, using the two Macusanite pebbles and the different nuclear reactors, age correction techniques, analysts, track-counting criteria, and thermal treatments before neutron irradiation. The great majority of the results (14/17) is compatible with the Ar–Ar ages of 5.12±0.11 and 5.10±0.11 Ma, Macusanite MB1 and MB2, respectively. However, the fission-track ages are systematically less (8%) than the Ar–Ar ages of the two Macusanite samples studied. 相似文献