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31.
Vera R. L. Constantino Luiz F. C. de Oliveira Paulo S. Santos Henrique E. Toma 《Transition Metal Chemistry》1994,19(1):103-107
Summary The synthesis, spectra and electrochemistry of [Ru(bipy)2-(picOH)]+ and -picO-[Ru(bipy)2]2
2+ (bipy = 2,2-bipyridine and picOH = 3-hydroxypicolinate ion) are described. The spectroscopic properties in the visible region are dominated by the intense Ru bipy chargetransfer transitions. In the binuclear complex, the two [Ru(bipy)2L]2+ moieties are nonequivalent, exhibiting E
1/2 = 0.69 and 1.20 V versus s.h.e. The partially oxidized species exhibits a weak intervalence transfer band at 1085 nm, and is consistent with a Robin-Day class II mixed valence complex. 相似文献
32.
Horacio R. Flores 《Thermochimica Acta》2007,452(1):49-52
Ulexite has a substantial amount of hydration water, which allows using calcination methods to increase the B2O3 content from 42.97 to 66.69%, due to the loss of 35.54% of its weight, corresponding to its hydration water.In this study, determinations of changes in the heat content at each temperature were made using an isoperibol calorimeter. The mean specific heat was calculated from these values. The reaction enthalpy was also determined by DTA methods.The sample used in the experiments contains 39.04% B2O3. The temperature was between 80 and 1000 °C. Curves of weight loss and enthalpy changes are presented and analysed.The results have industrial application in order to determine the thermal requirements for calcining ulexite at different temperatures, as well as its complete dehydration. 相似文献
33.
João Paulo R.F. André Hugh D. Burrows Carlos F.G.C. Geraldes Maria Da Graça M. Miguel M.Helena S.F. Teixeira L.F. Vilas Boas 《Polyhedron》1996,15(24):4331-4340
Complexation of europium(III) with glyceryl-1- and -2-phosphates has been studied by metal ion luminescence, 1H and 13C NMR spectroscopy and potentiometry. From the luminescence and NMR studies, the formation of a 1:1 inner-sphere complex, in which the glyceryl phosphate is directly bound to the metal, is confirmed. Similar apparent binding constants at pH 2 were obtained by the three methods. Values obtained by NMR at pH 2 are 53 M−1 and 12 M−1 for glyceryl-1- and -2-phosphate, respectively. By comparison with literature data on related systems it is suggested that the ligands bind through the phosphate group. To obtain structural information from the NMR data, complexation has also been studied with the lanthanide ions Dy(III), Er(III) and Gd(III) using both chemical shift and relaxation data. From this, metal-proton distance ratios have been calculated. Comparison of 1H and 13C NMR spectral data in the presence of paramagnetic lanthanides suggests conformational equilibria in the solutions. From the potentiometric studies, global formation constants have been determined, and speciation diagrams obtained over the pH range 1.5pH7.0 for ligand/metal ratios of 1 and 30. Implications of these results on lanthanide induced fusion of phospholipid membranes are discussed. 相似文献
34.
Joseph H. Montoya Kirsten T. Winther Raul A. Flores Thomas Bligaard Jens S. Hummelshj Muratahan Aykol 《Chemical science》2020,11(32):8517
We present an end-to-end computational system for autonomous materials discovery. The system aims for cost-effective optimization in large, high-dimensional search spaces of materials by adopting a sequential, agent-based approach to deciding which experiments to carry out. In choosing next experiments, agents can make use of past knowledge, surrogate models, logic, thermodynamic or other physical constructs, heuristic rules, and different exploration–exploitation strategies. We show a series of examples for (i) how the discovery campaigns for finding materials satisfying a relative stability objective can be simulated to design new agents, and (ii) how those agents can be deployed in real discovery campaigns to control experiments run externally, such as the cloud-based density functional theory simulations in this work. In a sample set of 16 campaigns covering a range of binary and ternary chemistries including metal oxides, phosphides, sulfides and alloys, this autonomous platform found 383 new stable or nearly stable materials with no intervention by the researchers.We present an end-to-end computational system for autonomous materials discovery. 相似文献
35.
J. Rodríguez Flores J. J. Berzas Nevado G. Castañeda Peñalvo M. I. Rodríguez Cáceres 《Chromatographia》2003,57(7-8):493-496
Summary Capillary zone electrophoresis (CZE) has been used for direct determination of 6-thioguanine, methotrexate, and 5-fluorouracil
in human urine, by use of a fused-silica capillary (60.2 cm×75 μm i.d.). Separation was performed after hydrodynamic injection
for 7 s; the separation potential and capillary temperature were 25 kV and 35°C, respectively. A 45mm borate buffer solution (pH 9.2) was used as separation electrolyte. Under these conditions the analysis takes approximately
10 min and interday precision of migration times and corrected peak areas is satisfactory. A linear response over the concentration
range 3.0–20.0 mg L1 was observed for the three chemotherapeutic drugs in diluted human urine. Detection limits (s/n=3) for 6-thioguanine and methotrexate were approximately 1.60 mg L1 in diluted human urine; that for fluorouracil was 2.60 mg L1. A 2-ml volume of human urine was diluted with 2-mL of water and introduced directly into the electrophoresis system. CZE
was shown to be a good method with regard to simplicity, satisfactory precision, and sensitivity. This method resulted in
especially excellent recoveries for determination of methotrexate in all the different urine samples analysed (n=10). 相似文献
36.
A new computationally-assisted methodology (PiMM), which accounts for the effects of intermolecular interactions in the crystal, is applied to the complete assignment of the Raman and infrared vibrational spectra of room temperature forms of crystalline caffeine, theobromine, and theophylline. The vibrational shifts due to crystal packing interactions are evaluated from ab initio calculations for a set of suitable molecular pairs, using the B3LYP/6-31G* approach.The proposed methodology provides an answer to the current demand for a reliable assignment of the vibrational spectra of these methyl-xanthines, and clarifies several misleading assignments. The most relevant intermolecular interactions in each system and their effect on the vibrational spectra are considered and discussed. Based on these results, significant insights are obtained for the structure of caffeine in the anhydrous form (stable at room temperature), for which no X-ray structure has been reported. A possible structure based on C((8))--H...N((9)) and C((1,3))--H...O intermolecular interactions is suggested. 相似文献
37.
Araceli Vernica Flores Carlos Alberto Prez Marco Aurlio Zezzi Arruda 《Analytica chimica acta》2005,530(2):619-305
In the present work, scandium was determined in sediment slurry samples (from three different rivers) by electrothermal atomic absorption spectrometry (ETAAS). Slurries were prepared by weighting 100 mg of dry sediment samples (≤53 μm particle sizes) and adding 6 ml of HCl:HNO3:HF (3:1:2, v/v). Accurate results were only possible due to the synergetic effect between Rh as permanent chemical modifier and acetylacetone (Acac) as complexing agent. The same platform was used for 400 heating cycles. The performance of the chemical modification was evaluated by using scanning electron microscopy (SEM), synchrotron radiation X-ray fluorescence (SRXRF) and some figures of merit (precision and detectability). The best analytical conditions were attained using 1500 and 2550 °C as pyrolysis and atomization temperatures. The scandium content in the liquid phase of the slurries ranged from 61 to 73%, thus indicating, in this study, that both liquid and solid phases play an important role in slurry analyses. An amount of 5.0–20.0 μg l−1 Sc linear range as well as LOD and LOQ of 0.19 and 0.62 μg l−1, respectively, were obtained under these conditions. The accuracy was checked by using microwave-assisted decomposition, and the results compared to those obtained with the proposed methodology (slurry analysis). By checking both sets of the results, there is no statistical difference at the 95% confidence levels. 相似文献
38.
J. J. Berzas Nevado J. Rodríguez Flores G. Castaeda Pealvo 《Analytica chimica acta》1997,340(1-3):257-265
Two spectrophotometric methods for the determination of Ethinylestradiol (ETE) and Levonorgestrel (LEV) by using the multivariate calibration technique of partial least square (PLS) and principal component regression (PCR) are presented. In this study the PLS and PCR are successfully applied to quantify both hormones using the information contained in the absorption spectra of appropriate solutions. In order to do this, a calibration set of standard samples composed of different mixtures of both compounds has been designed. The results found by application of the PLS and PCR methods to the simultaneous determination of mixtures, containing 4–11 μg ml−1 of ETE and 2–23 μg ml−1 of LEV, are reported. Five different oral contraceptives were analyzed and the results were very similar to that obtained by a reference liquid Chromatographic method. 相似文献
39.
Zamudio-Rivera LS George-Tellez R López-Mendoza G Morales-Pacheco A Flores E Höpfl H Barba V Fernández FJ Cabirol N Beltrán HI 《Inorganic chemistry》2005,44(15):5370-5378
The one pot reaction of salicylaldehyde 1, beta-amino alcohols 2a-2c, and di-n-butyltin(IV) oxide 3a or diphenyltin(IV) oxide 3b produced five diorganotin(IV) compounds, 4a-4c, 5a, and 5c, in good yields. All compounds were characterized by IR, (1)H, (13)C, and (119)Sn NMR spectroscopy, and elemental analysis; furthermore, compounds 4b, 4c, 5a, and 5c were characterized by X-ray diffraction analysis. After the structural characterization, all of the compounds were tested in vitro against Bacillus subtilis (Gram-positive, strain ATCC 6633), Escherichia coli (Gram-negative, strain DH5alpha), Pseudomonas aeruginosa (Gram-negative, strain BH3), Desulfovibrio longus (strain DSM 6739), and Desulfomicrobium aspheronum (strain DSM 5918) to assess their antimicrobial activity. Compounds 4 and 5 demonstrated a wide range of bactericidal activities against the tested aerobic (one Gram-positive and two Gram-negative subtypes) and anaerobic bacteria (two sulfate-reducing bacteria, SRB). Compound 5 had better bactericidal performances than compound 4. For all of the compounds, the acute toxicity was measured using luminescent bacteria toxicity (LBT-Microtox) tests to track their further environmental impact. According to these results and in order to fulfill environmental regulations, the toxicity of the compounds studied herein can be modulated through the proper selection of the disubstituted tin(IV) moiety. 相似文献
40.
Development of a bionematicide with Paecilomyces lilacinus to control Meloidogyne incognita 总被引:1,自引:0,他引:1
Brand D Roussos S Pandey A Zilioli PC Pohl J Soccol CR 《Applied biochemistry and biotechnology》2004,118(1-3):81-88
Root-knot disease caused by Meloidogyne incognita is a matter of grave concern because it affects several economically important crop plants. The use of solid-state fermentation
(SSF) may help to elaborate efficient formulations with fungi to be employed in the biologic control of nematodes. Attempts
were made to select low-cost substrates for spore production of a strain of Paecilomyces lilacinus with known nematicide capacity. Coffee husks, cassava bagasse, and defatted soybean cake were utilized as substrates, and
sugarcane bagasse was used as support. Fermentations were carried out in flasks covered with filter paper at 28°C for 10 d.
The products obtained by SSF were evaluated for their nematicide activity in pot experiments containing one seedling of the
plant Coleus inoculated with the nematode M. incognita. The plants were evaluated 2 mo after inoculation. Fermented products showed a reduction in the number of nematodes. The
best results were obtained with defatted soybean cake, which showed almost 100% reduction in the number of nematodes; the
reduction with coffee husk was 80% and with cassava bagasse was about 60%. 相似文献