Electromagnetic fields in magnetic materials: A resource letter

This work is a collection of selected, significant references focussing upon magnetic materials and their interaction with electromagnetic fields. The major topics included are ferrites, plasmas (both atmospheric and laboratory), magnetic composites, magnetic dielectric fluids, ferroelectric liquid crystals. Sections discussing general magnetic materials and phenomena are also included.     

Search for direct single-photon production at large pT in photon-proton collisions at √s = 62.4 GeV

As part of a study of large p_T phenomena in photon-proton collisions at the CERN ISR, a search for direct single photon production has been performed. A statistical division of the data sample into the fraction consistent with single photon and the fraction due to multiphoton decays of neutral hadrons is accomplished by measuring the average conversion probability for the sample in a one radiation length thick converter. The fraction of the sample attributable to direct single photon production is 〈γ/all〉 = 0.074 ± 0.012 for 6 GeV/c < p_T 10 GeV/c, and 〈γ/all〉 = 0.26 ± 0.04 for p_T > 10 GeV/c, with an additional systematic uncertainty of ±0.05 for both values.     

Neue Tetrathiocyanato-Diamin-Chromiate mit Naphthylaminen

New Tetrathiocyanato Diamin Chromiates with Naphthylamines Substitution reactions of anhydrous K₃[Cr(NCS)₆] with α- and β-naphthyl- amine without applying of solvents were carried out. The formulae of the new positionisomer complex anions were established with a series of double decomposition reactions with the hydrochlorides of some heterocyclic N-bases and cobalt(III) amines. From spectroscopical investigations -UV and UR) some structural problems are resolved.     

Asymmetric 1,4-reductions of hindered beta-substituted cycloalkenones using catalytic SEGPHOS-ligated CuH

The reagent combination of catalytic amounts of copper hydride ligated by a nonracemic SEGPHOS ligand leads in situ to an extremely reactive species capable of effecting asymmetric hydrosilylations of conjugated cyclic enones in very high ees. An unprecedented substrate-to-ligand ratio as high as 275 000:1 for this transformation has been documented. [reaction: see text]     

Construction of proximal distances over symmetric cones

Abstract

This paper is devoted to the study of proximal distances defined over symmetric cones, which include the non-negative orthant, the second-order cone and the cone of positive semi-definite symmetric matrices. Specifically, our first aim is to provide two ways to build them. For this, we consider two classes of real-valued functions satisfying some assumptions. Then, we show that its corresponding spectrally defined function defines a proximal distance. In addition, we present several examples and some properties of this distance. Taking into account these properties, we analyse the convergence of proximal-type algorithms for solving convex symmetric cone programming (SCP) problems, and we study the asymptotic behaviour of primal central paths associated with a proximal distance. Finally, for linear SCP problems, we provide a relationship between the proximal sequence and the primal central path.     

Reactivity of (ferrocenylmethyl)phosphine toward palladium and platinum chlorides. X-ray structure of [Pd(PH2CH2Fc)Cl(mu-PHCH2Fc)]4 (Fc = ferrocenyl), a unique complex containing a Pd4P4 cycle

The reaction of 2 equiv of the air-stable primary phosphine (ferrocenylmethyl)phosphine (PH2CH2Fc, 1) with [Pd(cod)Cl2] (Fc = ferrocenyl; cod = 1,5-cyclooctadiene) at 298 K gave the phosphanido-bridged Pd(II) tetramer [Pd(PH2CH2Fc)Cl(mu-PHCH2Fc)]4 (2), which shows an unprecedented arrangement of four Pd atoms embedded in an eight-membered Pd4P4 ring. An X-ray diffraction study showed that 2 crystallizes in the triclinic space group P with a = 17.607(7) A, b = 17.944(7) A, c = 18.792(7) A, alpha = 107.120(12) degrees, beta = 96.344(13) degrees, gamma = 117.087(15) degrees . Each molecule contains four palladium atoms in a distorted square-planar coordination formed by one chlorine and three phosphorus atoms. Two of the latter belong to bridging primary phosphanides and the remaining one is contributed by a terminal PH2CH2Fc ligand. The coordination environments of neighboring metal centers adopt an almost perpendicular mutual orientation. The reaction of 2 equiv of 1 with [Pt(cod)Cl2] at 323 K yielded the analogous Pt(II) tetramer of formula [Pt(PH2CH2Fc)Cl(mu-PHCH2Fc)]4 (3), which was fully characterized by multinuclear and dynamic NMR, IR, and elemental analyses. Single-crystal X-ray diffraction on 3 confirmed the tetranuclear arrangement in the solid state, but orientational disorder of the molecule precludes a more detailed discussion of the structure. Low-temperature NMR experiments in CD2Cl2 showed the presence of two slowly interconnecting conformers. Reaction of 1 and [M(cod)Cl2] (M = Pd or Pt) at lower temperatures (273 K for Pd, 295 K for Pt) in dichloromethane allowed the detection in solution of the mononuclear species cis-[M(PH2CH2Fc)2Cl2] (M = Pd, 4; M = Pt, 5) which, upon heating, transformed into the tetramers 2 and 3, respectively. Solid samples of 4 and 5 could be isolated after workup at low temperature and were characterized by conventional spectroscopic methods.     

Connection between complete and Möbius forms of gauge invariant operators

We study the connection between complete representations of gauge invariant operators and their Möbius representations acting in a limited space of functions. The possibility to restore the complete representations from Möbius forms in the coordinate space is proven and a method of restoration is worked out. The operators for transition from the standard BFKL kernel to the quasi-conformal one are found both in Möbius and total representations.     

QSAR classification models for the screening of the endocrine-disrupting activity of perfluorinated compounds

Perfluorinated compounds (PFCs) are a class of emerging pollutants still widely used in different materials as non-adhesives, waterproof fabrics, fire-fighting foams, etc. Their toxic effects include potential for endocrine-disrupting activity, but the amount of experimental data available for these pollutants is limited. The use of predictive strategies such as quantitative structure-activity relationships (QSARs) is recommended under the REACH regulation, to fill data gaps and to screen and prioritize chemicals for further experimentation, with a consequent reduction of costs and number of tested animals. In this study, local classification models for PFCs were developed to predict their T4-TTR (thyroxin-transthyretin) competing potency. The best models were selected by maximizing the sensitivity and external predictive ability. These models, characterized by robustness, good predictive power and a defined applicability domain, were applied to predict the activity of 33 other PFCs of environmental concern. Finally, classification models recently published by our research group for T4-TTR binding of brominated flame retardants and for estrogenic and anti-androgenic activity were applied to the studied perfluorinated chemicals to compare results and to further evaluate the potential for these PFCs to cause endocrine disruption.     

Extremal sizes of subspace partitions

A subspace partition Π of V?= V(n, q) is a collection of subspaces of V such that each 1-dimensional subspace of V is in exactly one subspace of Π. The size of Π is the number of its subspaces. Let σ _q (n, t) denote the minimum size of a subspace partition of V in which the largest subspace has dimension t, and let ρ _q (n, t) denote the maximum size of a subspace partition of V in which the smallest subspace has dimension t. In this article, we determine the values of σ _q (n, t) and ρ _q (n, t) for all positive integers n and t. Furthermore, we prove that if n ≥?2t, then the minimum size of a maximal partial t-spread in V(n +?t ?1, q) is σ _q (n, t).