An efficient synthesis of anti-microbial 1,2,4-triazole-3-thiones promoted by acidic ionic liquid

Acidic ionic liquid, [(Py)₂SO][HSO₄]₂ has been used as an efficient catalyst for the reaction of ketone with thiosemicarbazide in ethanol at room temperature for the eco-friendly synthesis of spiro-1,2,4-triazolidine-3-thiones. Smooth reactions, ambient temperature, use of alcohol as a solvent, high yields, easy work-up procedure and excellent recyclability of ionic liquid and high atom economy are the auxiliary advantages of the present protocol, which makes it ecofriendly. All the synthesized 1,2,4-trioazoles were screened for antimicrobial activity. Most of compounds displayed moderate to good biological activity.     

Effects of thermal buoyancy and variable thermal conductivity on the MHD flow and heat transfer in a power-law fluid past a vertical stretching sheet in the presence of a non-uniform heat source

The paper considers the flow of a power-law fluid past a vertical stretching sheet. Effects of variable thermal conductivity and non-uniform heat source/sink on the heat transfer are addressed. The thermal conductivity is assumed to vary linearly with temperature. Similarity transformation is used to convert the governing partial differential equations into a set of coupled, non-linear ordinary differential equations. Two different types of boundary heating are considered, namely Prescribed power-law Surface Temperature (PST) and Prescribed power-law Heat Flux (PHF). Shooting method is used to obtain the numerical solution for the resulting boundary value problems. The effects of Chandrasekhar number, Grashof number, Prandtl number, non-uniform heat source/sink parameters, wall temperature parameter and variable thermal conductivity parameter on the dynamics are shown graphically in several plots. The skin friction and heat transfer coefficients are tabulated for a range of values of the parameters. Present study reveals that in a gravity affected flow buoyancy effect has a significant say in the control of flow and heat transfer.     

Heat Transport in an Anisotropic Porous Medium Saturated with Variable Viscosity Liquid Under G-jitter and Internal Heating Effects

Thermo-rheological effect of temperature-dependent viscous fluid saturating a porous medium has been studied in the presence of imposed time periodic gravity field and internal heat source. Weak nonlinear stability analysis has been performed by using the power series expansion in terms of the amplitude of gravity modulation, which is considered to be small. Nusselt number is calculated numerically using Ginzburg–Landau equation. The nonlinear effects of thermo-mechanical anisotropies, internal heat source parameter, Vadász number, thermo-rheological parameter and amplitude of gravity modulation have been obtained and depicted graphically. Streamlines and isotherms have been drawn for different times. Comparisons have been made between various physical systems.     

Correction to: Effect of trigonometric sine,square and triangular wavetype time-periodic gravity-aligned oscillations on Rayleigh–Bénard convection in Newtonian liquids and Newtonian Nanoliquids

Meccanica - The original article has been updated due to typesetting mistakes made in Section 2.2 Mathematical formulation, Table 1 and in Equation (51).     

Effect of trigonometric sine,square and triangular wave-type time-periodic gravity-aligned oscillations on Rayleigh–Bénard convection in Newtonian liquids and Newtonian nanoliquids

The influence of trigonometric sine, square and triangular wave-types of time-periodic gravity-aligned oscillations on Rayleigh–Bénard convection in Newtonian liquids and in Newtonian nanoliquids is studied in the paper using the generalized Buongiorno two-phase model. The five-mode Lorenz model is derived under the assumptions of Boussinesq approximation, small-scale convective motion and some slip mechanisms. Using the method of multiscales, the Lorenz model is transformed to a Ginzburg–Landau equation the solution of which helps in quantifying the heat transport through the Nusselt number. Enhancement of heat transport in Newtonian liquids due to the presence of nanoparticles/nanotubes is clearly explained. The study reveals that all the three wave types of gravity modulation delay the onset of convection and thereby to a diminishment of heat transport. It is also found that in the case of trigonometric sine type of gravity modulation heat transport is intermediate to that of the cases of triangular and square types. The paper is the first such work that attempts to theoretically explain the effect of three different wave-types of gravity modulation on onset of convection and heat transport in the presence/absence of nanoparticles/nanotubes. Comparing the heat transport by the single-phase and by the generalized two-phase models, the conclusion is that the single-phase model under-predicts heat transport in nanoliquids irrespective of the type of gravity modulation being effected on the system. The results of the present study reiterate the findings of related experimental and numerical studies.