全文获取类型
收费全文 | 232760篇 |
免费 | 2250篇 |
国内免费 | 800篇 |
专业分类
化学 | 116831篇 |
晶体学 | 3996篇 |
力学 | 10757篇 |
综合类 | 1篇 |
数学 | 25503篇 |
物理学 | 78722篇 |
出版年
2020年 | 1787篇 |
2019年 | 2043篇 |
2018年 | 2719篇 |
2017年 | 2651篇 |
2016年 | 3913篇 |
2015年 | 2390篇 |
2014年 | 3969篇 |
2013年 | 10072篇 |
2012年 | 7531篇 |
2011年 | 9392篇 |
2010年 | 6685篇 |
2009年 | 6629篇 |
2008年 | 8701篇 |
2007年 | 8733篇 |
2006年 | 8272篇 |
2005年 | 7492篇 |
2004年 | 6918篇 |
2003年 | 6111篇 |
2002年 | 6061篇 |
2001年 | 7090篇 |
2000年 | 5372篇 |
1999年 | 4236篇 |
1998年 | 3563篇 |
1997年 | 3472篇 |
1996年 | 3293篇 |
1995年 | 3008篇 |
1994年 | 2951篇 |
1993年 | 3042篇 |
1992年 | 3151篇 |
1991年 | 3332篇 |
1990年 | 3084篇 |
1989年 | 3027篇 |
1988年 | 3066篇 |
1987年 | 2955篇 |
1986年 | 2800篇 |
1985年 | 3808篇 |
1984年 | 4005篇 |
1983年 | 3198篇 |
1982年 | 3410篇 |
1981年 | 3336篇 |
1980年 | 3230篇 |
1979年 | 3335篇 |
1978年 | 3422篇 |
1977年 | 3350篇 |
1976年 | 3448篇 |
1975年 | 3141篇 |
1974年 | 3150篇 |
1973年 | 3194篇 |
1972年 | 2235篇 |
1971年 | 1849篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Markus Bödenler Ludovic de Rochefort P. James Ross Nicolas Chanet Geneviève Guillot Gareth R. Davies 《Molecular physics》2019,117(7-8):832-848
ABSTRACTFast field-cycling (FFC) nuclear magnetic resonance relaxometry is a well-established method to determine the relaxation rates as a function of magnetic field strength. This so-called nuclear magnetic relaxation dispersion gives insight into the underlying molecular dynamics of a wide range of complex systems and has gained interest especially in the characterisation of biological tissues and diseases. The combination of FFC techniques with magnetic resonance imaging (MRI) offers a high potential for new types of image contrast more specific to pathological molecular dynamics. This article reviews the progress in FFC-MRI over the last decade and gives an overview of the hardware systems currently in operation. We discuss limitations and error correction strategies specific to FFC-MRI such as field stability and homogeneity, signal-to-noise ratio, eddy currents and acquisition time. We also report potential applications with impact in biology and medicine. Finally, we discuss the challenges and future applications in transferring the underlying molecular dynamics into novel types of image contrast by exploiting the dispersive properties of biological tissue or MRI contrast agents. 相似文献
82.
83.
Dr. Man-Bo Li Daniels Posevins Dr. Karl P. J. Gustafson Dr. Cheuk-Wai Tai Dr. Andrey Shchukarev Dr. Youai Qiu Dr. Jan-E. Bäckvall 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(1):210-215
A highly selective and efficient oxidative carbocyclization/borylation of enallenols catalyzed by palladium immobilized on amino-functionalized siliceous mesocellular foam (Pd-AmP-MCF) was developed for diastereoselective cyclobutenol synthesis. The heterogeneous palladium catalyst can be recovered and recycled without any observed loss of activity or selectivity. The high diastereoselectivity of the reaction is proposed to originate from a directing effect of the enallenol hydroxyl group. Optically pure cyclobutenol synthesis was achieved by the heterogeneous strategy by using chiral enallenol obtained from kinetic resolution. 相似文献
84.
Mathematical Notes - We prove the equivalence of a vector and a scalar equilibrium problem that naturally arise when studying the limit distribution of zeros of type I Hermite–Padé... 相似文献
85.
Lebedev V. T. Serebrov A. P. 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2020,14(1):1-5
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques - A method for studying the magnetic dynamics of endofullerenes M@C2n (2n = 60, 70, …) and their derivatives,... 相似文献
86.
87.
88.
Siberian Mathematical Journal - Under study are the right-symmetric algebras over a field $ F $ which possess a “unital” matrix subalgebra $... 相似文献
89.
Vanessa R. Machado Louis P. Sandjo Giovanni L. Pinheiro Milene H. Moraes Mario Steindel Moacir G. Pizzolatti 《Natural product research》2018,32(3):275-281
The natural product lupeol 1 was isolated from aerial parts of Vernonia scorpioides with satisfactory yield, which made it viable to be used as starting material in semisynthetic approach. Ten lupeol derivatives 2–11 were prepared by classical procedures. Including, five new esters derivatives 7–11, which were obtained by structural modifications in the isopropylidene fragment. All semisynthetic compounds and lupeol 1–11 were confirmed by 1H NMR, 13C NMR and HRMS. Their antiprotozoal activity was evaluated in vitro against L. amazonensis and T. cruzi. Derivative 6 showed the best antitrypanosomal activity (IC50 = 12.48 μg/mL) and the lowest cytotoxic derivative (CC50 = 161.50 μg/mL). The mechanism of action of the most active derivatives (4, 6 and 11) is not dependent from the enzyme trypanothione reductase. 相似文献
90.
N. I. Golovina G. N. Nechiporenko G. G. Nemtsev G. P. Dolganova V. P. Roshchupkin D. B. Lempert G. B. Manelis 《Russian Journal of Applied Chemistry》2007,80(1):24-30
Methods for phase stabilization of ammonium nitrate were sought for in order to considerably expand the application area of this oxidizing agent in various-purpose self-combustible formulations, including that in a new generation of gas-generating formulations for automobile air bags. New methods for stabilization of ammonium nitrate were studied and, in particular, a search was made for organic compounds that can stabilize ammonium nitrate even at their low content. The mechanism of phase state stabilization of ammonium nitrate by compounds of this kind was examined. 相似文献