Studies on Rare-Earth/Iron and Actinide/Iron Multilayers

Hyperfine Interactions - Multilayers of Ce/Fe and U/Fe were fabricated by sputtering and studied by X-ray diffraction and reflectivity, Mössbauer spectroscopy and polarised neutron...     

Application of time-variable feedback to the input amplifier of pulse magnetic resonance spectrometers: Experimental studies

Experimental research on the improvement of the sensitivity and time resolution of pulsed magnetic resonance spectrometers is discussed. It is shown that application of a time-variable feedback of a signal to the input of the receiver amplifier can decouple, the “fixed” relationship between the quality factorQ and the ringdown time of the resonance system. Experiments were performed with low-frequency, radio-frequency and microwave pulse-type magnetic resonance receivers. Modifications of an S/C-band electron spin echo modulation spectrometer carried out to check the “time-variable feedback” performance are described. It is demonstrated that the application of a time-variable feedback can significantly reduce the ringdown time and improve the recovery properties of the magnetic resonance receiver system. It is also demonstrated that the time-variable feedback can improve the overall receiver sensitivity due to the fact that the working bandwidth of the resonance system can be optimized separately for the transmitting and the receiving mode. Signal values could be increased at least three times and the signal-to-noise ratio about 1.5–2 times. The largest improvement is achieved with the initially overcoupled resonator. Experimental spectra of test samples for different settings of the time-variable feedback are shown.     

Four-Dimensional Lie Group Integration of the Klein–Fock Equation

A method of four-dimensional Lie group integration of the Fock–Klein equation is described in the present paper. The method is based on the formalism of co-adjoint representation orbits and on the non-commutative integration method. Right-invariant metrics being solutions of the Einstein equation are also classified for manifolds of four-dimensional Lie groups.     

A rapid and sensitive extractive spectrophotometric determination of copper(II) in pharmaceutical and environmental samples using benzildithiosemicarbazone.

Benzildithiosemicarbazone (BDTSC) is proposed as a sensitive and selective analytical reagent for the extractive spectrophotometric determination of copper(II). BDTSC reacts with copper(II) in the pH range 1.0-7.0 to form a yellowish complex. Beer's law is obeyed in the concentration range 0.5-0.4 microg cm(-3). The yellowish Cu(II)-BDTSC complex in chloroform shows a maximum absorbance at 380 nm, with molar absorptivity and Sandell's sensitivity values of 1.63 x 10(4) dm3 mol(-1) cm(-1) and 0.00389 microg cm(-2), respectively. A repetition of the method is checked by finding the relative standard deviation (RSD) (n = 10), which is 0.6%. The composition of the Cu(II)-BDTSC complex is established as 1:1 by slope analysis, molar ratio and Asmus' methods. An excellent linearity with a correlation coefficient value of 0.98 is obtained for the Cu(II)-BDTSC complex. The instability constant of the complex calculated from Edmond and Birnbaum's method is 7.70 x 10(-4) and that of Asmus' method is 7.66 x 10(-4), at room temperature. The method is successfully employed for the determination copper(II) in pharmaceutical and environmental samples. The reliability of the method is assured by analyzing the standard alloys (BCS 5g, 10g, 19e, 78, 32a, 207 and 179) and by inter-comparison of experimental values, using an atomic absorption spectrometer.     

Reaction of Chloroacetone with Cytisine and d-Pseudoephedrine Alkaloids

Alkylation of cytisine and d-pseudoephedrine alkaloids with chloroacetone was performed. The target product of the reaction with cytisine is aminoacetone and of the reaction with d-pseudoephedrine, a morpholine derivative.     

Superstable semigroups of operators

In [NR] the authors introduced the notion of superstable operators on a Banach space E using ultrapowers E_u of E. In [HR] this notion was extended to strongly continuous one-parameter semigroups again by means of ultrapowers.It is the aim of the present paper to give an equivalent intrinsic definition of superstability (without the reference to ultrapowers). This definition allows us to improve the results of [NR] as well as of [HR]. We apply our results to semigroups of positive linear operators on Banach lattices and C^*-algebras, respectively.     

Quantitative measurements of micro- and macromixing in a stirred vessel using Planar Laser-Induced Fluorescence

The Planar Laser-Induced Fluorescence (PLIF) technique enables measurement of the local degree of deviation in an arbitrary plane inside the mixing vessel. This is achieved by injecting a mixture of an inert dye and a reacting fluorescent into the vessel. The inert dye serves as a tracer for the macromixing. The fluorescent characteristics of the reacting dye change while undergoing a fast chemical reaction with the vessel content and it therefore shows the micromixing indirectly. The concentration fields of the dyes are measured simultaneously. For that a laser beam is expanded into a thin light sheet which illuminates an arbitrary plane in the mixing vessel, exciting the fluorescent dye in this area. The emitted light is detected by a CCD-camera which is positioned vertical to the measurement plane. The fluorescent light passes through two optical filters which are suitable for separating the fluorescent light of the two dyes. The light is then projected on half of the camera chip each so that the same display window is detected twice, and thus the local concentration of the two dyes can be measured simultaneously. Low Reynolds number measurements are performed in a mixing vessel equipped with a Rushton turbine. The lamellar structure is clearly resolved. Areas of micromixing are detected by calculating the local degree of deviation from the concentration fields. These areas are mainly found in the boundary layer of the lamellas.