First lanthanide dipolar complexes for second-order nonlinear optics

New push-pull NLO-phores based on lanthanide complexes (Ln = La, Gd, Dy, Yb) featuring an annelated dibutylaminophenyl functionalised terpyridyl ligand have been synthesised and shown to exhibit large first-order hyperpolarizability.     

Intramolecularly hydrogen-bonded versus copper(II) coordinated mono- and bis-phenoxyl radicals

Ligands bearing two salicylidene imine moieties substituted in ortho and para positions by tert-butyl groups have been electrochemically oxidized into mono- and bis-phenoxyl radicals. The process involves an intramolecular proton coupled to electron transfer and affords a radical in which the oxygen atom is hydrogen-bonded to a protonated ammonium or iminium group. A weak intramolecular dipolar interaction exists between the two phenoxyl moieties in the bis-radical species. The copper(II) complexes of these ligands have been characterized and electrochemically oxidized. The mono-phenoxyl radical species are X-band EPR silent. The bis-phenoxyl radical species exhibits a (S= 3/2) ground state: it arises from a ferromagnetic exchange coupling between the two spins of the radicals and that of the copper(II) when the spacer is rigid enough; a flexible spacer such as ethylidene induces decomplexation of at least one phenoxyl group. Metal coordination is more efficient than hydrogen-bonding to enhance the chemical stability of the mono-phenoxyl radicals.     

Enhanced two-photon absorption with novel octupolar propeller-shaped fluorophores derived from triphenylamine

[structure: see text] Novel octupolar fluorophores derived from the symmetrical functionalization of a triphenylamine core with strong acceptor peripheral groups via phenylene-ethynylene linkers have been synthesized and shown to exhibit high fluorescence quantum yields, very large TPA cross-sections in the red-NIR region, and suitable photostability.     

Groupes plongés quasi isométriquement dans un groupe de Lie

Soit un sous-groupe discret de type fini dun groupe de Lie semi-simple G. On donne ici une condition suffisante pour que linjection de dans le groupe G admet un voisinage de représentations fidèles et discrètes.     

Sur les caractères du groupe de Suzuki

Let σ be the automorphism of $\mathrm{Sp}(4\text{,}{2}^{2n+1})$ so that the set of fixed points is the Suzuki group. We propose in this Note to calculate the irreductible characters of $\mathrm{Sp}(4\text{,}{2}^{2n+1})?〈\sigma 〉$, extension of degree two of the symplectic group, and describe two consequences: first, the principal block of the Suzuki group and of this extension are perfectly isometric, and secondly we determine the eigenvalues of Frobenius of the unipotent characters of the Suzuki group. To cite this article: O. Brunat, C. R. Acad. Sci. Paris, Ser. I 339 (2004).     

Time-resolved tracking of a sound scatterer in a complex flow: nonstationary signal analysis and applications

It is known that ultrasound techniques yield nonintrusive measurements of hydrodynamic flows. For example, the study of the echoes produced by a large number of particles insonified by pulsed wavetrains has led to a now-standard velocimetry device. In this paper, a new technique for the measurement of the velocity of individual solid particles moving in fluid flows is proposed. It relies on the ability to resolve in time the Doppler shift of the sound scattered by the continuously insonified particle. For this signal-processing problem two classes of approaches can be used: time-frequency analysis and parametric high-resolution methods. In the first class the spectrogram and reassigned spectrogram is considered, and applied to detect the motion of a small bead settling in a fluid at rest. In nonstationary flows, methods in the second class are more robust. An approximated maximum likelihood (AML) technique has been adapted, coupled with a generalized Kalman filter. This method allows for the estimation of rapidly varying frequencies; the parametric nature of the algorithm also provides an estimate of the variance of the identified frequency parameters.     

Large-scale finite-wavelength modulation within turbulent shear flows

We show that turbulent "spirals" and "spots" observed in Taylor-Couette and plane Couette flow correspond to a turbulence-intensity modulated finite-wavelength pattern which in every respect fits the phenomenology of coupled noisy Ginzburg-Landau (amplitude) equations with noise. This suggests the existence of a long-wavelength instability of the homogeneous turbulence regime.     

Self-healing slip pulses along a gel/glass interface

We present experimental evidence of self-healing shear cracks at a gel/glass interface. This system exhibits two dynamical regimes depending on the driving velocity: steady sliding at high velocity (>V(c) approximately 100--125 microm/s), characterized by a shear-thinning rheology, and periodic stick-slip dynamics at low velocity. In this last regime, slip occurs by propagation of pulses that restick via a "healing instability" occurring when the local sliding velocity reaches the macroscopic transition velocity V(c). At driving velocities close below V(c), the system exhibits complex spatiotemporal behavior.     

Multispecies pair annihilation reactions

We consider diffusion-limited reactions A(i)+A(j)--> (1< or =i2 and d> or =2, we argue that the asymptotic density decay for such mutual annihilation processes with equal rates and initial densities is the same as for single-species pair annihilation A+A-->. In d=1, however, particle segregation occurs for all q< infinity. The total density decays according to a q dependent power law, rho(t) approximately t(-alpha(q)). Within a simplified version of the model alpha(q)=(q-1)/2q can be determined exactly. Our findings are supported through Monte Carlo simulations.