Effects of prescribed heat flux and transpiration on MHD axisymmetric flow impinging on stretching cylinder

A numerical treatment for axisymmetric flow and heat transfer due to a stretching cylinder under the influence of a uniform magnetic field and prescribed surface heat flux is presented. Numerical results are obtained for dimensionless velocity, temperature, skin friction coefficient and Nusselt number for several values of the suction/injection, magnetic and curvature parameters as well as the Prandtl number. The present study reveals that the controlling parameters have strong effects on the physical quantities of interest. It is seen that the magnetic field enhances the dimensionless temperature inside the thermal boundary layer, whereas it reduces the dimensionless velocity inside the hydrodynamic boundary layer. Heat transfer rate reduces, while the skin friction coefficient increases with magnetic field.     

Synthesis of highly pure poly(aryleneethnylene)s using palladium supported on calcium carbonate as an eco‐friendly heterogeneous catalyst

Metal catalyst contamination is a major concern in the preparation of polymeric materials. For conjugate polymers, trace amount of metal catalyst is detrimental to the optoelectronic properties. In this work, a method for synthesizing highly pure fluorescent polymers, poly(aryleneethynylene)s (PAEs), was developed using heterogeneous Pd/CaCO₃ catalytic system. Polymerization between a variety of aryl diethynes and aryl diiodides or dibromides were achieved using a catalytic amount of Pd/CaCO₃, CuI, and PPh₃ at 80 °C in good to excellent yields (79–100%). Resulting polymers possess degree of polymerization ranging from 8 to 50 with polydispersity index of 1.5–3.6. Importantly, PAEs from Pd/CaCO₃ catalytic system contain considerably lower level of Pd and Cu contamination (1.9 and 3.4 ppm, respectively) than those obtained from classical homogeneous catalyst, Pd(PPh₃)₄ and PdCl₂(PPh₃)₂ or heterogeneous catalyst Pd/C. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1556–1563