Fully polynomial time $$(\Sigma ,\Pi )$$ -approximation schemes for continuous nonlinear newsvendor and continuous stochastic dynamic programs

Mathematical Programming - We study the nonlinear newsvendor problem concerning goods of a non-discrete nature, and a class of stochastic dynamic programs with several application areas such as...     

Similarity Classes of 3 × 3 Matrices Over a Local Principal Ideal Ring

In this article similarity classes of three by three matrices over a local principal ideal commutative ring are analyzed. When the residue field is finite, a generating function for the number of similarity classes for all finite quotients of the ring is computed explicitly.     

Measuring small compartments with relatively weak gradients by angular double-pulsed-field-gradient NMR

NMR diffusion–diffraction patterns observed in compartments in which restricted diffusion occurs are a useful tool for direct extraction of compartment sizes. Such diffusion–diffraction patterns may be observed when the signal intensity E_(q,?) is plotted against the wave-vector q (when q = (2π)^− 1γδG). However, the smaller the compartment sizes are, the higher are the q-values needed to observe such diffractions. Moreover, these q-values should be achieved using short gradient pulses requiring extremely strong gradient systems. The angular double-pulsed-field gradient (d-PFG) NMR methodology has been proposed as a tool to extract compartment sizes using relatively low q-values. In this study, we have used single-PFG (s-PFG) NMR and angular d-PFG NMR to characterize the size of microcapillaries of about 2 ± 1 μm in diameter. We found that these microcapillaries are characterized by relatively strong background gradients that completely masked the effects of the microscopic anisotropy (μA) of the sample, resulting in a completely unexpected E(φ) profile in the angular d-PFG NMR experiments. We also show that bipolar angular d-PFG NMR experiments can largely suppress the effect of these background gradients resulting in the expected E(φ) profile from which the compartment dimensions could be obtained with relatively weak gradient pulses. These results demonstrate that the above methodology provides a quick, reliable, non-invasive means for estimating small pore sizes with relatively weak gradients in the presence of large magnetic susceptibility.     

Generic singular configurations of linkages

We study the topological and differentiable singularities of the configuration space C(Γ) of a mechanical linkage Γ in Rd, defining an inductive sufficient condition to determine when a configuration is singular. We show that this condition holds for generic singularities, provide a mechanical interpretation, and give an example of a type of mechanism for which this criterion identifies all singularities.     

Motion and shape of an axisymmetric viscoplastic drop slowly falling through a viscous fluid

Slow sedimentation of a deformable drop of Bingham fluid in an unbounded Newtonian medium is studied using a variation of the integral equation method (Toose et al., J Eng Math 30:131–150, 1996, Int J Numer Methods Fluids 30:653–674, 1999). The Green function for the Stokes equation is used, and the non-Newtonian stress is treated as a source term. The computations are performed for a range of physical parameters of the system. It is demonstrated that initially deformed drop similar to Newtonian ones breaks up for high capillary number, Ca, and stabilizes to steady shapes at low Ca. Estimations of critical capillary number for specific initial deformations demonstrated its growth (increase in the stability of the drop) with the yield stress magnitude both for prolate and oblate initial shapes. Prolate initial shapes become more stable with the increase of the plastic viscosity. In contrast to this, for low yield stress, oblate shapes are destabilized with the growth of the plastic viscosity. This effect is similar to the effect of the viscosity of a Newtonian drop on its stability. However, at higher yield stress, the effect of plastic viscosity is reversed.     

Exponential Riesz Bases, Discrepancy of Irrational Rotations and BMO

We study the basis property of systems of exponentials with frequencies belonging to ‘simple quasicrystals’. We show that a diophantine condition is necessary and sufficient for such a system to be a Riesz basis in L ² on a finite union of intervals. For the proof we extend to BMO a theorem of Kesten about the discrepancy of irrational rotations of the circle.     

Mechanochemical synthesis of glycine oligomers in a virtual rotational diamond anvil cell

Mechanochemistry of glycine under compression and shear at room temperature is predicted using quantum-based molecular dynamics (QMD) and a simulation design based on rotational diamond anvil cell (RDAC) experiments. Ensembles of high throughput semiempirical density functional tight binding (DFTB) simulations are used to identify chemical trends and bounds for glycine chemistry during rapid shear under compressive loads of up to 15.6 GPa. Significant chemistry is found to occur during compressive shear above 10 GPa. Recovered products consist of small molecules such as water, structural analogs to glycine, heterocyclic molecules, large oligomers, and polypeptides including the simplest polypeptide glycylglycine at up to 4% mass fraction. The population and size of oligomers generally increases with pressure. A number of oligomeric polypeptide precursors and intermediates are also identified that consist of two or three glycine monomers linked together through C–C, C–N, and/or C–O bridges. Even larger oligomers also form that contain peptide C–N bonds and exhibit branched structures. Many of the product molecules exhibit one or more chiral centers. Our simulations demonstrate that athermal mechanical compressive shearing of glycine is a plausible prebiotic route to forming polypeptides.

Compressive shearing forces can induce mechanochemical oligomerization reactions in glycine.     

Square Integrable Group Representations and?the?Uncertainty Principle

Let U be a square integrable representation of a Lie group G of transformations in a Hilbert space H\mathcal{H}, and let y ? H\psi\in\mathcal{H} be an admissible state. We call the product of variances in the state ψ, associated to two non-commuting infinitesimal operators T ₁ and T ₂, uncertainty measure.