Epitaxial structures of garnets as scintillation detectors of ionizing radiation

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 52, No. 6, pp. 967–972, June, 1990.     

On generalizations of Fermat curves over finite fields and their automorphisms

Let 𝒳 be an irreducible algebraic curve defined over a finite field 𝔽_q of characteristic p>2. Assume that the 𝔽_q-automorphism group of 𝒳 admits a subgroup isomorphic to the direct product of two cyclic groups C_m and C_n of orders m and n prime to p, such that both quotient curves 𝒳∕C_n and 𝒳∕C_m are rational. In this paper, we provide a complete classification of such curves as well as a characterization of their full automorphism groups.     

The Use of Aryl-Substituted Homophthalic Anhydrides in the Castagnoli–Cushman Reaction Provides Access to Novel Tetrahydroisoquinolone Carboxylic Acid Bearing an All-Carbon Quaternary Stereogenic Center

Novel aryl-substituted homophthalic acids were cyclodehydrated to the respective homophthalic anhydrides for use in the Castagnoli–Cushman reaction. With a range of imines, this reaction proceeded smoothly and delivered hitherto undescribed 4-aryl-substituted tetrahydroisoquinolonic acids with remarkable diastereoselectivity, good yields and no need for chromatographic purification. These findings significantly extend the range of cyclic anhydrides employable in the Castagnoli–Cushman reaction and signify access to a novel substitution pattern around the medicinally relevant tetrahydroisoquinolonic acid scaffold.     

An Inorganic Tire-Tread Lattice: Hydrothermal Synthesis of the Layered Vanadate [N(CH3)4]5V18O46 with a Supercell Structure

Two distinct V ₉ O ₂₃ building blocks having different vanadium coordination environments are intergrown in the unusual layered vanadate [N(CH₃)₄]₅V₁₈O₄₆ (see picture). Lattice strain is relieved by alternation of the vanadate strips formed from the blocks in both directions (akin to a three-dimensional tire tread). The formation of this lattice has implications for the assembly mechanism of this compound and related materials in hydrothermal synthesis.     

Characterization of CdTe thin films fabricated by close spaced sublimation technique and a study of Cu doping by ion exchange process

CdTe thin films were prepared onto water-white glass substrates by the close spaced sublimation technique. The films annealed right after the deposition were then immersed in copper nitrate solution for different periods of time. These films were again annealed at 500 ^oC for 1 h to ensure the diffusion of copper in the films. The samples were characterized by X-ray diffraction and scanning electron microscopy. The electron microprobe analyzer showed an increase of copper-content in composition. The dc electrical conductivity showed a credible increase with increasing copper-content in the films. With the increase of copper-content, the hole mobility increased systematically. The optical parameters were deduced by fitting the optical transmittance in the wavelength range 300–2500 nm.     

The purification and identification of human blood serum proteins with affinity to the antitumor active RL2 lactaptin using magnetic microparticles

The cytopoxic effect of RL2 lactaptin (the recombinant analog of proteolytic fragment of human kappa‐casein) toward tumor cells in vitro and in vivo presents it as a novel promising antitumor drug. The binding of any drug with serum proteins can affect their activity, distribution, rate of excretion and toxicity in the human body. Here, we studied the ability of RL2 to bind to various blood serum proteins. Using magnetic microparticles bearing by RL2 as an affinity matrix, in combination with mass spectrometry and western blot analysis, we found a number of blood serum proteins possessing affinity for RL2. Among them IgA, IgM and IgG subclasses of immunoglobulins, apolipoprotein A1 and various cortactin isoforms were identified. This data suggests that in the bloodstream RL2 lactaptin takes part in complicate protein–protein interactions, which can affect its activity.     

Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors

Energy‐storage technologies, including electrical double‐layer capacitors and rechargeable batteries, have attracted significant attention for applications in portable electronic devices, electric vehicles, bulk electricity storage at power stations, and “load leveling” of renewable sources, such as solar energy and wind power. Transforming lithium batteries and electric double‐layer capacitors requires a step change in the science underpinning these devices, including the discovery of new materials, new electrochemistry, and an increased understanding of the processes on which the devices depend. The Review will consider some of the current scientific issues underpinning lithium batteries and electric double‐layer capacitors.     

Screening for superoxide reactivity in Li-O2 batteries: effect on Li2O2/LiOH crystallization

Unraveling the fundamentals of Li-O(2) battery chemistry is crucial to develop practical cells with energy densities that could approach their high theoretical values. We report here a straightforward chemical approach that probes the outcome of the superoxide O(2)(-), thought to initiate the electrochemical processes in the cell. We show that this serves as a good measure of electrolyte and binder stability. Superoxide readily dehydrofluorinates polyvinylidene to give byproducts that react with catalysts to produce LiOH. The Li(2)O(2) product morphology is a function of these factors and can affect Li-O(2) cell performance. This methodology is widely applicable as a probe of other potential cell components.     

Relativistic polytropic models of charged anisotropic compact objects

In this paper, we introduce new viable solutions to the Einstein-Maxwell field equations by incorporating the features of anisotropic matter distributions within the realm of the general theory of relativity (\begin{document}${\rm GR}$\end{document}). To obtain these solutions, we employed the Finch-Skea spacetime, along with a generalized polytropic equation of state (\begin{document}${\rm EoS}$\end{document}). We constructed various models of generalized polytropes by assuming different values of the polytropic index, i.e., \begin{document}$\eta= \dfrac{1}{2},~ \dfrac{2}{3},~ 1$\end{document}, and \begin{document}$ 2 $\end{document}. Next, numerous physical characteristics of these considered models were studied via graphical analysis, and they were found to obey all the essential conditions for astrophysical compact objects. Furthermore, such outcomes of charged anisotropic compact star models could be reproduced in various other cases including linear, quadratic, and polytropic \begin{document}${\rm EoS}$\end{document}     

Synthesis of Novel Fluorescent Cyclohexenone Derivatives and their Partitioning Study in Ionic Micellar Media

An approach is demonstrated toward the synthesis of four novel cyclohexenone derivatives (CDs) via a convenient route of Michael addition of ethyl acetoacetate. The molecular structures of CDs were confirmed by means of FT-IR, ¹H NMR, EIMS, UV and also by X-ray single crystal structure analysis. CDs are strongly fluorescent compounds and their fluorescent spectra exhibits intense violet fluorescence. To model the binding to biological membranes the behavior of CDs in micellar solutions of a cationic surfactant, cetyltrimethylammonium bromide (CTAB) and an anionic surfactant, sodium dodecylsulfate (SDS) has also been examined. The characteristics of partition and binding interactions of CDs with CTAB and SDS were investigated by UV-Visible and fluorescence spectroscopic techniques. Higher values of all mentioned interactions in case of CTAB, compared to SDS, indicate that there are greater interactions between the CDs and CTAB than with SDS.