Room-temperature polycondensation of β-amino acid derivatives VI. Synthesis of various N-(hydroxyethyl) nylons

Various N-(hydroxyethyl)amino acid esters having a methyl substituent or phenyl group between amine and ester groups have been synthesized and their polycondensation behavior was investigated. These substituted amino acid esters gave amorphous polyamides which were soluble in alcohol. A model reaction between N-(hydroxyethyl)-amine and carboxylic acid ester was carried out in order to elucidate the role of hydroxyethyl group on the polycondensation. It was found that the amidation reaction took place rapidly at room temperature when the alkyl group of the carboxylic acid was small. N-(Hydroxyethyl) polyamides were obtained from N,N′-(bishydroxyethyl)-dicamines and dicarboxylic acid esters. The reaction mechanism of the room-temperature polycondensation reaction is discussed.     

Ultra-thin films of conjugated polymers for opto-electronic applications

Ultra-thin films of precursor polymers for poly(benzimidazole) (PBI), poly(benzoxazole) (PBO), or poly(benzthiazole) (PBT) were formed at air/water interface by spreading monomers and then polymerizing on the water surface. These thin films could be deposited onto appropriate substrates such as quartz by using the Langmuir-Blodgett (LB) method of horizontal lifting. Moreover, the heat treatment of the built-up films of the precursor polymers transformed the films into corresponding PBI, PBO, or PBT, which were high-temperature polymers. The resulting films had uniform and controllable thickness. Electronic and opto-electronic properties of these thin films were evaluated in terms of electric conductivities and nonlinear optical properties.     

Morphologies and domain sizes of microphase-separated structures of block and graft copolymers of different types

Well-defined block and graft copolymers of different types with different compositions and molecular weights, such as styrene(S)-2-vinylpyridine(P) diblock copolymers, SP star-shaped block copolymers, PSP triblock copolymers, styrene(S)-isoprene(I) multiblock copolymers of the (SI)_n type, ISP triblock copolymers, SPP graft copolymers and their deuterated samples were prepared. Variations of the morphologies with compositions, molecular weight dependences of the lamellar domain sizes and conformations and distributions of block chains in the lamellar domains were studied in the strong segregation limit. Besides typical morphologies such as spherical, cylindrical and lamellar structures, ordered bi- and tri-continuous structures were found between cylindrical and lamellar structures for SP diblock copolymers, PSP and ISP triblock copolymers, respectively. The composition ranges of morphologies are different for the block and graft copolymers of different types. The molecular weight dependences of lamellar domain sizes are about the same, but their magnitudes are not always the same for the block and graft copolymers of different types. These results are well explained by the theories of Helfand-Wasserman and Semenov. Block chains in lamellae are extended along the direction perpendicular to lamellae, but they are contracted along the parallel direction. The former result is well explained by the theories, but the latter is not. Chains adjacent to the junction points between different block chains are localized near the domain interface, but chains at the free-ends of block chains are widely distributed in the domain with the maximum at the center of domain.     

Preparation and porous control of amorphous carbons by co-defluorination of perfluorooctane and octafluorotoluene in vapor phases at 423 K

Two types of perfluorocarbon compounds, aliphatic perfluorooctane and aromatic octafluorotoluene, were co-defluorinated using sodium metal, and amorphous carbons were deposited from the vapor phase at very low temperature, 423 K. The products showed morphologies composed of fibrous, platelet, and spherical forms, which were dependent on the mixing ratio of the two. The BET surface areas also correlated well with the ratio of the starting mixtures, indicating that the surface area could be adjusted by changing the mixing ratio of these two compounds. However, when the carbonaceous product was further annealed in situ at 573 or 673 K, the porosities also modified. First the porosity decreased at 573 K, then increased greatly at 673 K, where radical interaction to shrink the pores and crystal growth of template fluoride occurred at 573 K and 673 K, respectively.     

Study of the metastable region in the growth of GaN using the Na flux method

It was revealed that the metastable region, in which liquid phase epitaxy (LPE) of GaN single crystals proceeds without the generation of polycrystals, expands with growth temperature in the Na flux method. The metastable region appears when LPE growth proceeds at temperatures above 1073 K, although generation of polycrystals inevitably occurs on a crucible at temperatures less than 1073 K. The highest growth rate of 14 μm/h in a small experimental setup was achieved at a temperature of 1163 K with a nitrogen pressure of 5.5 MPa due to complete suppression of the growth of polycrystals on a crucible, even though the supersaturation at this condition reached a fairly high level.Also, an LPE crystal with a flat surface could easily be obtained under high-temperature conditions.     

Photonic Implementation of Quantum Computation Algorithm Based on Spatial Coding

Several implementation methods of quantum computation algorithm by conventional computer have been explored for large-scale emulation. Due to the lack of quantum effects, these methods generally require exponential growth of the size of the hardware with increase of the number of qubits. In this paper, the spatial coding, which is an effective digital optical computing technique, is studied as an efficient implementation method of quantum computation algorithms. In the proposed scheme, quantum information is represented by the intensity and the phase of elemental cells. We confirmed correct operation of the quantum teleportation algorithm by computer simulation. We also demonstrated a photonic implementation of some of the quantum gates experimentally.     

An Isolated Umbilical Point of the Graph of a Homogeneous Polynomial

Suppose that the origin o of R ³ is an isolated umbilical point of the graph of a homogeneous polynomial in two real variables of degree k3. Then we see that the index of o is an element of the set 1–k/2+i ^[k/2] _i=0. Moreover, we see that each element of 1–k/2+i ^[k/2] _i=0 may be the index of o on the graph of a suitable homogeneous polynomial of degree k.     

Acylation of heteroaromatic amines. II dibenzoylation of aminopyridines

Three isomeric aminopyridines were reacted with an excess of benzoyl chloride in the presence of an excess of triethylamine, giving the corresponding dibenzoylaminopyridines in high yields. As an application of the dibenzoylation, the aminopyridines were also reacted with phthaloyl dichloride, resulting in appreciable yields of the respective N-pyridylphthalimides. The rate of the conversion under various conditions was studied with high pressure liquid chromatography in order to investigate the difference in reactivity among the three isomers.