Advances in the chemical synthesis of brassinosteroids

This review generalizes the latest advances in the chemical synthesis of the plant growth regulators brassinosteroids in 1990–1994.Institute of Bioorganic Chemistry, Belarus Academy of Sciences, 220141, Minsk, ul. Zhodinskaya, 5/2. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 507–544, July–August, 1997.     

Distribution of melamine in polyester–melamine surface coatings cured under nonisothermal conditions

The influence of experimental cure parameters on the diffusion of reactive species in polyester–melamine thermoset coatings during curing has been investigated with X‐ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infrared. The diffusion of melamine plays a vital role in the curing process and, therefore, in the ultimate properties of coatings. At a low (<20%) hexamethoxymethylmelamine (HMMM) crosslinker concentration, the matrix composition is uniform, but at high HMMM concentrations, excess HMMM rapidly segregates to the air–coating interface. The rate of migration is governed by the difference in the surface free energies of polyester and HMMM and the concentration gradient of HMMM between the bulk and the surface. An increased rate of energy absorption also increases the rate of migration of HMMM to the surface. A physical model has been proposed to explain this surface segregation phenomenon in terms of cocondensation and self‐condensation reactions. It suggests that an appropriate amount of melamine can be segregated on the surface and allowed to self‐condense to form a desired thickness of a melamine topcoat through the control of the binder composition and cure conditions. This technique can be implemented to apply a melamine topcoat during cure. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 83–91, 2004     

Elevation of the glass transition temperature in flexible‐chain semicrystalline polymers

In the idealized two‐phase model of a semicrystalline polymer, the amorphous intercrystalline layers are considered to have the same properties as the fully‐amorphous polymer. In reality, these thin intercrystalline layers can be substantially influenced by the presence of the crystals, as individual polymer molecules traverse both crystalline and amorphous phases. In polymers with rigid backbone units, such as poly(etheretherketone), PEEK, previous work has shown this coupling to be particularly severe; the glass transition temperature (T_g) can be elevated by tens of degrees celsius, with the magnitude of the elevation correlating directly with the thinness of the amorphous layer. However, this connection has not been explored for flexible‐chain polymers, such as those formed from vinyl‐type monomers. Here, we examine T_g in both isotactic polystyrene (iPS) and syndiotactic polystyrene (sPS), crystallized under conditions that produce a range of amorphous layer thicknesses. T_g is indeed shown to be elevated relative to fully‐amorphous iPS and sPS, by an amount that correlates with the thinness of the amorphous layer; the magnitude of the effect is severalfold less than that in PEEK, consistent with the minimum lengths of polymer chain required to make a fold in the different cases. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1198–1204, 2007     

Static dust sphere in Einstein-Cartan theory

Physically meaningful solutions of the field equations for static spherical dust distributions in the Einstein-Cartan theory have been obtained. There is one in which the spin is zero at the center and another with zero spin at the boundary of the sphere.     

Parametric linear programming techniques for the indefnite quadratic programming problem

In this paper, we discuss a multiparametric technique for findinga global minimum for an indefinite quadratic programming problembased on the spectral decomposition of the matrix of the quadraticform. Special attention is given to the case where this matrixhas only rank 1, where the multiparametric linear program turnsout to be a single-parameter linear program. An extension ofthe traditional linear parametric procedure is introduced whichin general solves this problem efficiently. However, an exampleis presented showing that this technique may take an exponentialnumber of steps.     

Optimal repair-cost limit for a consumer following expiry of a warranty

This paper develops a methodology for obtaining the optimalrepair-cost limit for the repair-replace decision that a consumerfaces on the expiry of a product warranty, where the producthas been minimally repaired on failure during the warranty.Three cases are considered; (i) an exponentially distributedtime to failure with an arbitrary repair-cost distribution,(ii) an exponentially distributed time to failure with a uniformrepair-cost distribution, and (iii) a Weibull-distributed timeto failure with a beta-distributed repair cost. Numerical optimizationsare performed for the third case, and conclusions drawn as tothe sensitivity of the optimal repair-cost limit on the parametervalues of the distributions involved.     

Periodic solutions of second-order quasilinear hyperbolic equations

We study a periodic boundary-value problem for a quasilinear equation with the d'Alembert operator on the left-hand side and a nonlinear operator on the right-hand side and establish conditions under which the solution of the indicated problem is unique.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 47, No. 10, pp. 1370–1375, October, 1995.     

High-frequency asymptotic behavior of the electromagnetic field on the surface of a stratified medium

Translated from Metody Matematicheskogo Modelirovaniya i Vychislitel'noi Diagnostiki, pp. 174–180, Izd. Moskovskogo Universiteta, Moscow, 1990.