排序方式: 共有158条查询结果,搜索用时 23 毫秒
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Alireza Aslani Mohammadreza Arefi Khalil Beyki-Shuraki Aziz Babapoor 《Journal of Saudi Chemical Society》2013,17(4):403-407
Lead iodide, bromide and chloride nanoparticles (NP-PbX2, X = I, Br and Cl) with various morphologies were successfully prepared through a simple hydrothermal method without any additives or stabilizers. By treating the PbX2 in EtOH/CH2Cl2 solution at 170 °C for 12 h, the corresponding PbX2 nanoparticles were synthesized. The average sizes of PbX2 nanoparticles were between 30 and 80 nm. The structure, morphology, surface and size of PbX2 nanoparticles were determined by X-ray diffraction powder, Scanning Electron Microscopy, solid state Photo Luminescent, BET surface area and solid state UV. 相似文献
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Mohammadreza Shariatgorji Juan Astorga-Wells Leopold L. Ilag 《Analytical and bioanalytical chemistry》2011,399(1):191-195
Downscaled analytical tools for sample preparation have offered benefits such as higher throughput, easier automation and
lower sample/reagent consumption. Microfluidic electrocapture, which is a newly developed sample preparation/manipulation
system, uses an electric field to trap and separate charged species without using any solid sorbent. The feasibility of using
microfluidic electrocapture is reported for separation, clean-up, concentration, microreactions and complexation studies of
proteins, peptides and other biologically important biomolecules. The instrumentation and applications of microfluidic electrocapture
are reviewed and an overview is provided of future perspectives offered by the current and envisaged platforms. 相似文献
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Mohammadreza Khanmohammadi 《光谱学快报》2013,46(4):269-272
An accurate and stable algorithm, QR Decomposition Algorithm (QRDA) is initially presented into the chemistry field. The basic principle of QR Multivariate Calibration Algorithm (QRMCA) is investigated, and the complexes system of sodium tripolyphosphate (STPP), sodium sulfate (SS), and sodium Carbonate (SC) with serious overlapping absorption peaks is analyzed by QRMCA. According to our survey, QRDA can avoid matrix inverting, reduce the orders of matrixes, and speed up the operation of matrices. So, it has bright prospects in chemometrics. The process of the QR Decomposition Algorithm (QRDA) was implemented by an orthogonal and upper triangular matrix decomposition that is robust and convenient. Then it was applied to overcome the problem of overlapping spectra of different components in detergent-washing powder. 相似文献
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Masoud Bodaghi Hesam Zolfonoon Mohammadreza Tahriri Meysam Karimi 《Solid State Sciences》2009,11(2):496-500
In this present work, the synthesis of nanocrystalline α-Al2O3 using pure aluminum (Al) and Fe2O3 (hematite) as the precursors by mechanical alloying technique has been studied. The formation of α-Al2O3 nanocrystallites occurs during the solid-state reaction and through the reduction treatment. Also in this paper, effects of milling time on particle size and the lattice strain nanocrystalline α-Al2O3 have been investigated. Obtained powders were evaluated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), differential thermal analysis (DTA), thermal gravimetric analysis (TGA) and X-ray diffraction (XRD). The obtained results indicated that a reduction reaction was completed after 2 h milling in a planetary mill. The crystallite size of obtained α-alumina (α-Al2O3) was in general about 12 nm. Finally, the results showed appropriate homogeneity and dispersion of related nanocrystalline. 相似文献
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Mohammadreza Khanmohammadi Amir Bagheri Garmarudi Nafiseh Khoddami Keyvan Shabani Mohammadreza Khanlari 《Microchemical Journal》2010,95(2):337-340
Determination of particle size is one of the critical parameters in nanotechnology. The relationship between particle size and diffuse reflectance (DR) spectra in near-infrared region has been applied to introduce a method for estimation of particle size. Back-propagation artificial neural network (BP-ANN) as a nonlinear model was applied to estimate average particle size based on near-infrared diffuse reflectance spectra. Thirty five different nano TiO2 samples with different particle size were analyzed by DR-FTNIR spectrometry and the obtained data were processed by BP-ANN. The network was trained by 30 samples and was evaluated by the remaining 5 samples. In order to establish whether the new method is applicable for estimation of particle size of nano structured samples, the optimized model was applied to analyze 44 nano TiO2 samples. It was observed that ANN using the back-propagation algorithm is capable of generalization and could correctly predict the average particle size of nano-sized particles. 相似文献
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Synthesis of molecularly imprinted polypyrrole as an adsorbent for solid‐phase extraction of warfarin from human plasma and urine 下载免费PDF全文
The aim of this work was to develop a method for the clean‐up and preconcentration of warfarin from biological sample employing a new molecularly imprinted polymer (MIP) as a selective adsorbent for solid‐phase extraction (SPE). This MIP was synthesized using warfarin as a template, pyrrole as a functional monomer and vinyl triethoxysilane as a cross‐linker. The molar ratio of 1:4:20 (template–functional monomer–cross‐linker) showed the best results. Nonimprinted polymers (NIPs) were prepared and treated with the same method, but in the absence of warfarin. The prepared polymer was characterized by Fourier transmission infrared spectrometry and scanning electron microscopy. An adsorption process (SPE) for the removal of warfarin using the fabricated MIPs and NIPs was evaluated under various conditions. Effective parameters on warfarin extraction, for example, type and volume of elution solvent, pH of sample solution, breakthrough volume and maximum loading capacity, were studied. The limits of detection were in the range of 0.0035–0.0050 µg mL?1. Linearity of the method was determined in the range of 0.0165–10.0000 µg mL?1 for plasma and 0.0115–10.0000 µg mL?1 for urine with coefficients of determination (R2) ranging from 0.9975 to 0.9985. The recoveries for plasma and urine samples were >95%. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Anna M. Fyhn Xiaodong Yang Mohammadreza Nematollahi John C. Walmsley Ursula J. Gibson 《Journal of Solid State Electrochemistry》2014,18(1):13-18
We demonstrate the anodic electrodeposition of copper-doped AgO at high pH using a silver counter-electrode. Precipitates from a mixture of nitrates and NaOH provided source material for the deposition, and application of a moderate anodic voltage (0.9 V) to the substrate led to deposition of crystalline nanoparticles with incorporated copper. Further increase of the NaOH concentration reduced the amount of copper in the crystals, and higher voltages degraded the crystal quality. XRD confirms the underlying structure to be that of AgO, and Auger and energy dispersive x-ray analyses confirm copper concentrations of approximately 3 % in the crystals. 相似文献
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In this paper, a new approach is proposed for nondestructive characterization of immersed and embedded isotropic rod-shaped samples by inversion of acoustic scattering data. The normal mode expansion technique is used for modelling the scattered field and the compression incident and compression scattered waves are considered. Genetic algorithm is the inversion technique used for estimating the elastic wave velocities and density of the rods from their measured backscattered pressure spectrum. The inversion technique is capable of computing the parameter values that best fit a particular set of data. A perturbation study is conducted on the sensitivity of the resonance frequencies to changes in elastic properties and density of the rods. The numerical results indicate that proper selection of resonance frequencies leads to accurate measurement of elastic constants and density. The proposed approach showed very good convergence and the results obtained were found to agree very well with available data. 相似文献