Polyaniline-coated cerium oxide nanoparticles as an efficient adsorbent for preconcentration of ultra-trace levels of cadmium (ІІ) followed by electrothermal atomic absorption spectrometry

For the first time, polyaniline-coated cerium oxide nanoparticles were synthesized in alkaline media and applied for preconcentration of ultra-trace levels of cadmium (??) in different real samples followed by electrothermal atomic absorption spectrometry. Cerium oxide nanoparticles were synthesized by a microwave method and modified by polyaniline to produce polyaniline-coated cerium oxide nanoparticles. Fourier-transform infrared spectroscopy and scanning electron microscopy were used to characterize the synthesized adsorbent. To optimize the critical experimental conditions; surface response methodology—Box–Behnken experimental design was used. On the basis of the results, pH 8.4, 10?mg of polyaniline-coated cerium oxide nanoparticles, 14.4?min extraction time, and 4.3?min desorption time were selected as the optimum conditions. Under the optimum conditions the calibration curve of cadmium (??) was linear in the range of 0.02–0.4?ng?mL^?1 with a correlation coefficient of 0.9976. The relative standard deviation based on seven replicate analysis of 0.1?ng?mL^?1 cadmium (??) was 4.2% and limit of detection was 0.005?ng?mL^?1 cadmium (??). The analysis of certified reference material shows very good agreement with the certified value. Finally, the proposed method was applied for the determination of ultra-trace levels of cadmium (??) in different water, rice, and tea samples.     

Tracking noisy limit cycle oscillation with nonlinear filters

For engineering systems, the dynamic state estimates provide valuable information for the detection and prediction of failure due to noise and vibration. From this perspective, nonlinear filtering techniques are applied to the problem of state estimation of dynamical systems undergoing noisy limit cycle oscillation. Specifically, the extended Kalman filter, ensemble Kalman filter and particle filter are used to track the limit cycle oscillations of a Duffing oscillator using noisy observational data. The noisy limit cycle oscillations feature highly non-Gaussian trends. The efficiency and limitations of the extended Kalman filter, ensemble Kalman filter and particle filter in tracking limit cycle oscillations are examined with respect to the model and measurement noise and sparsity of measurement data. For the limit cycle oscillations considered here, it is demonstrated that the ensemble Kalman filter and particle filter outperform the extended Kalman filter in the presence of sparse observational data or strong measurement noise. For moderate measurement noise and frequent measurement data, the ensemble Kalman filter and particle filter perform equally well in comparison to the extended Kalman filter.     

Cross-phase modulation induced phase fluctuations in optical RZ pulse propagating in dispersion compensated WDM transmission systems

The basic mechanism of cross-phase modulation induced phase fluctuations in optical RZ pulse propagating in a periodically dispersion compensated transmission line has been investigated. Ordinary differential equations have been derived using variational analysis to estimate the phase fluctuation and the analytical result is verified by numerical simulations based on split-step Fourier method. We therefore explore the impact of different dispersion compensation maps on phase fluctuation for 10 Gb/s and 40 Gb/s WDM transmission systems. The effects of initial pulse spacing between channels, channel spacing and residual dispersion on phase shift have been studied. We find that cross-phase modulation induced phase fluctuation can be mitigated by proper adjustment of channel spacing and/or residual dispersion.     

A perturbed hard-sphere equation of state extended to imidazolium-based ionic liquids

A perturbed hard-sphere equation of state (EOS) has been previously employed to predict pressure–volume–temperature properties of some ionic liquids (ILs) with phosphonium-, pyridinium-, and pyrrolidinium cations. In this work, we have extended the considered EOS to another class of ILs in compressed states. This class consists of 14 imidazolium-based ILs. The predicted densities were compared with those obtained from the experiment, over a broad pressure range from 0.1 to 200 MPa. From 1,122 data points examined for the aforementioned ILs, the total average absolute deviation was found to be 1.05%.     

Jet ejection from droplets near the Leidenfrost temperature

Abstract  

Droplets impinging on a hot surface that is near the Leidenfrost temperature were experimentally investigated. Ejection of jets from the top of the droplet was observed during the transient interaction between the droplet and a hot wall. We term this phenomenon jet ejection from droplets. When the bottom of the droplet initially impacts the hot surface, a jet is to be ejected from the top of the droplet. The jet ejection occurred only at low impact velocities and around the wetting limit temperature. It was not observed when droplets were dropped from large heights or when the surface was at a high temperature.     

Synthesis of 2-Mercaptonicotinic Acid-Capped CdSe Quantum Dots and its Application to Spectrofluorometric Determination of Cr(VI) in Water Samples

The CdSe quantum dots (QDs) capped with 2-mercaptonicotinic acid (H₂MN) were prepared through a controllable process at 80 °C. The prepared QDs were characterized by XRD, TEM, IR, UV–Vis and fluorescence (FL) techniques. It was found that the QDs were nearly mono-disperse with the diameters in the range of 8–10 nm. These QDs are capable to exhibit strong FL even in concentrated acidic media. They exhibit an enhanced fluorescence in the presence of Cr(VI), which was used for the determination of Cr(VI) in water samples. The linear range was found to be 1?×?10^?7–6.0?×?10^?6 M with the RSD and DL of 0.92 % and 5?×?10^?8 M, respectively. Except that Ca²⁺ and Fe³⁺ which can be eliminated through a simple precipitation process, the other co-existent ions present in natural water were not interfered. The recoveries obtained for the added amounts of Cr(VI) were in the range of 96.9–103.2 %, which denote on application of the method, satisfactorily.