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排序方式: 共有219条查询结果,搜索用时 15 毫秒
1.
Fukuyama Y Minami H Matsuo A Kitamura K Akizuki M Kubo M Kodama M 《Chemical & pharmaceutical bulletin》2002,50(3):368-371
New five seven-membered vibsane-type diterpenes named 5-epi-vibsanin C, 5-epi-vibsanin H, 5-epi-vibsanin K, 18-O-methyl-5-epi-vibsanin K and 5-epi-vibsanin E have been isolated from the leaves of Viburnum awabuki (Caplifoliaceae). Their structures have been elucidated by analyses of spectroscopic data and comparison of their spectral data with those of the previously known seven-membered vibsane-type diterpenes. The occurrence of these seven-membered vibsane-type diterpenes with a cis relationship on the C-5 and C-10 positions in nature have been predicted by conformational analysis of vibsanin B, an eleven-membered vibsane-type diterpene. Vibsanin C, 5-epi-vibsanin C and 5-epi-vibsanin H exhibited moderate cytotoxic activities on KB cells. 相似文献
2.
Tao Wang Shuai Shi Dr. Mie Højer Vilhelmsen Tuo Zhang Dr. Matthias Rudolph Prof. Dr. A. Stephen K. Hashmi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(37):12512-12516
New and chemoselective gold(I)‐catalyzed transformations of 1‐(arylethynyl)‐7‐oxabicyclo[4.1.0]‐ heptan‐2‐ones were developed. Two completely different products—6,7‐dihydrobenzofuran‐4(5H)‐ones and benzofurans—could be obtained from the same starting material. The selectivity is determined by the ligand of the gold catalyst: triphenylphosphine delivers 6,7‐dihydrobenzofuran‐4(5H)‐ones, and 1,3‐bis(diisopropylphenyl)imidazol‐2‐ylidene leads to benzofurans. Eleven examples of each case are provided. The mechanistic suggestions for the pathways to both product types are supported by isotope labeling experiments. 相似文献
3.
Prof. Dr. A. Stephen K. Hashmi Tobias Lauterbach Dipl.‐Chem. Pascal Nösel Dr. Mie Højer Vilhelmsen Dr. Matthias Rudolph Dr. Frank Rominger 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(3):1058-1065
A series of dinuclear gold σ,π‐propyne acetylide complexes were prepared and tested for their catalytic ability in dual gold catalysis that was based on the reaction of an electrophilic π‐complex of gold with a gold acetylide. The air‐stable and storable catalysts can be isolated as silver‐free catalysts in their activated form. These dual catalysts allow a fast initiation phase for the dual catalytic cycles without the need for additional additives for acetylide formation. Because propyne serves as a throw‐away ligand, no traces of the precatalyst are generated. Based on the fast initiation process, side products are minimized and reaction rates are higher for these catalysts. A series of test reactions were used to demonstrate the general applicability of these catalysts. Lower catalyst loadings, faster reaction rates, and better selectivity, combined with the practicability of these catalysts, make them ideal catalysts for dual gold catalysis. 相似文献
4.
Dr. Julian Heinrich Dr. Karolina Bossak-Ahmad Mie Riisom Dr. Haleh H. Haeri Tasha R. Steel Vinja Hergl Alexander Langhans Corinna Schattschneider Jannis Barrera Dr. Stephen M. F. Jamieson Prof. Matthias Stein Prof. Dariush Hinderberger Prof. Christian G. Hartinger Prof. Wojciech Bal Prof. Nora Kulak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(72):18093-18102
Redox-active Cu(II) complexes are able to form reactive oxygen species (ROS) in the presence of oxygen and reducing agents. Recently, Faller et al. reported that ROS generation by Cu(II) ATCUN complexes is not as high as assumed for decades. High complex stability results in silencing of the Cu(II)/Cu(I) redox cycle and therefore leads to low ROS generation. In this work, we demonstrate that an exchange of the α-amino acid Gly with the β-amino acid β-Ala at position 2 (Gly2→β-Ala2) of the ATCUN motif reinstates ROS production (•OH and H2O2). Potentiometry, cyclic voltammetry, EPR spectroscopy and DFT simulations were utilized to explain the increased ROS generation of these β-Ala2-containing ATCUN complexes. We also observed enhanced oxidative cleavage activity towards plasmid DNA for β-Ala2 compared to the Gly2 complexes. Modifications with positively charged Lys residues increased the DNA affinity through electrostatic interactions as determined by UV/VIS, fluorescence, and CD spectroscopy, and consequently led to a further increase in nuclease activity. A similar trend was observed regarding the cytotoxic activity of the complexes against several human cancer cell lines where β-Ala2 peptide complexes had lower IC50 values compared to Gly2. The higher cytotoxicity could be attributed to an increased cellular uptake as determined by ICP-MS measurements. 相似文献
5.
Amii H Ichihara Y Nakagawa T Kobayashi T Uneyama K 《Chemical communications (Cambridge, England)》2003,(23):2902-2903
N-Allylic difluoroenamines exhibited unusual behaviors under thermal conditions; N-allyl difluoroenamines in refluxing xylene afforded not only aza-Claisen rearrangement products, but also 2-azabicyclo[2.1.1]hexanes, whose formation could be explained via intramolecular [2+2]-cycloaddition, whilst N-prenyl difluoroenamine underwent an ene reaction to give the pyrrolidine as a sole product. 相似文献
6.
H. Akimune T. Yamagata S. Nakayama M. Fujiwara K. Fushimi K. Hara K. Y. Hara K. Ichihara K. Kawase K. Matsui K. Nakanishi A. Shiokawa M. Tanaka H. Utsunomiya M. Yosoi 《Physics of Atomic Nuclei》2004,67(9):1721-1725
Trinucleon molecular structures in 6He and 6Be were investigated by using the 6Li(7Li, 7Be)6He reaction at 455 MeV and 6Li(3He, t)6Be reaction at 450 MeV, respectively. Binary decays into t + t from a broad state at E x =18.0±1.0 MeV in 6He and into 3He + 3He from one at E x =18.0±1.2 MeV in 6Be, respectively, were observed by measuring trinucleon cluster decays in coincidence with reaction particles. The branching ratios for binary decay were estimated to be about 0.7 for 6He and 6Be. These large branching ratios show that a trinucleon cluster state exists as an isobaric partner around E x =18 MeV in 6He and 6Be. 相似文献
7.
Hajime Nagano Atsushi Torihata Mika Matsushima Ryo Hanai Yoshinori Saito Makiko Baba Yui Tanio Yasuko Okamoto Yuriko Takashima Mayu Ichihara Xun Gong Chiaki Kuroda Motoo Tori 《Helvetica chimica acta》2009,92(10):2071-2081
Root chemicals and evolutionarily neutral DNA regions in L. cyathiceps samples collected in the Zhongdian (Shangrila) County of Yunnan, P. R. China, were examined. Twenty compounds were isolated, including three new ones, 1β,10β‐epoxy‐6β‐(propionyloxy)furanoeremophilan‐9‐one ( 6 ), 1β,10β‐epoxy‐8α‐ethoxyeremophila‐6,11‐diene ( 14 ), and 11αH‐6β‐isobutyryloxy‐1β,10β,7β,8β‐diepoxyeremophilan‐12,8α‐olide ( 15 ). The chemical diversity was found to be limited, with cacalol ( 1 ) and 6‐(acyloxy)furanoeremophilan‐9‐ones ( 4 and/or 5 ) being major components in all the samples. The nuclear ribosomal RNA gene was also found to harbor little variation, although two distinct sequence types were found for the plastid atpB‐rbcL intergenic region. 相似文献
8.
9.
Y. Ichihara 《Lithuanian Mathematical Journal》2008,48(2):188-202
We consider the sum of coefficients which are in the Dirichlet series expansion of symmetric square L-functions. In this paper, we obtain two estimates of this sum in weight and level aspects. These imply two estimates of the
sum of the n
2th Fourier coefficients of cusp forms. 相似文献
10.
Masafumi Yano Yorichika Okino Yuji Ichihara Masakazu Tatsumi Munetaka Oyama Kazunobu Sato Takeji Takui 《Polyhedron》2009,28(9-10):1764-1767
Three highly π-extended tetraaryl-1,3-phenylenediamines for charged high-spin molecular systems were successfully synthesized using Suzuki coupling. Their electrochemical and spectroscopic properties were also examined. They showed blue fluorescence. The dications derived from highly π-extended tetraaryl-1,3-phenylenediamines were generated and characterized by electron transfer stopped-flow method. 相似文献