Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-（Acylamino）acrylates

Enantiomerically pure β-amino acids and their derivatives are especially attractive due to their vital importance for biochemical and medicinal applications1. One of the most convenient paths to β-amino acids involves the asymmetric hydrogenation of the…     

机械臂运动路径设计问题

针对机械臂运动的逆问题,提出了无障碍空间的牛顿迭代算法.并对牛顿迭代法进行了改进,建立了有障碍空间中避碰问题的一般模型,并对问题进行了求解.对于求出的机械臂指尖的姿态,先采用最大步长调整,再对剩余部分采用一次微调的方法生成指令序列,使生成的序列尽可能的短.针对具体问题①,给出了达到目标点的一个指令序列,步数为89步,精度为0.179mm;对于问题②,离散化裂纹,应用大步长调整的牛顿迭代法,给出了一个运动序列,实现了避碰焊接,各点的平均精度达到0.188mm,并对最低点附近在1mm误差范围内不可达到的区域进行了讨论,用解析和仿真的方法证明和验证了最低点不可达;对于问题③,改进了避碰问题的一般模型和算法,用试探法实现了四个焊接点的无碰焊接,并对圆台内表面在1mm误差范围内不可焊接的区域进行了分析.     

面向对象的BESⅢ探测器模拟系统

BESⅢ探测器的模拟软件包BOOST, 是基于Geant4开发的面向对象的模拟软件. BOOST全面地模拟了BESⅢ探测器的物质和几何结构, 给出了粒子在各个子探测器中的击中信息, 以ASCII码文件的形式输出原始数据和MC truth信息可供重建软件开发和物理分析使用, 初步结果显示BOOST的模拟是合理的.     

机械臂运动路径设计问题

主要运用最优化的思想对机械臂运动路径的设计问题进行了讨论.首先利用空间几何知识,得出了机械臂末端的空间位置与各关节角度间的关系,然后就不同问题进行具体分析后分别建立了最优化模型并设计了相应算法,根据模型和算法并采用逐步缩小搜索范围等方法对各个问题进行了求解.最后,从提高机械臂灵活性和扩大其适用范围方面提出了改进建议.     

Nonplanar Perylene Monoimide-Based Fluorescent Film for Enhanced BTX Sensing

Film-based fluorescent sensors have been adapted into portable devices for the vapor phase detection.The satisfactory sensing per-formance(e.g.,sensitivity,sele...     

Effect of Pr doping on magnetic and dielectric properties of Ni-Zn ferrites by “one-step synthesis”

Pr³⁺-doped Ni-Zn ferrites with a nominal composition of Ni_0.5Zn_0.5Pr_xFe_2−xO₄ (where x=0-0.08) were prepared by a one-step synthesis. The magnetic and dielectric properties of the as-prepared Ni-Zn ferrites were investigated. X-ray diffraction data indicated that, after doping, all samples consisted of the main spinel phase in combination of a small amount of a foreign PrFeO₃ phase. The lattice constants of the ferrites initially increased after Pr³⁺ doping, but then became smaller with additional Pr³⁺ doping. The addition of Pr³⁺ resulted in a reduction of grain size and an increase of density and densification of the as-prepared samples. Magnetic measurement revealed that the saturation magnetization of the as-prepared ferrites, M_s, decreased, while the coercivity, H_c, increased with increasing substitution level, x, and the Curie temperature, T_c, kept a rather high value, fluctuating between 308 and 320 °C. Both the real and imaginary parts of permeability of the ferrites decreased slightly after Pr³⁺ doping. However, the natural resonance frequency shifted towards higher frequency from 13.07 to 36.17 MHz after the addition of Pr³⁺, driving the magnetic permeability to much higher frequency, reaching the highest value (36.17 MHz) when x=0.04. Introduction of Pr³⁺ ions into the Ni-Zn ferrite reduced the values of the dielectric loss tangent, especially in the frequency range of 1-400 MHz. However, the magnitude of dielectric loss of the samples doped with different amounts of Pr³⁺ raised little.     

基于第一性原理计算H_2S、CO_2、CH_4在Fe-MoS_2上的吸附性能

在高含硫气藏开发中,伴随着CH_4的采出,H_2S和CO_2也不可避免的被采出.这两种气体会产生管道腐蚀和气体中毒等诸多不利影响.为了解决这一现实需要,从研究较为广泛的MoS_2材料入手,考虑了其掺杂结构中的吸附性能的变化,相关计算原理基于密度泛函数理论.主要计算了一种吸附式掺杂过渡金属原子Fe在MoS_2上的结构,同时也计算了H_2S,CO_2,CH_4气体在其表面的吸附能,电荷转移,电子密度差等相关参数.结果表明,CH_4对这种材料表现出不敏感的特性,而CO_2、H_2S均表现出吸附的性质,预测这种材料可能作为一种可使用的吸附材料,或是开发作为一种新型的气体预警材料.     

Total syntheses of bupleurynol and its analog

An efficient route to the natural products bupleurynol and its analog (RB-2), isolated from Bupleuri Radix, was established based on versatile intermediate (15). In this synthetic route, Sonogashira and Cadiot-Chodkiewicz coupling as well as Julia-Kocienski olefination are utilized as key steps. The highly efficient synthetic route provides opportunities to explore the biological behavior of bupleurynol and RB-2.     

基于G-四链体的生物传感器在食品污染物检测中的研究进展

食品污染物不仅对人类健康造成了严重威胁,还会给食品工业造成巨大的经济损失。G-四链体(G4)是由鸟嘌呤的碱基配对形成的核酸三维二级结构,具有灵活的绑定能力,已成为生物传感器的重要组成部分。将G4与生物传感器结合用于食品中污染物的检测得到了广泛的应用。本文对G4进行了简介,综述了2015～2022年间G4在食品污染物检测中的研究进展,并对其未来的发展趋势进行了展望。     

Y2O2S∶Eu,Ti,Mg红色长余辉的温度依赖

实际应用中在低温下一些长余辉材料不能正常工作, 因此需要研究长余辉材料的温度依赖特性. 用固相反应法合成了Y2O2S∶Eu, Ti, Mg, 测量了其余辉发射谱和热释光曲线, 研究Y2O2S∶Eu, Ti, Mg在140～300 K和290～350 K温区的长余辉发光的发射光谱和衰减曲线的温度依赖. 当温度低于其热释光曲线起始点230 K时, 其余辉的发射光谱强度较弱. 随温度增加, 其余辉的发射光谱强度随温度增强. 300 K后, 其余辉衰减时间随温度变快. Y2O2S∶Eu, Ti, Mg长余辉的温度依赖行为与其热释光曲线密切相关, 并通过长余辉机制对其进行了分析和讨论.