Yunnandaphninines F and G,New C30 Alkaloids from Daphniphyllum yunnanense

Eight C₃₀ Daphniphyllum alkaloids, including two new ones, yunnandaphninines F and G ( 1 and 2 , resp.), were isolated from the leaves and stems of Daphniphyllum yunnanense. Their structures were elucidated on the basis of the spectroscopic data.     

微型计算机在微弱光谱测试系统中的应用

本文报道了在我们研制的微弱光谱测试系统中微计算机的应用,介绍了数据采集、双机间的DMA传送数据、二维光栅扫描控制、应用微机改善信噪比、应用软件和图形显示等问题。着重讨论如何通过我们所做的研制工作,使性能较低的EG3003微计算机达到OMA系统所要求的水平。     

中子-质子相互作用玻色子模型的转动极限

本文讨论原子核相互作用玻色子模型Ⅱ的SU(3)极限情况。文中给出了按李代数链U(6)(?)SU(3)(?)SO(3)分类的IBM-Ⅱ波函数,并计算了具有此种动力学对称性的原子核能谱。     

Pattern formation in the Schlögl model of nonlinear kinetics

To study the effect of a local, spatial inhomogeneity on the progress of a chemical reaction which may exhibit a nonequilibrium phase transition, we have studied a (slightly) generalized version of a model proposed originally by Schlögl. Focusing on that regime of parameter space where the reaction sequence A + 2X[lrarr2]3X and B + X[lrarr2]C allows a first-order transition, we consider the consequences of introducing a spatially-varying diffusion coefficient characterized by a correlation length which calibrates the region over which the spatial inhomogeneity persists. We find that if the inhomogeneity is localized, only small quantitative differences are found between the exact solution reported earlier by Schlögl and the solutions generated here. However, as the correlation length becomes larger, abruptly at a certain critical value, a qualitative change in the nature of the solutions is found, with apparent oscillations produced in the concentration variable of the problem. We interpret this behavior as indicating the onset of pattern formation, and suggest that this behavior may be of importance in those radiation-induced phenomena where high-energy intermediates are produced.     

Programmed assembly of multi-layered protein/nanoparticle-carbon nanotube conjugates

Biomolecular interactions are used to programme the assembly of multi-layer, multi-functional CNT-based conjugates.     

第一过渡族自由离子光谱与最优化3d电子径向波函数

通过对第一过渡族自由离子光谱参数实验值的线性分析和计算，得到了具有系统性和规律性的最优化３ｄ电子径向波函数。并用最优化３ｄ电子径向波函数计算了自由离子光谱，理论计算与实验进行了比较。     

Photochemical Synthesis and Characterization of 8,9-Dihydroacenaphtho-[1,2-b][1,4]Dioxins

The orange-red 8,9-dihydroacenaphtho[1,2-b] [1,4]dioxins were synthesized by the photo-Diels-Alder reaction of acenaphthenequinone with the corresponding alkenes. The products were characterized by spectroscopic and X-ray methods.     

闪锌矿Ga_(1-x)Al_xN电子结构和光吸收的第一性原理

采用基于密度泛函理论的第一性原理平面波超软赝势法,计算了不同浓度Al(x=0,0.125,0.250,0.375,0.500)掺杂闪锌矿GaN体系的电子结构和光学吸收谱。结果表明:Al掺杂导致系统的晶格常数减小,禁带宽度增大,吸收谱蓝移,可以达到日盲区紫外线探测器的要求。