用于边缘检测的Laplace——样条(▽2S)算子

根据数据平滑理论,提出了一种图象边缘检测的方法:把二维四阶B样条函数与Laplacian算子相结合组合成▽²S算子,对图象卷积之后,根据过零点(ZeroCrossing)确定图象边缘。文中证明了它在图象平滑和边缘检测效果上,优于Marr和Hildreth提出的▽²G算子,且计算量较小。而▽²G算子可用高阶▽²S算子近似。文中给出了一些实验结果。     

非线性回旋动力方程

非线性回旋动力方程是处理等离子体中非线性电磁现象及相关输运现象的有力工具.在任意磁场位形、任意频率下,建立了一套适于描述非线性电磁现象、保留有限Larmor半径(FLR)效应的、自洽的非线性回旋动力的Vlasov-Maxwell方程.     

叶绿体结构和功能的研究——叶绿体残缺膜与线粒体嵴膜组合光合磷酸化活力的重建

本文证明了类囊体残缺膜可以与线粒体嵴膜组合而成为新囊膜。这种膜组织可以通过嵴膜的偶联因子借光能来进行光合磷酸化。电子显微镜图谱显示,这种膜组织是介乎残缺膜与嵴膜之间一种膜组织。 试验结果支持了这样一种观点,即:叶绿体内光合磷酸化与线粒体内氧化磷酸化的磷酸化机构是一致的,其细胞器可能是有着共同的来源。     

关于平面二次系统的极限环

关于常微分方程二次系统的极限环及分布结构,本文得到下述定理: 设有一个三阶细焦点,并且无限远奇点是唯一的简单的奇点,则必存在另外一个粗焦点。在粗焦点外有奇数个极限环,无限远奇点为鞍点,全局结构已定。 在上述的基础上对方程作参数的微小变化,使三阶细焦点跳出三个极限环,则得二个粗焦点,每个外面有奇数个极限环,总极限环数为偶数个,并至少为4个,全局结构已定。     

Potassium ion controlled switching of intra- to intermolecular electron transfer in crown ether appended free-base porphyrin-fullerene donor-acceptor systems

Photoinduced electron transfer in intramolecularly interacting free-base porphyrin bearing one or four 18-crown-6 ether units at different positions of the porphyrin macrocycle periphery and pristine fullerene was investigated in polar benzonitrile and nonpolar o-dichlorobenzene and toluene solvents. Owing to the presence of two modes of binding, stable dyads were obtained in which the binding constants, K, were found to range between 4.2 x 10(3) and 10.4 x 10(3) M(-1) from fluorescence quenching data depending upon the location and number of crown ether entities on the porphyrin macrocycle and the solvent. Computational studies using the B3LYP/3-21G() method were employed to arrive at the geometry and electronic structure of the intramolecular dyads. The energetics of the redox states of the dyads were established from cyclic voltammetric studies. Under the intramolecular conditions, both the steady-state and time-resolved emission studies revealed efficient quenching of the singlet excited free-base porphyrin in these dyads, and the measured rates of charge separation, k(CS), were found to be in the 10(8)-10(9) s(-1) range. Nanosecond transient absorption studies were performed to characterize the electron-transfer products and to evaluate the charge-recombination rates. Shifting of the electron-transfer pathway from the intra- to intermolecular route was achieved by complexing potassium ions to the crown ether cavity(ies) in benzonitrile. This cation complexation weakened the intramolecular interactions between fullerene and the crown ether appended free-base porphyrin supramolecules, and under these conditions, intermolecular type interactions were mainly observed. Reversible inter- to intramolecular electron transfer was also accomplished by extracting the potassium ions of the complex with the addition of 18-crown-6. The present study nicely demonstrates the application of supramolecular methodology to control the excited-state electron-transfer path in donor-acceptor dyads.     

A comparison of hydrogen bonding solvent effects on the singlet oxygen reactions of allyl and vinyl sulfides, sulfoxides, and sulfones

The singlet oxygen (¹Δ_g) photooxidations of 2-methyl-3-phenylthio-2-butene (1a), 1-[(4-nitrophenyl)thio]-2,3-dimethyl-2-butene (2c), 2-methyl-3-phenylsulfinyl-2-butene (3), 2-methyl-3-phenylsulfonyl-2-butene (6), and 1-[(4-nitrophenyl)sulfonyl]-2,3-dimethyl-2-butene (7c) were conducted in the following deuterated solvents: acetonitrile, benzene, chloroform, methanol, or methanol/water mixture. In each case the ene allylic hydroperoxide products and/or the [2+2] cycloaddition products were quantified and inspected for possible hydrogen bonding induced differences in product selectivity and regiochemistry. After comparison to literature values for related substrates, the results indicate that only photooxidations of vinyl sulfides are susceptible to hydrogen bonding solvent effects.     

Highly nonplanar, electron deficient, N-substituted tetra-oxocyclohexadienylidene porphyrinogens: structural, computational, and electrochemical investigations

The structures and electrochemistry of N-benzylated meso-tetrakis (3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene) porphyrinogens have been investigated. Structural determinations reveal the isomeric identity of the products obtained from the N-alkylation of the parent meso-tetra (oxo-cyclohexadienylidene) porphyrinogen. The compounds are subject to increased macrocyclic deformations upon increasing N-substitution culminating in the tetra-N-benzyl derivative, which has a buckling superimposed on the already highly puckered macrocycle. The electrochemical analyses emphasize the electron deficiency of the N-benzylated meso-tetra(oxo-cyclohexadienylidene) porphyrinogens and indicate that they can be considered as quinones conjugated via the unsaturated tetrapyrrolic macrocycle. The N-benzylated compounds studied form stable and well-defined pi-cation radical and pi-anion radical species because of their highly conjugated nature. Ab initio molecular orbital calculations at the B3LYP/3-21G() level confirmed the high degree of conjugation between tetrapyrrole and meso substituents and also gave good agreement between calculated and experimentally determined HOMO-LUMO band gap energies.     

From second to first order transitions in a disordered quantum magnet

The cross sections and transverse spin asymmetries in the hard exclusive electroproduction of decuplet baryons are calculated in the large N(c) limit and found to be comparable to that of octet baryons. Large N(c) selection rules for the production amplitudes are derived, leading to new sensitive tests of the spin aspects of the QCD chiral dynamics both in the nonstrange and strange sectors. Importance of such studies for the reliable extraction of the pion form factor from pion electroproduction is explained.     

甲氧羰基亚甲基三苯基胂与氟代烯烃的反应

本文报道甲氧羰基亚甲基三苯基胂(Ⅰ)与氟代烯烃反应生成加成物,Ⅰ与4,4-二氯六氟丁烯-[1]反应,生成甲氧羰基-[4,4-二氯五氟丁烯-1]-基亚甲基三苯基胂(Ⅲ)和甲氧羰基4,4-二氯2,3,3,4-四氟丁酰基亚甲基三苯基肿(Ⅳ),Ⅲ通过氧化铝柱或经湿苯回流都转化为Ⅳ,Ⅰ与四氟乙烯和六氟丙烯都能发生反应,粗产物通过氧化铝柱后,分离得到相应的羰基化合物Ⅶ和Ⅷ,所有产物的结构都经元素分析、红外光谱、核磁共振谱和质谱分析证明。     

论Ore图的泛连通性

符合Ore条件的简单图称为Ore图,Ore条件指图的两个不相邻的顶点的度数之和不小于图的顶点数。本文搞清了Ore图的泛连通性,同时得到了Ore图的点(边)泛圈性的结果,推广了Bondy的一个结论。